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Recent advances in the controlled preparation of poly(α-hydroxy acids): Metal-free catalysts and new monomers

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Bourissou, Didier, Moebs-Sanchez, Sylvie, Martín-Vaca, Blanca·2007·Comptes Rendus. Chimie
DOI 10.1016/j.crci.2007.05.004
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Abstract

Polylactides (PLAs) are at the forefront of biodegradable polymer research. These poly(α-hydroxy acids) can be prepared by polycondensation of lactic acid or ring-opening polymerization (ROP) of lactide, both routes typically involving metallic promoters. The first part of this review focuses on the recent achievements reported with metal-free systems via organocatalytic (nucleophilic, cationic and bifunctional) as well as enzymatic approaches. The second part of the review concerns the heterocyclic monomers that give access to poly(α-hydroxy acids) such as PLAs. Two complementary approaches will be discussed: substituted 1,4-dioxane-2,5-diones and synthetic equivalents thereof.

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Metadata

Authors
Bourissou, D., Moebs-Sanchez, S., & Martín-Vaca, B.
Venue
Comptes Rendus. Chimie
Publisher
MathDoc/Centre Mersenne
Published
2007-07-13
Volume
10
Issue
9
Pages
775-794
ISSN
  • 1631-0748 (ISSN-L)
  • 1878-1543
DOI
10.1016/j.crci.2007.05.004
OpenAlex
W2053047967
Cited by
169
References
8
FWCI
7.39
Type
journal article
Language
en
Open access
bronze

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Bourissou, D., Moebs-Sanchez, S., & Martín-Vaca, B. (2007). Recent advances in the controlled preparation of poly(α-hydroxy acids): Metal-free catalysts and new monomers. Comptes Rendus. Chimie. https://doi.org/10.1016/j.crci.2007.05.004

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