Beyond temperature: clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition
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In extreme pH environments where [CO3 2-] is dominant (pH > 9.5), shifts in chemical and isotopic equilibrium of the H2O-DIC-CaCO3 system cause carbonates to follow a different equilibrium TΔi relationship.
“This means that in extreme pH environments (such as where [CO 3 2-] is dominant, pH > 9.5), shifts in the chemical and isotopic equilibrium of the H 2 O-DIC-CaCO 3 system cause carbonates to follow a different equilibrium Ti relationship (Tripati et al. 2015, Watkins & Hunt 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Section 3.2 says pH changes the equilibrium isotopic composition of the DIC pool, and the Abstract says rapidly growing carbonates may record a DIC species’ signature. But section 3.2 explicitly says equilibrium mineral compositions depend on temperature, not pH. The claim omits the rapid-growth qualification and incorrectly presents the resulting carbonate signature as a different mineral equilibrium temperature relationship; section 2.2.1 also places roughly equal bicarbonate and carbonate concentrations at pH 10.2, rather than carbonate dominance throughout pH > 9.5. (LLM, conf=0.86)
Experimental — accuracy not yet measuredEquilibrium clumped isotopic compositions of DIC species depend on temperature, but at a given temperature fewer clumped isotopologues are found in CO3 2- than in HCO3- or H2CO3.
“Equilibrium clumped isotopic compositions of the DIC species depend on temperature, but at a given temperature fewer clumped isotopologues are found in CO 3 2-than in HCO 3 -or H 2 CO 3 (Hill et al. 2014, Tripati et al. 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Section 3.1.3.1 says equilibrium clumped-isotope compositions of DIC species vary with temperature, and the Fig. 4 description reports that CO3²⁻ has a lower value than HCO3⁻ at a given temperature. The passages in our copy do not establish the comparison with H2CO3, so that part of the sentence is not supported by this source. (LLM, conf=0.88)
Experimental — accuracy not yet measuredMineral precipitation occurring over a period of months removes the possibility of any pH-related disequilibrium effect being recorded in carbonate clumped isotope values.
“Mineral precipitation occurring over a period of months removes the possibility of any pH-related disequilibrium effect being recorded in carbonate clumped isotope values (Hill et al., 2014;Kluge et al., 2018;Tripati et al., 2015).”
From Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes (2024) · cites this paper as Tripati et al., 2015
Section 4.3 says that carbonate minerals growing slowly enough to reach lattice equilibrium have clumped-isotope values independent of solution chemistry, including pH. But Section 4.2 says the growth-rate threshold depends on mineral-growth conditions; the paper does not establish that precipitation over months necessarily eliminates pH-related disequilibrium. (LLM, conf=0.87)
Experimental — accuracy not yet measuredDeviations from the equilibrium ∆63 vs. ∆64 curve can suggest some kind of disequilibrium in the sample.
“Deviations from this curve can suggest some kind of disequilibrium in the sample (see Tripati et al. 2015 for further discussion).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. 2015
Section 1.1 says disequilibrium Δ63 values may be recorded by carbonate minerals, and the equilibrium-prediction tables list both Δ63 and Δ64 values. However, our copy does not discuss deviations from a Δ63-versus-Δ64 equilibrium curve as a diagnostic of disequilibrium. (LLM, conf=0.76)
Experimental — accuracy not yet measuredPaired measurements of ∆63 and ∆64 can provide constraints on which processes shape observed isotopic signatures in experimental samples.
“Paired measurements of ∆ 63 and ∆ 64 can provide constraints on which processes shape observed isotopic signatures in experimental samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
Section 4.3.2 proposes that coupled clumped-isotope measurements may help identify disequilibrium processes, supporting the general idea. But it specifies Δ47, Δ48, and Δ49 in field-collected carbonate minerals, not paired Δ63 and Δ64 measurements in experimental samples. Section 2.1 defines Δ63 and Δ64 but does not propose that pairing. (LLM, conf=0.86)
Experimental — accuracy not yet measured
Solution chemistry may be an important factor influencing mineral clumped isotope signatures if a crystal precipitates too rapidly to achieve thermodynamic mineral lattice equilibrium.
“Recently we hypothesized that solution chemistry may be an important factor influencing mineral clumped isotope signatures if a crystal precipitates too rapidly to achieve thermodynamic mineral lattice equilibrium (Tripati et al., 2010, 2015; Hill et al., 2014).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
At a given temperature, individual DIC species have distinct clumped isotope signatures.
“we showed that at a given temperature, individual DIC species have distinct clumped isotope signatures”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
Individual DIC species impact the Δ63 of the composite DIC pool and potentially measured carbonate mineral Δ47 values.
“and impact the Δ 63 of the composite DIC pool and potentially measured carbonate mineral Δ 47 values.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
Kinetics will also have an effect on isotopic fractionation of carbonates.
