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Crystallized RuTe2 as unexpected bifunctional catalyst for overall water splitting

Tang, Bo, Yang, Xudong, Kang, Zhenhui, Feng, Ligang·2020·Applied Catalysis B: Environmental

Abstract

Abstract Bifunctional catalysis for water splitting is for the first time realized on Ru noble metal in the form of crystallized RuTe2 nanoparticles on graphene. Super activity to the state-of-the-art Pt and RuO2 is found for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) because of the high degree of crystallinity, uniform distribution of nanoparticles, and electronic effect in the catalyst system. It offers a low cell voltage of 1.57 V to drive 10 mA cm−2, 100 mV lower than that of Pt/C-RuO2 benchmark electrodes in an alkaline electrolyte, along with a pretty good chemical and structural stability in the strong corrosive environment. The theory calculation confirms the superior intermediates adsorption property because of the Ru/Te synergism, and Pt like/RuO2 like character for water splitting reaction. It is a very promising catalyst in the alkaline electrolyzer due to the reliable catalytic ability and relatively low price (1/4 Pt).

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Metadata

Authors
Tang, B., Yang, X., Kang, Z., & Feng, L.
Venue
Applied Catalysis B: Environmental
Publisher
Elsevier BV
Published
2020-12
Volume
278
Pages
119281
ISSN
0926-3373 (ISSN-L)
OpenAlex
W3037276627
Cited by
219
References
11
FWCI
7.28
Type
journal article
Language
en
Open access
closed
Licence
  • www.elsevier.com/tdm/userlicense/1.0/ (tdm)
  • www.elsevier.com/legal/tdmrep-license (tdm)
Funders
National Natural Science Foundation of China

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CoChat. (2026). Citation check: Crystallized RuTe2 as unexpected bifunctional catalyst for overall water splitting. https://app.cochat.ai/papers/10.1016/j.apcatb.2020.119281
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Tang, B., Yang, X., Kang, Z., & Feng, L. (2020). Crystallized RuTe2 as unexpected bifunctional catalyst for overall water splitting. Applied Catalysis B: Environmental. https://doi.org/10.1016/j.apcatb.2020.119281

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