Controlled Cationic Polymerization of Lactide
Abstract
The combination of trifluoromethanesulfonic acid (as a catalyst) and a protic reagent (such as water, 2-propanol, or 1-pentanol as an initiator) efficiently initiates the cationic polymerization of lactide in dichloromethane solution at room temperature. Polylactides (PLAs) with molar masses up to 20 000 were obtained via an activated-monomer mechanism. 1 H NMR spectroscopy and electrospray-ionization mass spectrometry of PLA oligomers demonstrated the quantitative incorporation of the protic initiator in the polymer chains and showed that transesterification reactions did not occur to a significant extent. The controlled character of the polymerization was indicated by the linear relationships of the number-average molar mass vs monomer conversion and monomer-to-initiator ratio. Kinetic measurements revealed a first-order dependence on monomer concentration. Moreover, no noticeable epimerization of the stereogenic carbon atom was observed in these polymerization conditions, as deduced from 1 H NMR analysis of a poly( l -lactide) sample.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The most commonly used catalysts for ROP are transition and posttransition metal complexes, which mediate ROP through a coordination-insertion type mechanism.
“The most commonly used catalysts for ROP are transition and posttransition metal complexes, which mediate the ROP through a “coordination-insertion” type mechanism (Scheme 7).289”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [289]
Cites
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207 · see citing works
Ovitt, T. M., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012052+ · Cited by 713 · see citing works
Well-Defined Calcium Initiators for Lactide Polymerization
Chisholm, M. H., Gallucci, J. C., & Phomphrai, K. (2004) · Inorganic Chemistry · doi:10.1021/ic0490730 · Cited by 397 · see citing works
Syntheses and application of polylactides
Kricheldorf, H. R. (2001) · Chemosphere · doi:10.1016/s0045-6535(00)00323-4 · Cited by 343 · see citing works
O'Keefe, B. J., Breyfogle, L. E., Hillmyer, M. A., & Tolman, W. B. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012689t · Cited by 297 · see citing works
Zhong, Z., Dijkstra, P. J., Birg, C., Westerhausen, M., & Feijén, J. (2001) · Macromolecules · doi:10.1021/ma0019510 · Cited by 236 · see citing works
A General and Versatile Approach to Thermally Generated N‐Heterocyclic Carbenes
Nyce, G. W., Csihony, S., Waymouth, R. M., & Hedrick, J. L. (2004) · Chemistry - A European Journal · doi:10.1002/chem.200400196 · Cited by 209 · see citing works
Rapid and Controlled Polymerization of Lactide by Structurally Characterized Ferric Alkoxides
O'Keefe, B. J., Monnier, S. M., Hillmyer, M. A., & Tolman, W. B. (2000) · Journal of the American Chemical Society · doi:10.1021/ja003537l · Cited by 207 · see citing works
Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
Csihony, S., Culkin, D. A., Sentman, A. C., Dove, A. P., Waymouth, R. M., & Hedrick, J. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050909n · Cited by 180 · see citing works
Latent, Thermally Activated Organic Catalysts for the On‐Demand Living Polymerization of Lactide
Coulembier, O., Dove, A. P., Pratt, R. C., Sentman, A. C., Culkin, D. A., Mespouille, L., Dúbois, P., Waymouth, R. M., & Hedrick, J. L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500723 · Cited by 155 · see citing works
Chamberlain, B. M., Jazdzewski, B. A., Pink, M., Hillmyer, M. A., & Tolman, W. B. (2000) · Macromolecules · doi:10.1021/ma0000834 · Cited by 131 · see citing works
Sentman, A. C., Csihony, S., Waymouth, R. M., & Hedrick, J. L. (2005) · The Journal of Organic Chemistry · doi:10.1021/jo048555q · Cited by 104 · see citing works
Observation of Weak CH⋅⋅⋅O Hydrogen Bonding to Unactivated Alkanes
Wang, X., Woo, H., Kiran, B., & Wang, L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501349 · Cited by 63 · see citing works