“Kinetics will also have an effect on such fractionation (e.g., Hill et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Guo, 2019), but is beyond the scope of the present study.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
A disagreement between the magnitude of predicted changes from theory and observations has been reported in other studies.
“However, a disagreement between the magnitude of predicted changes from theory and observations has been reported in other studies (e.g., Guo et al., 2009; Tripati et al., 2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
Paired measurements of Δ47 and Δ48 can provide constraints on what processes shape observed isotopic signatures in samples.
“Paired measurements of Δ 47 and Δ 48 can provide constraints on what processes shape observed isotopic signatures in samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 and natural travertines at pH 5.6-9.
“Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tripati et al., 2015
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Carbonate clumped isotope thermometry of deep-sea corals and implications for vital effects
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Self-citationBody temperatures of modern and extinct vertebrates from 13C-18O bond abundances in bioapatite
Eagle, R., Schauble, E., Tripati, A., Tütken, T., Hulbert, R., & Eiler, J. (2010) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.0911115107 · Cited by 158 · see citing works
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“Clumped isotope thermometry has emerged as a powerful tool in the geosciences (Ghosh et al., 2006; Came et al., 2007; Eagle et al., 2010, 2011,2013a,b; Passey et al., 2010; Csank et al., 2011; Loyd et al., 2012, 2013; Tripati et al., 2010, 2014).”
Self-citationHill, P. S., Tripati, A. K., & Schauble, E. A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.06.018 · Cited by 155 · see citing works
Self-citationCalcite growth kinetics: Modeling the effect of solution stoichiometry
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“It is debated whether these isotopic signatures originate from kinetic effects associated with CO2 hydrolysis due to different isotopologues of CO2 reacting at variable rates (McConnaughey, 1989; Saenger et al., 2012), or from pH effects on the stable isotope composition of the DIC pool (Adkins et al.”
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Self-citationCalcite (1 0 4)–water interface structure, revisited
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Devils Hole, Nevada, δ18O record extended to the mid-Holocene
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Quantifying kinetic fractionation in Bunker Cave speleothems using Δ47
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Estimates of Arctic land surface temperatures during the early Pliocene from two novel proxies
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Self-citationSpontaneous movement of ions through calcite at standard temperature and pressure
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Self-citationClumped isotopic equilibrium and the rate of isotope exchange between CO2 and water
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Self-citationDevils Hole paleotemperatures and implications for oxygen isotope equilibrium fractionation
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Self-citationOxygen grain boundary diffusion in natural and hot-pressed calcite aggregates
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Proton/calcium ion exchange behavior of calcite
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Diffusion of C and O in calcite from 0.1 to 200 MPa
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An experimental study of the diffusion of C and O in calcite in mixed CO2-H2O fluid
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Self-citationData from Devils Hole Core DH-11
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Interaction of BaCl 2 and BaCO 3 at Elevated Temperatures
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Cited by
Sorted by citations
Hollis, C. J., Jones, T. D., Anagnostou, E., Bijl, P. K., Cramwinckel, M. J., Cui, Y., Dickens, G. R., Edgar, K. M., Eley, Y. L., Evans, D., et al. (2019) · Geoscientific model development · doi:10.5194/gmd-12-3149-2019 · Cited by 268 · see citing works
“, 2006); (2) the technique involves the simultaneous measurement of Δ47 and δ18O, enabling the independent and direct calculation of ancient δ(18)Osw; (3) many biogenic carbonates and inorganic precipitates fall on the same calibration line, suggesting the absence of measurable ‘vital effects’ (e.g. Ghosh et al., 2006…”
MethodSelf-citationMost Earth-surface calcites precipitate out of isotopic equilibrium
Daëron, M., Drysdale, R. N., Peral, M., Huyghe, D., Blamart, D., Coplen, T. B., Lartaud, F., & Zanchetta, G. (2019) · Nature Communications · doi:10.1038/s41467-019-08336-5 · Cited by 236 · see citing works
Self-citationPetersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., et al. (2019) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2018gc008127 · Cited by 209 · see citing works
“However, a few studies have found mineralogy ‐ speci fi c behavior in Δ 47 (van Dijk et al., 2019; Müller et al., 2017; Murray et al., 2016; Tripati et al., 2015), such as 10.1029/2018GC008127 Geochemistry, Geophysics, Geosystems Müller et al. (2017) who found a measurable difference on the order of…”
InfluentialSelf-citationKelson, J. R., Huntington, K. W., Schauer, A. J., Saenger, C., & Lechler, A. R. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.010 · Cited by 177 · see citing works
Lunt, D. J., Huber, M. S., Anagnostou, E., Baatsen, M., Caballero, R., Deconto, R. M., Dijkstra, H. A., Yannick Donnadieu, A., Evans, D., Feng, R., et al. (2017) · Geoscientific model development · doi:10.5194/gmd-10-889-2017 · Cited by 169 · see citing works
Self-citationA robust calibration of the clumped isotopes to temperature relationship for foraminifers
Meinicke, N., Ho, S. L., Hannisdal, B., Nürnberg, D., Tripati, A., Schiebel, R., & Meckler, A. N. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.11.022 · Cited by 121 · see citing works
Self-citationOxygen isotope composition of the Phanerozoic ocean and a possible solution to the dolomite problem
Ryb, U., & Eiler, J. M. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1719681115 · Cited by 129 · see citing works
“Such compositions appear to be the product of rapid carbonate growth where CO2 outgassing or hydration/hydroxylation are rate-limiting processes (40, 41, 44, 45).”
