Time-resolved dynamics of laser-induced cavitation bubbles during production of Ni nanoparticles via pulsed laser ablation in different solvents and their electrocatalytic activity for determination of toxic nitroaromatics
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In the thermal evaporation process, plasma plume and vapor are produced when a focused laser beam interacts on the surface of the target metal immersed in a liquid.
“In the thermal evaporation process, the plasma plume and vapor are produced when a focused laser beam is allowed to interact on the surface of the target metal immersed in a liquid (solvent).”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
The lifetime of laser-induced cavitation bubbles (LICBs) during Ni NP formation via PLA is dependent on the solvent medium, and the phase of Ni NPs is defined by the LICB lifetime.
“Herein, the time-resolved formation of LICBs was measured using an intensified charge-coupled device camera, and it was found that the lifetime of LICBs is dependent on the solvent medium and that the phase of Ni NPs is defined by the LICB lifetime during the PLA process.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
LICBs produced in ACN medium showed a shorter lifetime, while LICBs produced in methanol exhibited a larger longer lifetime.
“Herein, the LICBs produced in the ACN medium showed a shorter lifetime, while the LICBs produced in methanol exhibited a larger longer lifetime.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
Maximum size of LICBs (2.28, 2.70, 3.36, and 4.0 mm) reached at 201 μs (methanol), 251 μs (DI water), 276 μs (hexane), and 351 μs (ACN), respectively; LICBs collapsed and disappeared completely at 426, 501, 551, and 651 μs, respectively.
“the maximum size of LICBs (2.28, 2.70, 3.36, and 4.0 mm) reached at 201 μs (methanol), 251 μs (DI water), 276 μs (hexane), and 351 μs (ACN), respectively. Consequently, the LICBs began to collapse and disappeared completely at 426, 501, 551, and 651 μs, respectively (Fig. 7a, c), as presented in Table 2.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
The lifetime and size of LICBs highly depend on the solvents used in the PLA process.
“As a result, it is confirmed that the lifetime and size of the LICBs highly depend on the solvents used in the PLA process25.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
Short lifetime of LICBs in ACN leads to formation of metastable hcp phase Ni NPs, while long LICB lifetime produced stable fcc Ni phase in methanol.
“Especially, the short lifetime of LICBs in ACN leads to the formation of metastable hcp phase Ni NPs, while the long LICB lifetime produced a stable fcc Ni phase in methanol.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
When cooling rate is slow, LICB lifetime is long, so Ni NPs have enough time to produce thermodynamically stable fcc structures; when cooling rate is rapid, LICB lifetime is short, and Ni NPs have a metastable hcp phase.
“When the cooling rate is slow, the lifetime of LICBs is long; thus, Ni NPs have enough time to produce thermodynamically stable fcc structures. On the contrary, when the cooling rate of the plasma plume is rapid, the lifetime of LICBs is short, and Ni NPs have a metastable hcp phase.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [25]
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“[153] Methanol, DIW, hexane, acetonitrile Cavitation bubble dynamics of Ni NPs FCC/HCP, Pure FCC and spherical-shaped NPs Bubble lifetime and crystal structure depends on liquid media”
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Self-citationCharacteristics of Cobalt Powders as Laser Cladded Materials for Austenitic and Martensitic Steels
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Progress of laser-assisted methodologies and their advantages
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- Authors
- Lee, S. J., Theerthagiri, J., & Choi, M. Y.
- Affiliations
- Gyeongsang National University (KR)
- Corresponding author
- Choi, Myong Yong
- Venue
- Chemical Engineering Journal
- Publisher
- Elsevier BV
- Published
- 2022-01
- Volume
- 427
- Pages
- 130970
- ISSN
- 1385-8947 (ISSN-L)
- OpenAlex
- W3175465277
- Cited by
- 75
- References
- 40
- Citations by year
- 2026: 8 · 2025: 9 · 2024: 16 · 2023: 11 · 2022: 19 · 2021: 12
- FWCI
- 4.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Chemical Engineering Journal (publishedVersion)
- Funders
- NRF
- KBSI
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Materials Science › Materials Chemistry › Ultrasound and Cavitation Phenomena
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Keywords
- pulsed laser ablation, nickel nanoparticles, solvent effects, bubble lifetime, crystalline phase formation, electrocatalysis, 4-nitrophenol detection, electrochemical sensor, nitroaromatic compounds, glassy carbon electrode
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