G-Matrix Fourier Transform NOESY-Based Protocol for High-Quality Protein Structure Determination
Shen, Y., Atreya, H. S., Liu, G., & Szyperski, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0501870 · Cited by 60 · see citing works
Drumright, R. E., Gruber, P. R., & Henton, D. E. (2000) · Advanced Materials · doi:10.1002/1521-4095(200012)12:23
New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
Nederberg, F., Connor, E. F., Möller, M., Glauser, T., & Hedrick, J. L. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010716)40:14
Flagged first, then by citations
Cited by
Sorted by citations
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489 · see citing works
Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907 · see citing works
Biodegradable Polymers-A Review on Recent Trends and Emerging Perspectives
Luckachan, G. E., & Pillai, C. K. S. (2011) · Journal of Polymers and the Environment · doi:10.1007/s10924-011-0317-1 · Cited by 767 · see citing works
Biocompatible Initiators for Lactide Polymerization
Platel, R., Hodgson, L., & Williams, C. (2008) · Polymer Reviews · doi:10.1080/15583720701834166 · Cited by 706 · see citing works
Balla, E. D., Daniilidis, V., Karlioti, G., Kalamas, T., Stefanidou, M., Bikiaris, N. D., Vlachopoulos, A., Koumentakou, I., & Bikiaris, D. Ν. (2021) · Polymers · doi:10.3390/polym13111822 · Cited by 661 · see citing works
Organic Catalysis for Ring-Opening Polymerization
Dove, A. P. (2012) · ACS Macro Letters · doi:10.1021/mz3005956 · Cited by 545 · see citing works
Recyclable and (Bio)degradable Polyesters in a Circular Plastics Economy
Shi, C., Quinn, E. C., Diment, W. T., & Chen, E. Y. ‐. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00848 · Cited by 418 · see citing works
Single site catalysts for stereoselective ring-opening polymerization of lactides
Dijkstra, P. J., Du, H., & Feijén, J. (2010) · Polymer Chemistry · doi:10.1039/c0py00204f · Cited by 401 · see citing works
Makiguchi, K., Satoh, T., & Kakuchi, T. (2011) · Macromolecules · doi:10.1021/ma200043x · Cited by 338 · see citing works
Dove, A. P. (2008) · Chemical Communications · doi:10.1039/b813059k · Cited by 311 · see citing works
Hydrogen-bonding organocatalysts for ring-opening polymerization
Thomas, C., & Bibal, B. (2013) · Green Chemistry · doi:10.1039/c3gc41806e · Cited by 278 · see citing works
A review on synthesis and biomedical applications of polyglycolic acid
Budak, K., Sogut, O., & Sezer, Ü. A. (2020) · Journal of Polymer Research · doi:10.1007/s10965-020-02187-1 · Cited by 255 · see citing works
Bourissou, D., Moebs‐Sanchez, S., & Martín-Vaca, B. M. (2007) · Comptes Rendus Chimie · doi:10.1016/j.crci.2007.05.004 · Cited by 168 · see citing works
Self-citationMakiguchi, K., Ogasawara, Y., Kikuchi, S., Satoh, T., & Kakuchi, T. (2013) · Macromolecules · doi:10.1021/ma4000495 · Cited by 165 · see citing works
Gazeau-Bureau, S., Delcroix, D., Martín-Vaca, B., Bourissou, D., Navarro, C., & Magnet, S. (2008) · Macromolecules · doi:10.1021/ma800626q · Cited by 165 · see citing works
Self-citationJohn, G., Nagarajan, S., Vemula, P. K., Silverman, J. R., & Pillai, C. K. S. (2019) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2019.02.008 · Cited by 161 · see citing works
An Activated Equivalent of Lactide toward Organocatalytic Ring-Opening Polymerization
Boullay, O. T. D., Marchal, E., Martín-Vaca, B. M., Cossío, F. P., & Bourissou, D. (2006) · Journal of the American Chemical Society · doi:10.1021/ja067046y · Cited by 144 · see citing works
Self-citationDelcroix, D., Martín-Vaca, B. M., Bourissou, D., & Navarro, C. (2010) · Macromolecules · doi:10.1021/ma101461y · Cited by 134 · see citing works
Self-citationDelcroix, D., Couffin, A., Susperrégui, N., Navarro, C., Maron, L., Martín-Vaca, B. M., & Bourissou, D. (2011) · Polymer Chemistry · doi:10.1039/c1py00210d · Cited by 125 · see citing works
Self-citationBaśko, M., & Kubisa, P. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21712 · Cited by 122 · see citing works