BackgroundSelf-citationUpdated calibration of the clumped isotope thermometer in planktonic and benthic foraminifera
Peral, M., Daëron, M., Blamart, D., Bassinot, F., Dewilde, F., Smialkowski, N., Isguder, G., Bonnin, J., Jorissen, F., Kissel, C., et al. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.016 · Cited by 113 · see citing works
Dual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures
Bajnai, D., Guo, W., Spötl, C., Coplen, T. B., Methner, K., Löffler, N., Krsnik, E., Gischler, E., Hansen, M., Henkel, D., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-17501-0 · Cited by 147 · see citing works
Self-citationGuo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108 · see citing works
A process-based model for non-equilibrium clumped isotope effects in carbonates
Watkins, J. M., & Hunt, J. D. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.09.042 · Cited by 105 · see citing works
“28 (acid digestion at 25 ◦C; Tripati et al., 2015) for the comparison to experimental data.”
BackgroundMethodResultInfluentialCalibration of the dual clumped isotope thermometer for carbonates
Fiebig, J., Daëron, M., Bernecker, M., Guo, W., Schneider, G., Boch, R., Bernasconi, S. M., Jautzy, J., & Dietzel, M. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.07.012 · Cited by 110 · see citing works
Fernandez, A., Müller, I. A., Rodríguez‐Sanz, L., van Dijk, J., Looser, N., & Bernasconi, S. M. (2017) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007106 · Cited by 101 · see citing works
“Because external reproducibilities can vary over short time periods, we only Table 1 External Reproducibility of Carbonate Standards From Nine Different Clumped Isotope Laboratories Expressed as the Long-Term Standard Deviation (r) of Multiple Measurements in ppm Reference r 6 ppm Number of analyses (n) Standards Trip…”
MethodCenozoic evolution of deep ocean temperature from clumped isotope thermometry
Meckler, A. N., Sexton, P. F., Piasecki, A. M., Leutert, T. J., Marquardt, J., Ziegler, M., Agterhuis, T., Lourens, L. J., Rae, J. W. B., Barnet, J., et al. (2022) · Science · doi:10.1126/science.abk0604 · Cited by 120 · see citing works
“…influence on 47 , if present, would bias those temperatures in the same direction, but the effect should be approximately four times smaller than for 18 O-derived temperatures (Guo, 2020; Tripati et al., 2015) and has so far not been observed in the typical oceanic pH range (Tang et al., 2014).”
BackgroundSelf-citationLoyd, S. J., Sample, J., Tripati, R., Defliese, W. F., Brooks, K., Hovland, M. T., Torres, M. E., Marlow, J. J., Hancock, L. G., Martin, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms12274 · Cited by 92 · see citing works
Self-citationClumped isotope composition of cold-water corals: A role for vital effects?
Spooner, P. T., Guo, W., Robinson, L. F., Thiagarajan, N., Hendry, K. R., Rosenheim, B. E., & Leng, M. J. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.01.023 · Cited by 84 · see citing works
Assessing kinetic fractionation in brachiopod calcite using clumped isotopes
Bajnai, D., Fiebig, J., Tomášových, A., Garcia, S. A. M., Rollion‐Bard, C., Raddatz, J., Löffler, N., Primo, C., & Brand, U. (2018) · Scientific Reports · doi:10.1038/s41598-017-17353-7 · Cited by 80 · see citing works
Falk, E. S., Guo, W., Paukert, A. N., Matter, J. M., Mervine, E. M., & Kelemen, P. B. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.06.026 · Cited by 75 · see citing works
“…et al., 2011), consistent with the steepness of the 579 Ghosh et al. (2006) calibration produced at Caltech, which appears to remain valid for a 580 wide variety materials analyzed at Caltech regardless of updated digestion procedures at 581 90°C (Falk and Kelemen, 2015; Tripati et al., 2015).”
