The DOI matches its Crossref record; 134 of the 135 references it cites were found in a registry or an index.
Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition
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“This means that in extreme pH environments (such as where [CO 3 2-] is dominant, pH > 9.5), shifts in the chemical and isotopic equilibrium of the H 2 O-DIC-CaCO 3 system cause carbonates to follow a different equilibrium Ti relationship (Tripati et al. 2015, Watkins & Hunt 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
In the citing paper
“Equilibrium clumped isotopic compositions of the DIC species depend on temperature, but at a given temperature fewer clumped isotopologues are found in CO 3 2-than in HCO 3 -or H 2 CO 3 (Hill et al. 2014, Tripati et al. 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
In the citing paper
“Mineral precipitation occurring over a period of months removes the possibility of any pH-related disequilibrium effect being recorded in carbonate clumped isotope values (Hill et al., 2014;Kluge et al., 2018;Tripati et al., 2015).”
From Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes (2024) · cites this paper as Tripati et al., 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
In the citing paper
“Deviations from this curve can suggest some kind of disequilibrium in the sample (see Tripati et al. 2015 for further discussion).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
In the citing paper
“Paired measurements of ∆ 63 and ∆ 64 can provide constraints on which processes shape observed isotopic signatures in experimental samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
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In the citing paper
“Recently we hypothesized that solution chemistry may be an important factor influencing mineral clumped isotope signatures if a crystal precipitates too rapidly to achieve thermodynamic mineral lattice equilibrium (Tripati et al., 2010, 2015; Hill et al., 2014).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“we showed that at a given temperature, individual DIC species have distinct clumped isotope signatures”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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In the citing paper
“and impact the Δ 63 of the composite DIC pool and potentially measured carbonate mineral Δ 47 values.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
The cited source says what the claim attributes to it.
In the citing paper
“Kinetics will also have an effect on such fractionation (e.g., Hill et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Guo, 2019), but is beyond the scope of the present study.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
The cited source says what the claim attributes to it.
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“However, a disagreement between the magnitude of predicted changes from theory and observations has been reported in other studies (e.g., Guo et al., 2009; Tripati et al., 2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
The cited source says what the claim attributes to it.
In the citing paper
“Paired measurements of Δ 47 and Δ 48 can provide constraints on what processes shape observed isotopic signatures in samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
The cited source says what the claim attributes to it.
In the citing paper
“Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tripati et al., 2015
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Citations
Cites
On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
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1 of the 135 references couldn’t be matched to a known paper.
Research works printed but not linked: 3
- Guo, W., Kim, S.-T., Yuan, J., Farquhar, J., Passey, B. (2012) 13C–18O bonds in dissolved inorganic carbon: toward a better understanding of clumped isotope thermometer in biogenic carbonates. In 22nd Annual V.M. Goldschmidt Conference, Montreal, Canada.
- Kimball J. B., Tripati A., Dunbar, R. B., and Eagle, R. (2013). 13C–18O bonding (Δ47) in deep-sea corals: a calibration study. In AGU Fall Meeting Abstracts. Vol. 1, p. 1935.
- Usdowski, 1991, Factors for the oxygen isotope equilibrium fractionation between aqueous and gaseous CO2, carbonic acid, bicarbonate, carbonate, and water (19°C), Zeitsch. Phys. Chem., 170, 237
Cited by
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Items 101–139 of 139
Jautzy, J., Savard, M. M., Larmagnat, S., Fosu, B., & Campbell, C. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.05.023 · Cited by 3
Quizon, A. A., Petersen, S., de Winter, N. J., & Vellekoop, J. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.10.023 · Cited by 4
Mentzer, C., Garzione, C. N., Jaramillo, C. A., Hinojosa, L. F., Escobar, J. H., Glade, N., Gómez, S., Upadhyay, D., Tripati, A., & Thirumalai, K. (2024) · Global and Planetary Change · doi:10.1016/j.gloplacha.2024.104674 · Cited by 7
Self-citationHavranek, R., Snell, K. E., Brookins, S., & Davidheiser‐Kroll, B. (2025) · Paleoceanography and Paleoclimatology · doi:10.1029/2024pa005071 · Cited by 4
“…the ONG site is that cracking of the soil from the shrinking of 2:1 clays caused rapid soil CO 2 degassing, which in turn caused pedogenic carbonate to form out of isotopic equilibrium with the DIC pool, creating anomalously high T(Δ 47 ) and δ 18 O w (Affek & Zaarur, 2014; Tripati et al., 2015).”