Valderrama, M. A. M., van Putten, R., & Gruter, G. M. (2019) · European Polymer Journal · doi:10.1016/j.eurpolymj.2019.07.036 · Cited by 119 · see citing works
Organocatalytic ring-opening polymerization of l-lactide in bulk: A long standing challenge
Mezzasalma, L., Dove, A. P., & Coulembier, O. (2017) · European Polymer Journal · doi:10.1016/j.eurpolymj.2017.05.013 · Cited by 116 · see citing works
The influence of the functional end groups on the properties of polylactide-based materials
Kost, B., Baśko, M., Bednarek, M., Socka, M., Kopka, B., Łapienis, G., Biela, T., Kubisa, P., & Brzeziński, M. (2022) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2022.101556 · Cited by 115 · see citing works
Silvernail, C. M., Yao, L. J., Hill, L. M. R., Hillmyer, M. A., & Tolman, W. B. (2007) · Inorganic Chemistry · doi:10.1021/ic700581s · Cited by 113 · see citing works
Bonduelle, C. V., Martín-Vaca, B. M., Cossío, F. P., & Bourissou, D. (2008) · Chemistry - A European Journal · doi:10.1002/chem.200800346 · Cited by 110 · see citing works
Self-citationSusperrégui, N., Delcroix, D., Martín-Vaca, B. M., Bourissou, D., & Maron, L. (2010) · The Journal of Organic Chemistry · doi:10.1021/jo101346t · Cited by 107 · see citing works
Self-citationSingh, V., & Tiwari, M. (2010) · International Journal of Polymer Science · doi:10.1155/2010/652719 · Cited by 103 · see citing works
Syntheses of polylactides by means of tin catalysts
Kricheldorf, H. R., & Weidner, S. M. (2022) · Polymer Chemistry · doi:10.1039/d2py00092j · Cited by 105 · see citing works
Pascual, A., Sardón, H., Veloso, A., Ruipérez, F., & Mecerreyes, D. (2014) · ACS Macro Letters · doi:10.1021/mz500401u · Cited by 99 · see citing works
Kakuchi, R., Tsuji, Y., Chiba, K., Fuchise, K., Sakai, R., Satoh, T., & Kakuchi, T. (2010) · Macromolecules · doi:10.1021/ma100798u · Cited by 94 · see citing works
Zhao, J., Pahovnik, D., Gnanou, Y., & Hadjichristidis, N. (2014) · Macromolecules · doi:10.1021/ma500830v · Cited by 92 · see citing works
Homo- and heteroleptic zinc aminophenolates as initiators for lactide polymerization
Ejfler, J., Szafert, S., Mierzwicki, K., Jerzykiewicz, L. B., & Sobota, P. (2008) · Dalton Transactions · doi:10.1039/b808882a · Cited by 86 · see citing works
Acyclic Guanidines as Organic Catalysts for Living Polymerization of Lactide
Zhang, L., Pratt, R. C., Nederberg, F., Horn, H. W., Rice, J. E., Waymouth, R. M., Wade, C. G., & Hedrick, J. L. (2010) · Macromolecules · doi:10.1021/ma901776x · Cited by 85 · see citing works
Progress in Polymerization of Cyclic Esters: Mechanisms and Synthetic Applications
Biela, T., Kowalski, A., Libiszowski, J., Duda, A., & Penczek, S. (2006) · Macromolecular Symposia · doi:10.1002/masy.200650807 · Cited by 85 · see citing works
O-Carboxyanhydrides: Useful Tools for the Preparation of Well-Defined Functionalized Polyesters
Martín-Vaca, B. M., & Bourissou, D. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00376 · Cited by 84 · see citing works
Self-citationEngler, A. C., Chan, J. M. W., Coady, D. J., O’Brien, J. M., Sardón, H., Nelson, A., Sanders, D. P., Yang, Y. Y., & Hedrick, J. L. (2013) · Macromolecules · doi:10.1021/ma4001258 · Cited by 84 · see citing works
Kadota, J., Pavlović, D., Desvergne, J., Bibal, B., Peruch, F., & Deffieux, A. (2010) · Macromolecules · doi:10.1021/ma101688d · Cited by 82 · see citing works
Nomura, N., Taira, A., Nakase, A., Tomioka, T., & Okada, M. (2007) · Tetrahedron · doi:10.1016/j.tet.2007.05.073 · Cited by 81 · see citing works
Branched aliphatic polyesters by ring-opening (co)polymerization
Bednarek, M. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2016.02.002 · Cited by 79 · see citing works
Designing Polymer Electrolytes via Ring‐Opening Polymerization for Advanced Lithium Batteries
Wang, S., Zhang, L., Zeng, Q., Guan, J., Gao, H., Zhang, L., Jin, Z., Lai, W., & Wang, Q. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202302876 · Cited by 78 · see citing works
