Occurrence of perfluoroalkyl acids in environmental waters in Vietnam
Abstract
This is the first nationwide study of perfluoroalkyl acids (PFAAs) in environmental waters in Vietnam. Twenty-eight river water and 22 groundwater samples collected in four major cities and 14 river water samples from the Red River were screened to investigate the occurrence and sources of 16 PFAAs. Perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA), and perfluorononanoic acid (PFNA) were the most prevalent of 11 detected PFAAs with maximum concentrations in urban river water of 5.3, 18 and 0.93ngL(-1), respectively, and in groundwater of 8.2, 4.5 and 0.45ngL(-1), respectively. PFAAs in the Red River water were detected at low levels. PFAA concentrations in river water were higher in the rainy season than in the dry season, possibly due to storm water runoff, a common phenomenon in Southeast Asian countries. The highest concentrations of PFAAs in river water were observed in samples from highly populated and industrialized areas, perhaps sourced from sewage. The PFAA concentrations observed were similar to those in other Southeast Asian countries, but lower than in developed nations. From the composition profiles of PFAAs, industrial products containing PFAAs imported from China and Japan might be one of the major sources of PFAAs in the Vietnamese aquatic environment. According to the health-based values and advisory issued by the United States Environmental Protection Agency (USEPA), the concentrations of detected PFAAs in this study do not pose an immediate health risk to humans and aquatic organisms.
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Duong et al. observed higher levels of PFAS in rainy seasons possibly due to stormwater runoff.
“Duong et al. (2015) also observed higher levels of PFAS in rainy seasons possibly due to the influence of stormwater runoff”
From Per and poly-fluoroalkyl substances (PFAS) as a contaminant of emerging concern in surface water: A transboundary review of their occurrences and toxicity effects (2021) · cites this paper as Duong et al., 2015
PFAS contamination was reported in multiple parts of Asia including India, Bangladesh, Vietnam, Singapore, Thailand, Malaysia, and others.
“PFAS contamination was reported in multiple parts of Asia including India, Bangladesh, Vietnam, Singapore, Thailand, Malaysia, and many others (Duong et al., 2015; Habibullah-Al-Mamun et al., 2016; Kim et al., 2012; Lam et al., 2017; Nguyen et al., 2011; Sakurai et al., 2016; Sharma et al., 2016; Yeung et al., 2009).”
From Per and poly-fluoroalkyl substances (PFAS) as a contaminant of emerging concern in surface water: A transboundary review of their occurrences and toxicity effects (2021) · cites this paper as Duong et al., 2015
Maximum concentrations of PFOA and PFOS in groundwater in Vietnam were 4.5 and 8.2 ng L−1, respectively.
“Duong et al. (2015) focused on the occurrence of PFAS in Vietnam and reported that PFOA and PFOS were among the most detected PFAS in urban river waters at maximum concentrations of 18 and 5.3 ng L−1, respectively; while the maximum concentrations of these pollutants detected in groundwater were 4.5 and 8.2 ng L−1, respectively.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
PFAS concentrations in Vietnam were subject to seasonal variation, with relatively higher concentrations in the rainy season versus the dry season.
“Their results indicated that PFAS concentrations were subject to seasonal variation as concentrations were relatively higher in the rainy season versus the dry season suggesting that stormwater runoff could be a potential non-point source of PFAS pollution in Vietnam.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
PFOS was detected in 59% of surface water samples and 45% of groundwater samples in Vietnam.
“PFOA was detected in 98% of surface water samples and 36% of groundwater samples, while PFOS was detected in 59% of surface water samples and 45% of groundwater samples.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
Stormwater runoff could be a potential non-point source of PFAS pollution in Vietnam.
“Their results indicated that PFAS concentrations were subject to seasonal variation as concentrations were relatively higher in the rainy season versus the dry season suggesting that stormwater runoff could be a potential non-point source of PFAS pollution in Vietnam.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
Duong et al. (2015) reported that PFOA and PFOS were among the most detected PFAS in urban river waters in Vietnam, with maximum concentrations of 18 and 5.3 ng L−1, respectively.
“Duong et al. (2015) focused on the occurrence of PFAS in Vietnam and reported that PFOA and PFOS were among the most detected PFAS in urban river waters at maximum concentrations of 18 and 5.3 ng L−1, respectively; while the maximum concentrations of these pollutants detected in groundwater were 4.5 and 8.2 ng L−1, respectively.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
PFOA concentrations in the Red River were generally low, ranging from 0.16 to 0.52 ng L−1.
“PFOA concentrations in the Red River were generally low, ranging from 0.16–0.52 ng L−1, and PFOS was detected at only one location at a concentration of 0.21 ng L−1 (Duong et al., 2015).”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
PFOA was detected in 98% of surface water samples and 36% of groundwater samples in Vietnam.
“PFOA was detected in 98% of surface water samples and 36% of groundwater samples, while PFOS was detected in 59% of surface water samples and 45% of groundwater samples.”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
PFOS was detected at only one location in the Red River, at a concentration of 0.21 ng L−1.
“PFOA concentrations in the Red River were generally low, ranging from 0.16–0.52 ng L−1, and PFOS was detected at only one location at a concentration of 0.21 ng L−1 (Duong et al., 2015).”
From Per- and polyfluoroalkyl substances in water and wastewater: A critical review of their global occurrence and distribution (2022) · cites this paper as Duong et al., 2015
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- Authors
- Duong, H. T., Kadokami, K., Shirasaka, H., Hidaka, R., Chau, H. T. C., Kong, L., Nguyen, T. Q., & Nguyen, T. T.
- Affiliations
- The University of Kitakyushu (JP)
- Vietnam Academy of Science and Technology (VN)
- Corresponding author
- Kadokami, Kiwao
- Venue
- Chemosphere
- Publisher
- Elsevier BV
- Published
- 2015-03
- Volume
- 122
- Pages
- 115-124
- ISSN
- 0045-6535 (ISSN-L)
- OpenAlex
- W2025692940
- Cited by
- 88
- References
- 5
- Citations by year
- 2026: 8 · 2025: 16 · 2024: 4 · 2023: 7 · 2022: 11 · 2021: 16 · 2020: 4 · 2019: 2 · 2018: 8 · 2017: 4 · 2016: 5 · 2015: 3
- FWCI
- 3.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemosphere (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Japan Society for the Promotion of Science (12308030)
- Vietnam Academy of Science and Technology – Vietnam (VAST.HTQT.NHAT.01/2012-2014)
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Per- and polyfluoroalkyl substances research
- Life Sciences › Pharmacology, Toxicology and Pharmaceutics › Pharmaceutical Science › Fluorine in Organic Chemistry
- Physical Sciences › Environmental Science › Water Science and Technology › Fluoride Effects and Removal
- Keywords
- perfluoroalkyl acids, PFOS, perfluorooctanoic acid, PFNA, river water, groundwater, Red River, Vietnam, seasonal variation, stormwater runoff, wastewater pollution, industrial sources, health risk assessment
- MeSH terms
- Caprylates, Cities, Environmental Monitoring, Fatty Acids, Fluorocarbons, Fresh Water, Rain, Sewage, Vietnam, Water Pollutants, Chemical, Alkanesulfonic Acids, Rivers, Groundwater
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