Substantial continental temperature rise over the Paleocene-Eocene Thermal Maximum in the Pyrenees
Újvári, G., Kele, S., Rinyu, L., Payros, A., Stadelmaier, K. H., Kovács, J., Kovács, I., Bajnóczi, B., Pujalte, V., Schmitz, B., et al. (2025) · Communications Earth & Environment · doi:10.1038/s43247-025-02479-8 · Cited by 4
“…which is the dominant reaction at typical soil pH levels during carbonate precipitation, may often result in disequilibrium isotope signatures with 13 C and 18 O enrichment and lower Δ 47 values in calcite relative to the expected equilibrium isotope composition 44,62,63 .”
Taha, T. M., & Abdullah, E. J. (2019) · Iraqi Journal of Science · doi:10.24996/ijs.2019.60.8.10 · Cited by 4
“, thermodynamic equilibrium for a mineral, which is independent of solution chemistry), several factors are other than temperature, including dissolved inorganic carbon (DIC) speciation may influence mineral isotopic signatures [28].”
BackgroundExperimental Constraints on Clumped Isotope Fractionation During BaCO3 Precipitation
Guo, Y., Deng, W., & Wei, G. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010249 · Cited by 4
“003) is similar to that for pH-driven isotopic disequilibrium determined experimentally (Tripati et al., 2015).”
BackgroundResultInfluentialComparative clumped isotope temperature relationships in freshwater carbonates
Arnold, A., Mering, J., Chari, L., Román‐Palacios, C., Li, H., Petrys, H., Mitsunaga, B., Elliott, B., Wilson, J., Lucarelli, J., et al. (2025) · The Depositional Record · doi:10.1002/dep2.312 · Cited by 4
“…4B shows biologically mediated carbonates and travertines show a positive offset from the 1:1 line, overestimating δ 18 O water relative to the measured value, that may also arise from pH-related effects on isotopic fractionation or kinetic isotope effects (Beck et al., 2005; Tripati et al., 2015).”
InfluentialSelf-citationPietzsch, R. (2021) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2021.104963 · Cited by 4
Condensation Corrosion Speleogenesis in the Amargosa Desert and the Tecopa Basin
Dublyansky, Y. V., Klenke, J., & Spötl, C. (2017) · Cave and karst systems of the world · doi:10.1007/978-3-319-53348-3_35 · Cited by 3
The Application of Clumped Isotopes to Dolomites
Murray, S. T. (2016) · Cited by 3
Carbonate clumped isotope (Δ47) thermometry andits application in paleoelevation reconstruction
Xiong, Z., Ding, L., & Xie, J. (2019) · Chinese Science Bulletin (Chinese Version) · doi:10.1360/n972019-00032 · Cited by 3
McIntosh, J. A., Tabor, N. J., & Montañez, I. P. (2025) · Chemical Geology · doi:10.1016/j.chemgeo.2025.122941 · Cited by 3
Banerjee, S., & Ghosh, P. (2023) · Applied Geochemistry · doi:10.1016/j.apgeochem.2023.105809 · Cited by 3
Kapcsolt izotópok (clumped isotopes) a földtudományi kutatásokban
Kele, S., & Bajnai, D. (2017) · Földtani Közlöny · doi:10.23928/foldt.kozl.2017.147.2.177 · Cited by 2
Shang, F. (2016) · doi:10.33915/etd.6615 · Cited by 2
“Recent development of carbonate clumped-isotope thermometry provides an innovative technique that holds potential for reconstruction of carbonate-formation temperatures over a range of timescales (e.g., Dennis et al., 2013; Eagle et al., 2013; Eiler, 2011; Fan et al., 2014; Garzione et al., 2014; Hough et al., 2014; H…”
BackgroundLucarelli, J., Carroll, H. M., Elliott, B. M., Eagle, R. A., & Tripati, A. (2021) · doi:10.31223/x5t318 · Cited by 2
Self-citationHelten, O., Bach, W., Hinrichs, K., & Ostertag-Henning, C. (2024) · Applied Geochemistry · doi:10.1016/j.apgeochem.2024.106147 · Cited by 1
Oligocene deep ocean oxygen isotope variations primarily driven by temperature
