Cited by 82Per- and polyfluoroalkyl substances researchToxic Organic Pollutants ImpactFluorine in Organic Chemistry

Priority perfluoroalkyl substances in surface waters - a snapshot survey from 22 developing countries

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Baabish, Abeer, Sobhanei, Siamak, Fiedler, Heidelore·2021·Chemosphere

Abstract

The Stockholm Convention on Persistent Organic Pollutants (POPs) has established a global monitoring plan (GMP) to generate comparable data on the presence of POPs listed in the Stockholm Convention to identify changes in POPs concentrations over time and in regions. Perfluoroalkyl substances (PFAS) have been listed into the annexes of the Stockholm Convention in 2009 and 2019, namely perfluorooctane sulfonic acid (PFOS), its salts and perfluorooctane sulfonyl fluoride and perfluorooctanoic acid (PFOA), its salts and PFOA-related compounds. Perfluorohexane sulfonic acid (PFHxS) is recommended for listing in 2021. Surface water samples from 22 countries through the UNEP/Global Monitoring Plan 2 projects were collected from 2017 until 2019. 144 water samples from Africa (n=44), Asia-Pacific (n=60), and the Group of Latin America and Caribbean countries (GRULAC) (n=40) were analyzed using a ultra-performance liquid chromatograph coupled to a tandem mass spectrometer (UPLC-MS/MS). The three PFAS were quantified in the range of 0.03 ng L-1 to 6.23 ng L-1 for ΣPFOS, 0.05 ng L-1 to 4.02 ng L-1 for PFOA and 0.03 ng L-1 to 3.51 ng L-1 for PFHxS. Variation between or within regions, time points, countries’ economy and population density was assessed. Statistically significant difference was found only for the PFOA concentration in the Asia Pacific region (11 countries) in comparison to Africa (seven countries) and GRULAC (five countries). Using the standardized sampling protocol for surface waters, these data may serve as a baseline for future monitoring activities and the starting point for trend assessment.

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Authors
Baabish, A., Sobhanei, S., & Fiedler, H.
Affiliations
Örebro University (SE)
Corresponding author
Fiedler, Heidelore
Venue
Chemosphere
Publisher
Elsevier BV
Published
2021-06
Volume
273
Pages
129612
ISSN
0045-6535 (ISSN-L)
OpenAlex
W3122442381
Cited by
82
References
19
Citations by year
2026: 16 · 2025: 22 · 2024: 16 · 2023: 4 · 2022: 19 · 2021: 5
FWCI
4.17
Type
journal article
Language
en
Open access
Locations
  • Chemosphere (publishedVersion, cc-by)
  • PubMed (publishedVersion)
Funders
Global Environment Facility
Topics
  • Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
  • Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Toxic Organic Pollutants Impact
  • Life Sciences › Pharmacology, Toxicology and Pharmaceutics › Pharmaceutical Science › Fluorine in Organic Chemistry
Keywords
perfluorinated compounds, PFOS, perfluorooctanoic acid, PFHxS, surface water contamination, Stockholm Convention, persistent organic pollutants, developing countries, Asia-Pacific region, Africa, Latin America and the Caribbean
MeSH terms
Africa, Asia, Caprylates, Chromatography, Liquid, Developing Countries, Fluorocarbons, Water Pollutants, Chemical, Alkanesulfonic Acids, Tandem Mass Spectrometry

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