ResultBurgener, L., Huntington, K. W., Hoke, G. D., Schauer, A. J., Ringham, M., Latorre, C., & Díaz, F. P. (2016) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2016.02.033 · Cited by 68 · see citing works
Clumped isotope fractionation during phosphoric acid digestion of carbonates at 70 °C
Müller, I. A., Violay, M. E. S., Storck, J.-C., Fernandez, A., van Dijk, J., Madonna, C., & Bernasconi, S. M. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2016.11.030 · Cited by 64 · see citing works
Frontiers of Carbonate Clumped Isotope Thermometry
Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66 · see citing works
Davies, A., & John, C. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.038 · Cited by 61 · see citing works
Modestou, S. E., Leutert, T. J., Fernandez, A., Lear, C. H., & Meckler, A. N. (2020) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa003927 · Cited by 57 · see citing works
“Changes in carbonate saturation state are not thought to affect carbonate Δ 47 compositions to a measurable extent (Eagle et al., 2013; Hill et al., 2014; Kelson et al., 2017; Tang et al., 2014; Tripati et al., 2015).”
BackgroundMurray, S. T., & Swart, P. K. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.021 · Cited by 52 · see citing works
Guo, Y., Deng, W., & Wei, G. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.01.012 · Cited by 50 · see citing works
Levitt, N. P., Eiler, J. M., Romanek, C. S., Beard, B. L., Xu, H., & Johnson, C. M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007089 · Cited by 48 · see citing works
“Recent work has argued that the ‘‘high slope’’ calibration curves are most likely to be correct, including those of Zaarur et al. (2013) and Tripati et al. (2015).”
BackgroundMethodResultInfluentialSelf-citationClumped-isotope thermometry of magnesium carbonates in ultramafic rocks
García del Real, P., Maher, K., Kluge, T., Bird, D. K., Brown, G. E., & John, C. M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.08.003 · Cited by 50 · see citing works
Clumped isotope temperature calibration for calcite: Bridging theory and experimentation
Jautzy, J. J., Savard, M. M., Dhillon, R. S., Bernasconi, S. M., & Smirnoff, A. (2020) · Geochemical Perspectives Letters · doi:10.7185/geochemlet.2021 · Cited by 50 · see citing works
“Recent studies (Coplen, 2007; Tang et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Levitt et al., 2018; Daëron et al., 2019) seem to agree regarding a dependence of the αcc/w 2.”
BackgroundSample, J., Torres, M. E., Fisher, A., Hong, W., Destrigneville, C., Defliese, W. F., & Tripati, A. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.013 · Cited by 46 · see citing works
Self-citationLiu, Y., Eagle, R. A., Aciego, S. M., Gilmore, R. E., & Ries, J. B. (2018) · Nature Communications · doi:10.1038/s41467-018-04463-7 · Cited by 46 · see citing works
Self-citationKatz, A., Bonifacie, M., Hermoso, M., Cartigny, P., & Calmels, D. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.025 · Cited by 44 · see citing works
“…values in inorganic carbonate minerals have been conducted (Ghosh et al., 2006; Dennis et Schrag, 2010; Zaarur et al., 2013; Fernandez et al., 2014; Tang et al., 2014; Defliese et al., 2015; Kele et al., 2015; Kluge et al., 2015; Tripati et al., 2015; Bonifacie et al., 2017; Kelson et al., 2017).”
BackgroundMethodInfluentialShuai, Y., Douglas, P., Zhang, S., Stolper, D. A., Ellis, G. S., Lawson, M. J., Lewan, M. D., Formolo, M. J., Mi, J., He, K., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.11.024 · Cited by 46 · see citing works
“…A. CombazInfluence of nature and diagenesis of organic matter in formation of petroleum AAPG Bull., 58 (3) (1974), pp. 499-506 View Record in Scopus Tripati et al., 2015 A.K. Tripati, P.S. Hill, R.A. Eagle, J.L. Mosenfelder, J. Tang, E.A. Schauble, J.M. Eiler, R.E.Zeebe, J. Uchikawa, T.B. Coplen,…”
Self-citationInfluence of water on clumped-isotope bond reordering kinetics in calcite
Brenner, D. C., Passey, B. H., & Stolper, D. A. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.12.026 · Cited by 41 · see citing works
“…isotopic equilibrium with water (and thus internal isotopic equilibrium between carbonate groups) and can result in non-equilibrium clumped isotope abundances (e.g., Affek et al., 2008, Daëron et al., 2011, Saenger et al., 2012, Kluge et al., 2014, Affek and Zaarur, 2014, Tripati et al., 2015).”
BackgroundFan, M., Ayyash, S., Tripati, A., Passey, B. H., & Griffith, E. M. (2017) · Geological Society of America Bulletin · doi:10.1130/b31732.1 · Cited by 41 · see citing works
Self-citationHodson, K. R., Crider, J. G., & Huntington, K. W. (2016) · Tectonophysics · doi:10.1016/j.tecto.2016.04.032 · Cited by 40 · see citing works
“Differences among these calibrations are topics of ongoing research (e.g. Defliese et al., 2015; Kluge et al., 2015; Tripati et al., 2015).”