Boscolo‐Galazzo, F., Taylor, V., Galaasen, E. V., Liebrand, D., Gasson, E. G. W., Dallanave, E., Fernández, Á., Witkowski, J., Bohaty, S. M., & Meckler, A. N. (2026) · Nature Geoscience · doi:10.1038/s41561-025-01878-y · Cited by 1
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Lucarelli, J., Purgstaller, B., Parven, Z., Watkins, J. M., Eagle, R. A., Dietzel, M., & Tripati, A. (2022) · doi:10.31223/x5ns7w · Cited by 1
Self-citationBayClump: Bayesian Calibration and Temperature Reconstructions for Clumped Isotope ThermometryPreprint
Román‐Palacios, C., Carroll, H. M., Arnold, A., Gan, Q., & Tripati, A. (2022) · doi:10.1002/essoar.10507995.2 · Cited by 1
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Padgett, A. B., Hyland, E. G., West, C. K., Burgener, L., Greenwood, D. R., & Basinger, J. F. (2023) · Paleoceanography and Paleoclimatology · doi:10.1029/2023pa004609 · Cited by 1
“These cryogenic kinetic isotope effects result in positive δ 18 O and δ 13 C anomalies and negative Δ 47 anomalies (e.g., higher apparent carbonate formation temperatures; Burgener et al., 2018; Tripati et al., 2015).”
BackgroundCLUMPED ISOTOPE THERMOMETRY AND ITS APPLICATION IN GEOSCIENCE RESEARCH
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Self-citationLucarelli, J., Purgstaller, B., Parvez, Z., Watkins, J. M., Eagle, R. A., Dietzel, M., & Tripati, A. (2025) · Geochemistry Geophysics Geosystems · doi:10.1029/2025gc012202
“However, the dual measurement of Δ 47 and Δ 48 has been theoretically (Guo, 2020; Hill et al., 2014, 2020; Tripati et al., 2015) and experimentally (Bajnai et al., 2020; Fiebig et al., 2019, 2021; Lucarelli, Carroll, et al., 2023; Swart et al., 2021) shown to have a characteristic equilibrium…”
InfluentialSelf-citationGorin, A. L., Kahanamoku, S. S., Finnegan, S., & Stolper, D. A. (2026) · Paleoceanography and Paleoclimatology · doi:10.1029/2025pa005195
“…both of these isotopic systems are sensitive to kinetic processes associated with carbonate formation (e.g., Bajnai et al., 2020; Guo, 2020; Tripati et al., 2015; Watkins & Devriendt, 2022) and to later diagenetic alteration during marine burial (Killingley, 1983; Pearson et al., 2001;…”
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Metadata
- Authors
- Tripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., Ries, J. B., & Henry, D.
- Affiliations
- California Institute of Technology (US)
- University of California, Los Angeles (US)
- University of Minnesota (US)
- University of Hawaiʻi at Mānoa (US)
- United States Geological Survey (US)
- Northeastern University (US)
- Corresponding author
- Tripati, Aradhna K.
- ORCID
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-10
- Volume
- 166
- Pages
- 344-371
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1823013860
- Cited by
- 139
- References
- 135
- Citations by year
- 2026: 5 · 2025: 10 · 2024: 9 · 2023: 16 · 2022: 12 · 2021: 19 · 2020: 10 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 16 · 2015: 2
- FWCI
- 16.83
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Geochimica et Cosmochimica Acta (acceptedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- NOAA Institutional Repository (submittedVersion, public-domain)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- National Science Foundation (EAR-1325054, ARC-1215551, EAR-0949191)
- National Oceanic and Atmospheric Administration (NA13OAR4310186)
- University of California, Los Angeles
- American Chemical Society (51182-DNI2, OCE-1437166, OCE09-27089, OCE-1357665)
- Basic Energy Sciences (DE-FG02-13ER16402)
- U.S. Department of Energy
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- clumped isotope thermometry, calcite, carbonic anhydrase, oxygen isotope exchange, coral calcification
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