Equilibrium isotopic fractionation and isotopic exchange kinetics between Cr(III) and Cr(VI)
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Because Cr(III)-Cr(VI) isotopic exchange is slow at Earth-surface conditions, low-temperature Cr isotope behavior is likely dominated by kinetic fractionations from partial Cr(VI) reduction.
“due to the long timescales of isotopic exchange between Cr(III) and Cr(VI) under Earth-surface conditions (e.g., Wang et al., 2015), the isotope systematics of low-temperature Cr cycling are likely to be dominated by kinetic fractionations associated with partial Cr(VI) reduction.”
From The chromium isotope composition of reducing and oxic marine sediments (2016) · cites this paper as Wang et al., 2015
The isotopic composition of natural Cr species is mainly controlled by redox state changes, with large fractionations expected for equilibrium Cr(III)-Cr(VI) exchange and incomplete Cr(VI) reduction.
“the isotopic composition of natural Cr species is governed principally by shifts in redox state -with significant isotopic fractionations expected for both equilibrium exchange between Cr(III) and Cr(VI) species and incomplete reduction of Cr(VI) to Cr(III)”
From The chromium isotope composition of reducing and oxic marine sediments (2016) · cites this paper as Wang et al., 2015
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The chromium isotope composition of reducing and oxic marine sediments
Gueguen, B., Reinhard, C. T., Algeo, T. J., Peterson, L. C., Nielsen, S. G., Wang, X., Rowe, H., & Planavsky, N. J. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.04.004 · Cited by 106 · see citing works
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Self-citationZheng, X.-Y., Beard, B. L., Reddy, T. R., Roden, E. E., & Johnson, C. M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.05.012 · Cited by 81 · see citing works
- Authors
- Wang, X., Johnson, T. M., & Ellis, A. S.
- Affiliations
- University of Illinois Urbana-Champaign (US)
- California State University Los Angeles (US)
- Corresponding author
- Wang, Xiangli
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-03
- Volume
- 153
- Pages
- 72-90
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2008995300
- Cited by
- 74
- References
- 67
- Citations by year
- 2026: 3 · 2025: 2 · 2024: 1 · 2023: 4 · 2022: 8 · 2021: 6 · 2020: 6 · 2019: 9 · 2018: 10 · 2017: 10 · 2016: 12 · 2015: 3
- FWCI
- 7.30
- Type
- journal article
- Language
- en
- Update notices
- erratum (2015-08-15)
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- Funders
- National Science Foundation (EAR 08-43631)
- Topics
- Physical Sciences › Environmental Science › Health, Toxicology and Mutagenesis › Chromium effects and bioremediation
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Keywords
- chromium isotopes, trivalent chromium, hexavalent chromium, chromium(V), isotope fractionation, isotope exchange kinetics, redox equilibria, chromate, chromium oxyhydroxide, adsorption, electron transfer, chromium speciation, uranium-contaminated groundwater, chromium-53, chromium-52, chromium-50
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