BackgroundKimball, J., Eagle, R., & Dunbar, R. (2016) · Biogeosciences · doi:10.5194/bg-13-6487-2016 · Cited by 36 · see citing works
“Recent experimental and theoretical studies have suggested that mineral equilibrium with respect to147 might not always be attained, however (Saenger et al., 2012; Tripati et al., 2015).”
BackgroundMethodResultInfluentialSelf-citationA Combined Model for Kinetic Clumped Isotope Effects in the CaCO3‐DIC‐H2O System
Watkins, J. M., & Devriendt, L. S. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010200 · Cited by 34 · see citing works
Upadhyay, D., Lucarelli, J., Arnold, A., Flores, R., Bricker, H., Ulrich, R. N., Jesmok, G., Santi, L., Defliese, W., Eagle, R. A., et al. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9143 · Cited by 33 · see citing works
“Carbonate clumped isotope thermometry has been used to probe the temperature history of surface(8) and subsurface environments,(9) paleophysiology,(10) biomineralization processes,(11) and the alteration history of meteorites, as well as the origin of possible kinetic effects.(3,15) However, a range of instrumentation…”
MethodSelf-citationHill, P. S., Schauble, E. A., & Tripati, A. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.10.016 · Cited by 32 · see citing works
Self-citationHudson, A. M., Quade, J., Ali, G., Boyle, D., Bassett, S., Huntington, K. W., De los Santos, M. G., Cohen, A. S., Lin, K., & Wang, X. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.06.024 · Cited by 32 · see citing works
Evaluation of meteoric calcite cements as a proxy material for mass-47 clumped isotope thermometry
Defliese, W. F., & Lohmann, K. C. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.10.022 · Cited by 31 · see citing works
Oxygen isotope fractionation in the siderite-water system between 8.5 and 62 °C
van Dijk, J., Fernandez, A., Müller, I. A., Lever, M., & Bernasconi, S. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.10.009 · Cited by 30 · see citing works
Holdsworth, C. M., John, C. M., Snæbjörnsdóttir, S. Ó., Johnson, G., Sigfússon, B., Leslie, R., Haszeldine, R. S., & Gilfillan, S. M. V. (2024) · Applied Geochemistry · doi:10.1016/j.apgeochem.2024.105925 · Cited by 32 · see citing works
Came, R. E., Azmy, K., Tripati, A., & Olanipekun, B.-J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.028 · Cited by 29 · see citing works
Self-citationZhang, N., Lin, M., Snyder, G., Kakizaki, Y., Yamada, K., Yoshida, N., & Matsumoto, R. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.02.005 · Cited by 22 · see citing works
Daëron, M., & Vermeesch, P. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121881 · Cited by 28 · see citing works
Optical clumped isotope thermometry of carbon dioxide
Prokhorov, I., Kluge, T., & Janssen, C. (2019) · Scientific Reports · doi:10.1038/s41598-019-40750-z · Cited by 29 · see citing works
Uchikawa, J., Chen, S., Eiler, J. M., Adkins, J. F., & Zeebe, R. E. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.08.014 · Cited by 27 · see citing works
Self-citationBöttcher, M. E., Neubert, N., Escher, P., von Allmen, K., Samankassou, E., & Nägler, T. F. (2018) · Geochemistry · doi:10.1016/j.chemer.2018.01.001 · Cited by 28 · see citing works
Burgener, L., Huntington, K. W., Sletten, R. S., Watkins, J. M., Quade, J., & Hallet, B. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.06.006 · Cited by 28 · see citing works
Dietzel, M., Purgstaller, B., Kluge, T., Leis, A., & Mavromatis, V. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.02.032 · Cited by 28 · see citing works
Leutert, T. J., Modestou, S., Bernasconi, S. M., & Meckler, A. N. (2021) · Climate of the past · doi:10.5194/cp-17-2255-2021 · Cited by 28 · see citing works
“On the basis of current knowledge, other environmental variables such as pH and salinity appear to be of minor importance for measured 147 values over the range of natural variation (Tripati et al., 2015; Watkins and Hunt, 2015).”
BackgroundLucarelli, J. K., Carroll, H. M., Ulrich, R. N., Elliott, B. M., Coplen, T. B., Eagle, R. A., & Tripati, A. (2023) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2022gc010458 · Cited by 27 · see citing works
Self-citationClumped isotope acid fractionation factors for dolomite and calcite revisited: Should we care?