Shi, C., Guo, Y.-T., Wu, Y., Li, Z.-Y., Wang, Y.-Z., Du, F., & Li, Z. (2019) · Macromolecules · doi:10.1021/acs.macromol.8b02498 · Cited by 78 · see citing works
Skotak, M., Leonov, A. P., Larsen, G. F., Noriega, S. E., & Subramanian, A. (2008) · Biomacromolecules · doi:10.1021/bm800158c · Cited by 77 · see citing works
Poly(lactic acid) stereocomplexes based molecular architectures: Synthesis and crystallization
Michell, R. M., Ladelta, V., Da Silva, E., Müller, A. J., & Hadjichristidis, N. (2023) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2023.101742 · Cited by 77 · see citing works
Chile, L.-E., Mehrkhodavandi, P., & Hatzikiriakos, S. G. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02568 · Cited by 75 · see citing works
Ross, G. M., Ross, S., & Tighe, B. J. (2016) · Elsevier eBooks · doi:10.1016/b978-0-323-35824-8.00023-2 · Cited by 66 · see citing works
Makiguchi, K., Kikuchi, S., Yanai, K., Ogasawara, Y., Sato, S.-I., Satoh, T., & Kakuchi, T. (2014) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.27089 · Cited by 67 · see citing works
Cationic polymerization of L , L ‐lactide
Baśko, M., & Kubisa, P. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24048 · Cited by 65 · see citing works
Barker, I. A., & Dove, A. P. (2012) · Chemical Communications · doi:10.1039/c2cc38114a · Cited by 63 · see citing works
Couffin, A., Delcroix, D., Martín-Vaca, B. M., Bourissou, D., & Navarro, C. (2013) · Macromolecules · doi:10.1021/ma400916k · Cited by 62 · see citing works
Self-citationPenczek, S., & Pretula, J. (2021) · ACS Macro Letters · doi:10.1021/acsmacrolett.1c00509 · Cited by 62 · see citing works
Organocatalytic copolymerization of mixed type monomers
Song, Q.-L., Hu, S., Zhao, J., & Zhang, G. (2017) · Chinese Journal of Polymer Science · doi:10.1007/s10118-017-1925-6 · Cited by 58 · see citing works
Zhao, J., & Hadjichristidis, N. (2015) · Polymer Chemistry · doi:10.1039/c5py00019j · Cited by 57 · see citing works
Polyglycolic acid from the direct polymerization of renewable C1 feedstocks
Göktürk, E., Pemba, A. G., & Miller, S. A. (2015) · Polymer Chemistry · doi:10.1039/c5py00230c · Cited by 56 · see citing works
Kan, S., Jin, Y., He, X., Chen, J., Wu, H., Ouyang, P., Guo, K., & Li, Z. (2013) · Polymer Chemistry · doi:10.1039/c3py00667k · Cited by 56 · see citing works
Poly(α-hydroxy acid)s and poly(α-hydroxy acid-co-α-amino acid)s derived from amino acid
Basu, A., Kunduru, K. R., Katzhendler, J., & Domb, A. J. (2016) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2016.08.003 · Cited by 54 · see citing works
Air- and Moisture-Stable Indium Salan Catalysts for Living Multiblock PLA Formation in Air
Ebrahimi, T., Aluthge, D. C., Patrick, B. O., Hatzikiriakos, S. G., & Mehrkhodavandi, P. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01939 · Cited by 54 · see citing works
Mechanism of propagation in the cationic polymerization of L,L ‐lactide
Baśko, M., & Kubisa, P. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23074 · Cited by 54 · see citing works
Wang, X., Cui, S., Li, Z., Kan, S., Zhang, Q., Zhao, C., Wu, H., Liu, J., Wu, W., & Guo, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00773e · Cited by 52 · see citing works
Xia, Y., Chen, Y., Song, Q., Hu, S., Zhao, J., & Zhang, G. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b01542 · Cited by 52 · see citing works
Regulating cationic polymerization: From structural control to life cycle management
Wu, L., Rondon, B., Dym, S., Wang, W., Chen, K., & Niu, J. (2023) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2023.101736 · Cited by 49 · see citing works
Baśko, M., & Kubisa, P. (2007) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22065 · Cited by 50 · see citing works
Oshimura, M., Tang, T., & Takasu, A. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24539 · Cited by 48 · see citing works
