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Oxidative upgrade of lignin – Recent routes reviewed

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Lange, Heiko, Decina, Silvia, Crestini, Claudia·2013·European Polymer Journal
DOI 10.1016/j.eurpolymj.2013.03.002
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Abstract

Lignin is the second most abundant natural polymer. Its use and targeted functionalisation within biomass refinery processes, however, still needs to be further explored and developed. The oxidative functionalisation, and thus valorisation of lignin, is a very promising way to go, since it holds the possibilities to yield highly functionalised, monomeric or oligomeric products that can serve as starting materials for other valorisation processes in the chemical and pharmaceutical industries. Gaining a profound knowledge about the structure of lignin, being able to analyse structural features, and understanding the mechanisms that guide the reactions leading to the oxidative derivatisation, depolymerisation and functionalisation of lignin samples from different renewable sources are key requirements for developing successful valorisation protocols for lignin. In this review, we wish to revisit, and set into context, some important achievements in the field of oxidatively upgrading lignin. We will focus on organometal catalyses (MTO, salen complexes, POMs), biomimetic catalyses (porphyrins), and enzymatic catalyses (laccase, peroxidase) for upgrading lignin and lignin model compounds. Details of mechanistic implications and means of potential manipulations of reaction outcomes are discussed.

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Cited by

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Metadata

Authors
Lange, H., Decina, S., & Crestini, C.
Venue
European Polymer Journal
Publisher
Elsevier BV
Published
2013-06
Volume
49
Issue
6
Pages
1151-1173
ISSN
0014-3057 (ISSN-L)
DOI
10.1016/j.eurpolymj.2013.03.002
OpenAlex
W2023878189
Cited by
473
References
6
FWCI
17.89
Type
journal article
Language
en
Open access
hybrid
Licence

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CoChat. (2026). Citation check: Oxidative upgrade of lignin – Recent routes reviewed. https://app.cochat.ai/papers/10.1016/j.eurpolymj.2013.03.002
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Lange, H., Decina, S., & Crestini, C. (2013). Oxidative upgrade of lignin – Recent routes reviewed. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2013.03.002

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