Lu, C., Murray, S. T., Koeshidayatullah, A., & Swart, P. K. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120637 · Cited by 25 · see citing works
Saenger, C., Gabitov, R. I., Farmer, J. R., Watkins, J. M., & Stone, R. P. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.02.014 · Cited by 25 · see citing works
Katō, H., Amekawa, S., Kano, A., Mori, T., Kuwahara, Y., & Quade, J. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.10.016 · Cited by 25 · see citing works
Zhang, N., Yamada, K., Kano, A., Matsumoto, R., & Yoshida, N. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.05.001 · Cited by 21 · see citing works
Li, H., Liu, X., Arnold, A., Elliott, B. M., Flores, R., Kelley, A. M., & Tripati, A. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116840 · Cited by 23 · see citing works
Self-citationThe role of temperature in the initiation of the end-Triassic mass extinction
Petryshyn, V. A., Greene, S. E., Farnsworth, A., Lunt, D. J., Kelley, A. M., Gammariello, R., Ibarra, Y., Bottjer, D. J., Tripati, A., & Corsetti, F. A. (2020) · Earth-Science Reviews · doi:10.1016/j.earscirev.2020.103266 · Cited by 21 · see citing works
Self-citationProteinaceous corals as proxy archives of paleo-environmental change
Williams, B. (2020) · Earth-Science Reviews · doi:10.1016/j.earscirev.2020.103326 · Cited by 22 · see citing works
Lloyd, M. K., Eldridge, D. L., & Stolper, D. A. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.10.008 · Cited by 21 · see citing works
Hermoso, M. (2016) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2016.02.003 · Cited by 21 · see citing works
“…this proxy has permitted, it is laudable that we are continuously developing this isotopic tool to generate more reliable SST estimates (Zeebe et al., 2008; Arbuszewski et al., 2010; Watkins et al., 2013; Minoletti et al., 2014; Prentice et al., 2014; Reghellin et al., 2015; Tripati et al., 2015).”
MethodLu, C., & Swart, P. K. (2024) · Geology · doi:10.1130/g51576.1 · Cited by 21 · see citing works
Santi, L., Arnold, A., Ibarra, D. E., Whicker, C. A., Mering, J. A., Lomarda, R. B., Lora, J. M., & Tripati, A. (2020) · Geological Society of America Bulletin · doi:10.1130/b35484.1 · Cited by 20 · see citing works
Self-citationPeral, M., Bassinot, F., Daëron, M., Blamart, D., Bonnin, J., Jorissen, F. J., Kissel, C., Michel, É., Waelbroeck, C., Rebaubier, H., et al. (2022) · EarthArXiv (California Digital Library) · doi:10.1016/j.gca.2022.10.030
Warm deep-sea temperatures across Eocene Thermal Maximum 2 from clumped isotope thermometry
Agterhuis, T., Ziegler, M., de Winter, N. J., & Lourens, L. J. (2022) · Communications Earth & Environment · doi:10.1038/s43247-022-00350-8 · Cited by 28 · see citing works
Davies, A., Davis, S., & John, C. M. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120317 · Cited by 19 · see citing works
Bajnai, D., Coplen, T., Methner, K., Löffler, N., Krsnik, E., & Fiebig, J. (2021) · Geophysical Research Letters · doi:10.1029/2021gl093257 · Cited by 15 · see citing works
“7°C among Earth-surface carbonates (Coplen, 2007; Daëron et al., 2019; Tripati et al., 2015; Wostbrock et al., 2020).”
BackgroundSelf-citationThaler, C., Katz, A., Bonifacie, M., Ménez, B., & Ader, M. (2020) · Biogeosciences · doi:10.5194/bg-17-1731-2020 · Cited by 18 · see citing works
Guo, Y., Deng, W., Wei, G., Lo, L., & Wang, N. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.04.030 · Cited by 17 · see citing works
Chang, B., Defliese, W. F., Li, C., Huang, J., Tripati, A., & Algeo, T. J. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8678 · Cited by 17 · see citing works
Self-citationClumped isotopic compositions of cultured and natural land-snail shells and their implications
Dong, J., Eiler, J. M., An, Z., Li, X., Liu, W., & Hu, J. (2021) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2021.110530 · Cited by 16 · see citing works
Self-citationWierzbowski, H. (2021) · Geosciences · doi:10.3390/geosciences11100419 · Cited by 15 · see citing works
“Despite the common equilibrium precipitation of clumped isotopes in biogenic calcites and aragonites, kinetic effects, which induce Δ47 offsets, are observed or suggested in cold water benthic and planktic foraminifera [355,357], rapidly growing hermatypic corals [375,376], deep-water corals [359,377], and temperate-…”
BackgroundDietzel, M., & Boch, R. (2024) · Geochemistry · doi:10.1016/j.chemer.2024.126206 · Cited by 14 · see citing works
Sun, F., Wang, Y., Jablonski, N. G., Hou, S., Ji, X., Wolff, B., Tripati, A., Cao, J., & Yang, X. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120123 · Cited by 14 · see citing works
Self-citationKluge, T., John, C. M., Boch, R., & Kele, S. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2017gc006969 · Cited by 14 · see citing works
Marchegiano, M., Peral, M., Venderickx, J., Martens, K., García‐Alix, A., Snoeck, C., Goderis, S., & Claeys, P. (2024) · Geophysical Research Letters · doi:10.1029/2023gl107426 · Cited by 14 · see citing works
“…variability in lacustrine environments and/or ostracod species environmental preferences, previous studies showed that the Δ 47 signal is not affected by parameters such as salinity, pH, and δ 18 O w (Grauel et al., 2013; Peral et al., 2018, 2022; Schauble et al., 2006; Tripati et al., 2015).”
