Cited by 201Carbon Dioxide Capture TechnologiesThermochemical Biomass Conversion ProcessesAdsorption and biosorption for pollutant removal

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Recent advances in biochar-based adsorbents for CO2 capture

Open access
Guo, Shifang, Li, Yuqing, Wang, Yaru, Wang, Linna, Sun, Yifei, Liu, Lina·2022·Carbon Capture Science & Technology

Abstract

The global industrialization accelerates the use of fossil fuels and hence the excessive emissions of greenhouse gasses, especially carbon dioxide (CO2), which poses a serious threat to the ecological environment. CO2 capture is considered as a potential strategy to reduce the amount of CO2 released into the atmosphere. The development of adsorption materials that are both economically feasible and effective is the most critical issue. Biochar is a promising candidate for CO2 capture among the capture materials. It offers a diverse range of raw materials and a lower environmental impact than other adsorbent materials. Even though pristine biochar could be employed directly to CO2 capture, it generally exhibits a poor adsorption performance. Therefore, biochar needs to be modified in practical applications to improve physicochemical properties such as specific surface area, pore structure, and surface functional groups. This paper summaries recent research advances in biochar-based adsorbents for CO2 adsorption. Pre-combustion capture technology and post-combustion capture technology are investigated. The production of biochar and the influence of raw materials and process conditions on the adsorption capacity of CO2 are described in detail. The mechanism of CO2 adsorption on biochar is also discussed, which summarized physical and chemical adsorption, respectively, as well as the corresponding presentation of some current methods of physical/chemical modification of biochar. Finally, the future prospects are proposed in order to provide a guideline for the adsorption of CO2 by biochar. Despite the progress made in the production of biochar for CO2 adsorption, more efforts are needed to produce biochar with higher adsorption capacity and long-term stability for large-scale CO2 capture.

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Crossref · 10.1016/j.ccst.2022.100059

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213 of 213 references verified0 citation errors · 0 not checkable

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Figures

Image 1
CC-BY-NC-ND · From the PDF
Fig. 1 Scheme for carbon dioxide capture and utilization ( de Kleijne et al., 2022 ).
Fig. 1 Scheme for carbon dioxide capture and utilization ( de Kleijne et al., 2022 ).CC-BY-NC-ND · From the PDF
Fig. 2 Specific mechanisms and reaction modeling of biomass pyrolysis (reproduced from ( Vamvuka, 2011 ).).
Fig. 2 Specific mechanisms and reaction modeling of biomass pyrolysis (reproduced from ( Vamvuka, 2011 ).).CC-BY-NC-ND · From the PDF
Fig. 3 Mechanism typically found in biomass gasification in a gasifier with air ( Valderrama Rios et al., 2018 ).
Fig. 3 Mechanism typically found in biomass gasification in a gasifier with air ( Valderrama Rios et al., 2018 ).CC-BY-NC-ND · From the PDF
Fig. 4 Physical and chemical adsorption mechanism of CO 2 on biomass-derived adsorbents.
Fig. 4 Physical and chemical adsorption mechanism of CO 2 on biomass-derived adsorbents.CC-BY-NC-ND · From the PDF
Fig. 5 CO 2 adsorption isotherms at 25 °C. WFW20: biochars with a composition of 20% of food waste/80% of wood, WFW30: biochars with a composition of 30% of food waste + 70% of wood, WFW40: a composition of 40% of food waste + 60% of wood, WFW40-K: a composition of 40% of food waste + 60% of wood + KOH, WFW40-KC: a composition of 40% of food waste + 60% of wood + KOH + CO 2 ( Igalavithana et al., 2020 ).
Fig. 5 CO 2 adsorption isotherms at 25 °C. WFW20: biochars with a composition of 20% of food waste/80% of wood, WFW30: biochars with a composition of 30% of food waste + 70% of wood, WFW40: a composition of 40% of food waste + 60% of wood, WFW40-K: a composition of 40% of food waste + 60% of wood + KOH, WFW40-KC: a composition of 40% of food waste + 60% of wood + KOH + CO 2 ( Igalavithana et al., 2020 ).CC-BY-NC-ND · From the PDF
Fig. 6 CO 2 adsorption capacities of both raw and sono-chemically activated biochar samples synthesized at different pyrolysis temperatures ( Chatterjee et al., 2020 ).
Fig. 6 CO 2 adsorption capacities of both raw and sono-chemically activated biochar samples synthesized at different pyrolysis temperatures ( Chatterjee et al., 2020 ).CC-BY-NC-ND · From the PDF
Fig. 7 Comparison of unactivated biochar and biochar activated physically with steam or chemically activated with acid, oxidant or alkaline solution. ( Sizmur et al., 2017 ).
Fig. 7 Comparison of unactivated biochar and biochar activated physically with steam or chemically activated with acid, oxidant or alkaline solution. ( Sizmur et al., 2017 ).CC-BY-NC-ND · From the PDF
Fig. 8 SEM image of a) biochar after ultrasonic activation, b) biochar after ultrasonic physical activation and amine chemical treatment ( Chatterjee et al., 2018 ).
Fig. 8 SEM image of a) biochar after ultrasonic activation, b) biochar after ultrasonic physical activation and amine chemical treatment ( Chatterjee et al., 2018 ).CC-BY-NC-ND · From the PDF

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Citations

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Research works printed but not linked: 3

  1. 2020, carbon dioxide at record high levels despite reduced emissions in, Met Office
  2. You, 2017, A critical review on sustainable biochar system through gasification: energy and environmental applications, Bioresour. Technol., 246, 242, 10.1016/j.biortech.2017.06.177 · DOI
  3. Li, 2016, Influences of doping nitrogen, sulfur, and phosphorus on the activated carbons for gas adsorption of H2, CH4 and CO2, RSC Adv., 6

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Metadata

Authors
Guo, S., Li, Y., Wang, Y., Wang, L., Sun, Y., & Liu, L.
Affiliations
  • Nankai University (CN)
  • Beihang University (CN)
Corresponding author
  • Sun, Yifei
  • Liu, Lina
Venue
Carbon Capture Science & Technology
Publisher
Elsevier BV
Published
2022-09
Volume
4
Pages
100059
ISSN
2772-6568 (ISSN-L)
OpenAlex
W4285405596
Cited by
201
References
211
Citations by year
2026: 35 · 2025: 74 · 2024: 58 · 2023: 29 · 2022: 5
FWCI
15.65
Type
journal article
Language
en
Open access
Locations
  • Carbon Capture Science & Technology (publishedVersion, cc-by-nc-nd)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
National Natural Science Foundation of China (21976011, 22006075)
Topics
  • Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
  • Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
Keywords
biochar, CO2 capture, CO2 adsorption, biochar modification, pre-combustion capture, post-combustion CO2 capture, adsorption mechanism, physisorption, chemisorption, biochar production, surface functional groups, adsorption capacity, long-term stability

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