Pascual, A., Leiza, J. R., & Mecerreyes, D. (2013) · European Polymer Journal · doi:10.1016/j.eurpolymj.2013.02.009 · Cited by 46 · see citing works
Prasad, A., Stubbs, L., Ma, Z., & Zhu, Y.-H. (2012) · Journal of Applied Polymer Science · doi:10.1002/app.34494 · Cited by 41 · see citing works
Makiguchi, K., Kikuchi, S., Satoh, T., & Kakuchi, T. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26631 · Cited by 44 · see citing works
Alba, A., Schopp, A., Delgado, A. D. S., Cherif‐Cheikh, R., Martín-Vaca, B. M., & Bourissou, D. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23852 · Cited by 43 · see citing works
Self-citationJones, G. O., Chang, Y. A., Horn, H. W., Acharya, A. K., Rice, J. E., Hedrick, J. L., & Waymouth, R. M. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b01595 · Cited by 42 · see citing works
Synthetic approaches to uniform polymers☆
Ali, M. S., & Brocchini, S. (2006) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2006.10.002 · Cited by 41 · see citing works
Couffin, A., Martín-Vaca, B. M., Bourissou, D., & Navarro, C. (2013) · Polymer Chemistry · doi:10.1039/c3py00935a · Cited by 41 · see citing works
Self-citationMiao, Y., Phuphuak, Y., Rousseau, C., Bousquet, T., Mortreux, A., Chirachanchai, S., & Zinck, P. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26612 · Cited by 41 · see citing works
Zhao, J., Pahovnik, D., Gnanou, Y., & Hadjichristidis, N. (2014) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27332 · Cited by 39 · see citing works
Mechanical Recycling of PLA Filled with a High Level of Cellulose Fibres
Åkesson, D., Vrignaud, T., Tissot, C., & Skrifvars, M. (2016) · Journal of Polymers and the Environment · doi:10.1007/s10924-016-0760-0 · Cited by 38 · see citing works
Catalytic Systems for the Production of Poly(lactic acid)
Byers, J. A., Biernesser, A. B., Chiaie, K. R. D., Kaur, A., & Kehl, J. A. (2017) · Advances in polymer science · doi:10.1007/12_2017_20 · Cited by 39 · see citing works
Mezzasalma, L., Winter, J. D., Taton, D., & Coulembier, O. (2018) · Green Chemistry · doi:10.1039/c8gc03096k · Cited by 38 · see citing works
Jehanno, C., Mezzasalma, L., Sardón, H., Ruipérez, F., Coulembier, O., & Taton, D. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01853 · Cited by 38 · see citing works
Microspheres from stereocomplexes of polylactides containing ionic liquid end‐groups
Biedroń, T., Brzeziński, M., Biela, T., & Kubisa, P. (2012) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26266 · Cited by 36 · see citing works
Kałużyński, K., Pretula, J., Lewiński, P., Kaźmierski, S., & Penczek, S. (2022) · Macromolecules · doi:10.1021/acs.macromol.1c02325 · Cited by 36 · see citing works
Organocatalyzed Ring-Opening Polymerizations
Fevre, M., Vignolle, J., Gnanou, Y., & Taton, D. (2012) · Elsevier eBooks · doi:10.1016/b978-0-444-53349-4.00119-9 · Cited by 36 · see citing works
Gowda, R. R., Chakraborty, D., & Ramkumar, V. (2009) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200900280 · Cited by 36 · see citing works
Acid-catalyzed Ring-opening Polymerization of γ-Butyrolactone under High-pressure Conditions
Yamashita, K., Yamamoto, K., & Kadokawa, J. (2013) · Chemistry Letters · doi:10.1246/cl.130952 · Cited by 36 · see citing works
Dong, H., Zhu, Y., Li, Z., Xu, J., Liu, J., Xu, S., Wang, H., Gao, Y. M., & Guo, K. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01784 · Cited by 35 · see citing works
Baśko, M., Duda, A., Kaźmierski, S., & Kubisa, P. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26916 · Cited by 34 · see citing works
He, X., Ji, Y., Jin, Y., Kan, S., Xia, H., Chen, J., Liang, B., Wu, H., Guo, K., & Li, Z. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27082 · Cited by 34 · see citing works
Time‐Resolved Diffusion NMR Measurements for Transient Processes
MacDonald, T. S. C., Price, W. S., & Beves, J. E. (2019) · ChemPhysChem · doi:10.1002/cphc.201900150 · Cited by 34 · see citing works
Stereoretention in the Bulk ROP of l -Lactide Guided by a Thermally Stable Organocatalyst