BackgroundComplex Biomineralization Pathways of the Belemnite Rostrum Cause Biased Paleotemperature Estimates
Hoffmann, R., Linzmeier, B. J., Kitajima, K., Nehrke, G., Dietzel, M., Jöns, N., Stevens, K., & Immenhauser, A. (2021) · Minerals · doi:10.3390/min11121406 · Cited by 13 · see citing works
Lucarelli, J., Purgstaller, B., Ulrich, R., Parvez, Z. A., Leis, A., Goetschl, K. E., Eagle, R., Dietzel, M., & Tripati, A. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.07.027 · Cited by 12 · see citing works
Self-citationTaylor, V., Wilson, P. A., Bohaty, S. M., & Meckler, A. N. (2023) · Paleoceanography and Paleoclimatology · doi:10.1029/2023pa004650 · Cited by 10 · see citing works
“Lower ocean pH has been shown to increase planktic foraminiferal δ 18 O values (Spero et al., 1997; Uchikawa & Zeeve, 2010), while the influence on Δ 47 values is negligible by comparison (Guo, 2020; Tang et al., 2014; Tripati et al., 2015).”
InfluentialSynthetic Witherite for Standardisation of Clumped Isotope ( Δ47 ) Measurements
Kong, K., Guo, Y., Deng, W., & Wei, G. (2023) · Geostandards and Geoanalytical Research · doi:10.1111/ggr.12520 · Cited by 10 · see citing works
A Non-traditional Stable Isotope Perspective on Coral Calcification
Saenger, C., & Erez, J. (2016) · Springer eBooks · doi:10.1007/978-3-319-31305-4_12 · Cited by 11 · see citing works
Seep carbonate clumped isotopes revealing ocean warming-induced gas hydrate dissociation
Liu, L., Guan, H., Wu, N.-Y., Chang, B., Chen, F.-Q., Feng, D., & Li, S. (2024) · Global and Planetary Change · doi:10.1016/j.gloplacha.2024.104439 · Cited by 8 · see citing works
Microbial Autotrophy Recorded by Carbonate Dual Clumped Isotope Disequilibrium
Ingalls, M., Leapaldt, H. C., & Lloyd, M. K. (2024) · Geochemistry Geophysics Geosystems · doi:10.1029/2024gc011590 · Cited by 9 · see citing works
“…values than the line of mutual equilibrium during the re‐equilibration process, whereas addition of new CO 2 from an external pool produces positive ∆ 47 and/or negative ∆ 48 offsets from equilibrium (W. Guo, 2020; Tripati et al., 2015; Uchikawa et al., 2021; Watkins & Devriendt, 2022; Figure 1).”
BackgroundParvez, Z. A., Lucarelli, J. K., Matamoros, I. W., Rubi, J., Miguel, K., Elliott, B., Flores, R., Ulrich, R. N., Eagle, R. A., Watkins, J. M., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.022 · Cited by 9 · see citing works
“…moved away from the surface where the majority of rapid precipitation is occurring, isotopic equilibration of DIC within the detached layer is still hindered by the high pH of 11.5 (Beck et al., 2005), which favors hydroxylation and CO 3 2 – as the most abundant DIC species (Tripati et al., 2015).”
BackgroundMethodInfluentialSelf-citationParvez, Z. A., El-Shenawy, M., Lucarelli, J., Kim, S.-T., Johnson, K., Wright, K., Gebregiorgis, D., Montanez, I. P., Wortham, B., Asrat, A., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.11.017 · Cited by 9 · see citing works
Self-citationDefliese, W., & Tripati, A. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8666 · Cited by 6 · see citing works
Self-citationSavard, M., Jautzy, J., Lavoie, D., Dhillon, R., & Defliese, W. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.01.041 · Cited by 7 · see citing works
A multi-region study of carbonate clumped isotope data from terrestrial snails
Bricker, H., Bateman, J. B., Elliott, B. M., Mitsunaga, B., Mering, J. A., Foster, I. S., Yanes, Y., Oches, E. A., Eagle, R. A., & Tripati, A. (2023) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2023.111754 · Cited by 8 · see citing works
Self-citationFluid Mixing and Spatial Geochemical Variability in the Lost City Hydrothermal Field Chimneys
Aquino, K. A., Früh‐Green, G. L., Bernasconi, S. M., Rickli, J., Lang, S. Q., & Lilley, M. D. (2024) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2023gc011011 · Cited by 8 · see citing works
“Calcium carbonate minerals often precipitate under non‐equilibrium conditions in laboratory and most natural settings and thus display δ 18 O values that deviate from equilibrium (Daëron et al., 2019; Tripati et al., 2015; Watkins et al., 2013).”
