Doped graphene for metal-free catalysis
Abstract
Graphene has attracted increasing attention in different scientific fields including catalysis. Via modification with foreign metal-free elements such as nitrogen, its unique electronic and spin structure can be changed and these doped graphene sheets have been successfully employed in some catalytic reactions recently, showing them to be promising catalysts for a wide range of reactions. In this review, we summarize the recent advancements of these new and interesting catalysts, with an emphasis on the universal origin of their catalytic mechanisms. We are full of hope for future developments, such as more precisely controlled doping methods, atom-scale surface characterization technology, generating more active catalysts via doping, and finding wide applications in many different fields.
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Boron doping generates p-type semiconductors.
“In particular, boron doping generates p-type semiconductors [27].”
From Influence of boron doping level and calcination temperature on hydrogen evolution reaction in acid medium of metal-free graphene aerogels (2023) · cites this paper as [27]
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- Authors
- Kong, X.-K., Chen, C.-L., & Chen, Q.-W.
- Affiliations
- Hefei National Laboratory for Physical Sciences at Microscale and Department of Materials Science & Engineering
- CAS Key Laboratory of Soft Matter Chemistry and Department of Polymer Science & Engineering
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 43
- Issue
- 8
- Pages
- 2841-2857
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2082658405
- Cited by
- 783
- References
- 126
- Citations by year
- 2026: 12 · 2025: 41 · 2024: 31 · 2023: 45 · 2022: 56 · 2021: 55 · 2020: 76 · 2019: 90 · 2018: 93 · 2017: 70 · 2016: 96 · 2015: 83 · 2014: 35
- FWCI
- 4.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Society Reviews (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- doped graphene, nitrogen-doped graphene, metal-free catalysts, catalytic mechanism, electronic structure, spin structure, doping methods, surface characterization, heterogeneous catalysis
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
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