Basterretxea, A., Gabirondo, E., Jehanno, C., Zhu, H., Coulembier, O., Mecerreyes, D., & Sardón, H. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c01060 · Cited by 34 · see citing works
Alba, A., Boullay, O. T. D., Martín-Vaca, B. M., & Bourissou, D. (2014) · Polymer Chemistry · doi:10.1039/c4py00973h · Cited by 34 · see citing works
Self-citationControlled ring-opening polymerization of cyclic esters with phosphoric acid as catalysts
Zhou, X. C., & Hong, L. (2013) · Colloid & Polymer Science · doi:10.1007/s00396-013-2950-9 · Cited by 32 · see citing works
Tripodal hydrogen bond donor binding with sulfonic acid enables ring-opening polymerization
Li, X., Zhang, Q., Li, Z., Xu, S., Zhao, C., Chen, C., Zhi, X., Wang, H., Zhu, N., & Guo, K. (2016) · Polymer Chemistry · doi:10.1039/c5py01931a · Cited by 32 · see citing works
Kricheldorf, H. R., & Weidner, S. M. (2021) · Journal of Polymer Science · doi:10.1002/pol.20200866 · Cited by 32 · see citing works
Han, H., Wang, X., & Wu, D. (2012) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2012.06.014 · Cited by 32 · see citing works
Polymer – Ionic liquid – Pharmaceutical conjugates as drug delivery systems
Halayqa, M., Zawadzki, M., Domańska, U., & Plichta, A. (2018) · Journal of Molecular Structure · doi:10.1016/j.molstruc.2018.12.023 · Cited by 32 · see citing works
Nguyen, Q. V., Nomura, S., Hoshino, R., Ninomiya, K., Takada, K., Kakuchi, R., & Takahashi, K. (2017) · Polymer Journal · doi:10.1038/pj.2017.49 · Cited by 30 · see citing works
Recent advances in biodegradable polymeric materials
Pillai, C. (2014) · Materials Science and Technology · doi:10.1179/1743284713y.0000000472 · Cited by 19 · see citing works
Couffin, A., Boullay, O. T. D., Vedrenne, M., Navarro, C., Martín-Vaca, B. M., & Bourissou, D. (2014) · Chemical Communications · doi:10.1039/c4cc00466c · Cited by 28 · see citing works
Self-citationWojtczak, E., Kubisa, P., & Bednarek, M. (2018) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2018.03.003 · Cited by 27 · see citing works
Attandoh, N. W., Ojwach, S. O., & Munro, O. Q. (2014) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201402049 · Cited by 27 · see citing works
Carbonylative Polymerization of Oxetanes Initiated by Acetyl Cobalt Complexes
Permana, Y., Nakano, K., Yamashita, M., Watanabe, D., & Nozaki, K. (2008) · Chemistry - An Asian Journal · doi:10.1002/asia.200700339 · Cited by 26 · see citing works
Kost, B., & Baśko, M. (2021) · Polymer Chemistry · doi:10.1039/d1py00358e · Cited by 26 · see citing works
Makiguchi, K., Satoh, T., & Kakuchi, T. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24815 · Cited by 25 · see citing works
- Authors
- Bourissou, D., Martin-Vaca, B., Dumitrescu, A., Graullier, M., & Lacombe, F.
- Affiliations
- Université Toulouse III - Paul Sabatier (FR)
- Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), Université Paul Sabatier, 118 route de Narbonne, F-31062 Toulouse Cedex 9, France, and Ipsen Pharma, Ctra. Laureà Miró 395, E-08980 Sant Feliu de Llobregat, Spain
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-01
- Volume
- 38
- Issue
- 24
- Pages
- 9993-9998
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2068119802
- Cited by
- 226
- References
- 17
- Citations by year
- 2026: 5 · 2025: 3 · 2024: 8 · 2023: 6 · 2022: 7 · 2021: 13 · 2020: 10 · 2019: 16 · 2018: 13 · 2017: 21 · 2016: 12 · 2015: 10 · 2014: 16 · 2013: 24 · 2012: 11
- FWCI
- 3.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- HAL (submittedVersion)
- International Journal of Biological Macromolecules
- Funders
- Centre National de la Recherche Scientifique
- Ipsen
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
- Keywords
- cationic polymerization, lactide, polylactic acid, trifluoromethanesulfonic acid, activated monomer mechanism, controlled polymerization, polymerization kinetics, epimerization, stereoselectivity, transesterification
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review