BackgroundMethodInfluentialEffects of mineralogy on Δ47 and Δ48 of carbonate-derived CO2 below analytical resolution
Bernecker, M., Bonifacie, M., Staudigel, P. T., Meijer, N., Siebert, J., Wehr, N., Haussühl, E., Bernasconi, S. M., Petrash, D. A., Dietzel, M., et al. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.06.004 · Cited by 9 · see citing works
Calibration of the carbonate clumped isotope thermometer of land snail shells
Bao, R., Sheng, X., Li, C., Cui, C., Yan, H., Ji, J., & Chen, J. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121773 · Cited by 8 · see citing works
An “On-Line” Method for Oxygen Isotope Exchange Between Gas-Phase CO2 and Water
Levitt, N. P., & Romanek, C. S. (2016) · Aquatic Geochemistry · doi:10.1007/s10498-016-9291-5 · Cited by 8 · see citing works
“This innovative approach to understanding isotope equilibrium carries with it a need for new methods such as those described by Spencer and Kim (2015) that can keep pace with advanced analytical capabilities and computational power that permit the use of clumped isotopes in geosciences (Hill et al. 2014; Tripati et al…”
MethodMost bivalves and gastropods calcify indistinguishably from dual clumped isotope equilibrium
Schlidt, V., Evans, D., de Winter, N. J., Bernecker, M., Arndt, I., Staudigel, P. T., Davies, A., Brand, U., Müller, W., & Fiebig, J. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.10.008 · Cited by 10 · see citing works
Smith, M. E., McNeill, D. F., Murray, S. T., & Swart, P. K. (2023) · Sedimentology · doi:10.1111/sed.13087 · Cited by 7 · see citing works
Deep Heat: Proxies, Miocene Ice, and an End in Sight for Paleoclimate Paradoxes?
Evans, D. (2021) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa004174 · Cited by 6 · see citing works
Affek, H. P., Barkan, E., Tal, Y., Steidle, S. D., Wendt, K. A., Spötl, C., Edwards, R. L., Fishman, E., & Dublyansky, Y. V. (2025) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2025.119528 · Cited by 6 · see citing works
Lopez‐Maldonado, R., Bateman, J. B., Ellis, A. S., Bader, N. E., Ramírez, P. D., Arnold, A., Ajoku, O. F., Lee, H., Jesmok, G., Upadhyay, D., et al. (2023) · Paleoceanography and Paleoclimatology · doi:10.1029/2021pa004266 · Cited by 5 · see citing works
“, mean summer air temperatures), and the δ 18O of water in which the carbonate precipitated) can be compared to output from these three different models, in order to assess model-to-model accuracy in simulations of terrestrial hydroclimates (Eagle et al., 2013; Santi et al., 2020; Tripati et al., 2015).”
BackgroundSelf-citationHoldsworth, C., MacDonald, J., & John, C. M. (2022) · Minerals · doi:10.3390/min12121611 · Cited by 5 · see citing works
Development of clumped isotope techniques and their application to palaeoclimate studies
Kirk, R. (2017) · UEA Digital Repository (University of East Anglia) · Cited by 5 · see citing works
- Authors
- Tripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., Ries, J. B., & Henry, D.
- Affiliations
- California Institute of Technology (US)
- University of California, Los Angeles (US)
- University of Minnesota (US)
- University of Hawaiʻi at Mānoa (US)
- United States Geological Survey (US)
- Northeastern University (US)
- Corresponding author
- Tripati, Aradhna K.
- ORCID
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-10
- Volume
- 166
- Pages
- 344-371
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1823013860
- Cited by
- 139
- References
- 135
- Citations by year
- 2026: 5 · 2025: 10 · 2024: 9 · 2023: 16 · 2022: 12 · 2021: 19 · 2020: 10 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 16 · 2015: 2
- FWCI
- 16.83
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Geochimica et Cosmochimica Acta (acceptedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- NOAA Institutional Repository (submittedVersion, public-domain)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- National Science Foundation (EAR-1325054, ARC-1215551, EAR-0949191)
- National Oceanic and Atmospheric Administration (NA13OAR4310186)
- University of California, Los Angeles
- American Chemical Society (51182-DNI2, OCE-1437166, OCE09-27089, OCE-1357665)
- Basic Energy Sciences (DE-FG02-13ER16402)
- U.S. Department of Energy
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- clumped isotope thermometry, calcite, carbonic anhydrase, oxygen isotope exchange, coral calcification
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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