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Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition
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“This means that in extreme pH environments (such as where [CO 3 2-] is dominant, pH > 9.5), shifts in the chemical and isotopic equilibrium of the H 2 O-DIC-CaCO 3 system cause carbonates to follow a different equilibrium Ti relationship (Tripati et al. 2015, Watkins & Hunt 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
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“Equilibrium clumped isotopic compositions of the DIC species depend on temperature, but at a given temperature fewer clumped isotopologues are found in CO 3 2-than in HCO 3 -or H 2 CO 3 (Hill et al. 2014, Tripati et al. 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
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“Mineral precipitation occurring over a period of months removes the possibility of any pH-related disequilibrium effect being recorded in carbonate clumped isotope values (Hill et al., 2014;Kluge et al., 2018;Tripati et al., 2015).”
From Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes (2024) · cites this paper as Tripati et al., 2015
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“Deviations from this curve can suggest some kind of disequilibrium in the sample (see Tripati et al. 2015 for further discussion).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. 2015
Experimental — accuracy not yet measuredThe source backs part of the claim, not all of it — or backs it for a different population, condition or comparison.
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“Paired measurements of ∆ 63 and ∆ 64 can provide constraints on which processes shape observed isotopic signatures in experimental samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
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“Recently we hypothesized that solution chemistry may be an important factor influencing mineral clumped isotope signatures if a crystal precipitates too rapidly to achieve thermodynamic mineral lattice equilibrium (Tripati et al., 2010, 2015; Hill et al., 2014).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“we showed that at a given temperature, individual DIC species have distinct clumped isotope signatures”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“and impact the Δ 63 of the composite DIC pool and potentially measured carbonate mineral Δ 47 values.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“Kinetics will also have an effect on such fractionation (e.g., Hill et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Guo, 2019), but is beyond the scope of the present study.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“However, a disagreement between the magnitude of predicted changes from theory and observations has been reported in other studies (e.g., Guo et al., 2009; Tripati et al., 2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“Paired measurements of Δ 47 and Δ 48 can provide constraints on what processes shape observed isotopic signatures in samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
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“Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tripati et al., 2015
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Citations
Cites
On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
McCrea, J. M. (1950) · The Journal of Chemical Physics · doi:10.1063/1.1747785 · Cited by 3,742
A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media
Dickson, A. G., & Millero, F. J. (1987) · Deep Sea Research Part A Oceanographic Research Papers · doi:10.1016/0198-0149(87)90021-5 · Cited by 2,913
Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates
Kim, S.-T., & O'Neil, J. R. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00169-5 · Cited by 2,558
Coplen, T. B. (2011) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.5129 · Cited by 1,831 · cited 2×
“where R is the number ratio (Coplen, 2011), the number of a minor isotopologue to the number of the major isotopologue of a specified molecule (or atom) of interest.”
Self-citationAtmospheric carbon dioxide concentrations over the past 60 million years
Pearson, P. N., & Palmer, M. R. (2000) · Nature · doi:10.1038/35021000 · Cited by 1,771
Stable Prenucleation Calcium Carbonate Clusters
Gebauer, D., Völkel, A., & Cölfen, H. (2008) · Science · doi:10.1126/science.1164271 · Cited by 1,673
Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization
Addadi, L., Raz, S., & Weiner, S. (2003) · Advanced Materials · doi:10.1002/adma.200300381 · Cited by 1,594
Marine calcifiers exhibit mixed responses to CO2-induced ocean acidification
Ries, J. B., Cohen, A. L., & McCorkle, D. C. (2009) · Geology · doi:10.1130/g30210a.1 · Cited by 1,233
Self-citationRodriguez-Blanco, J. D., Shaw, S., & Benning, L. G. (2011) · Nanoscale · doi:10.1039/c0nr00589d · Cited by 1,141
13C and 18O isotopic disequilibrium in biological carbonates: I. Patterns
McConnaughey, T. (1989) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(89)90282-2 · Cited by 1,033
Research works printed but not linked: 3
- Guo, W., Kim, S.-T., Yuan, J., Farquhar, J., Passey, B. (2012) 13C–18O bonds in dissolved inorganic carbon: toward a better understanding of clumped isotope thermometer in biogenic carbonates. In 22nd Annual V.M. Goldschmidt Conference, Montreal, Canada.
- Kimball J. B., Tripati A., Dunbar, R. B., and Eagle, R. (2013). 13C–18O bonding (Δ47) in deep-sea corals: a calibration study. In AGU Fall Meeting Abstracts. Vol. 1, p. 1935.
- Usdowski, 1991, Factors for the oxygen isotope equilibrium fractionation between aqueous and gaseous CO2, carbonic acid, bicarbonate, carbonate, and water (19°C), Zeitsch. Phys. Chem., 170, 237
Cited by
Sorted by citations
Hollis, C. J., Jones, T. D., Anagnostou, E., Bijl, P. K., Cramwinckel, M. J., Cui, Y., Dickens, G. R., Edgar, K. M., Eley, Y. L., Evans, D., et al. (2019) · Geoscientific model development · doi:10.5194/gmd-12-3149-2019 · Cited by 286
“, 2006); (2) the technique involves the simultaneous measurement of Δ47 and δ18O, enabling the independent and direct calculation of ancient δ(18)Osw; (3) many biogenic carbonates and inorganic precipitates fall on the same calibration line, suggesting the absence of measurable ‘vital effects’ (e.g. Ghosh et al., 2006…”
MethodSelf-citationMost Earth-surface calcites precipitate out of isotopic equilibrium
Daëron, M., Drysdale, R. N., Peral, M., Huyghe, D., Blamart, D., Coplen, T. B., Lartaud, F., & Zanchetta, G. (2019) · Nature Communications · doi:10.1038/s41467-019-08336-5 · Cited by 236
Self-citationPetersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., et al. (2019) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2018gc008127 · Cited by 209
“However, a few studies have found mineralogy ‐ speci fi c behavior in Δ 47 (van Dijk et al., 2019; Müller et al., 2017; Murray et al., 2016; Tripati et al., 2015), such as 10.1029/2018GC008127 Geochemistry, Geophysics, Geosystems Müller et al. (2017) who found a measurable difference on the order of…”
InfluentialSelf-citationKelson, J. R., Huntington, K. W., Schauer, A. J., Saenger, C., & Lechler, A. R. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.010 · Cited by 177
Lunt, D. J., Huber, M. S., Anagnostou, E., Baatsen, M., Caballero, R., Deconto, R. M., Dijkstra, H. A., Yannick Donnadieu, A., Evans, D., Feng, R., et al. (2017) · Geoscientific model development · doi:10.5194/gmd-10-889-2017 · Cited by 181
Self-citationA robust calibration of the clumped isotopes to temperature relationship for foraminifers
Meinicke, N., Ho, S. L., Hannisdal, B., Nürnberg, D., Tripati, A., Schiebel, R., & Meckler, A. N. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.11.022 · Cited by 121
Self-citationOxygen isotope composition of the Phanerozoic ocean and a possible solution to the dolomite problem
Ryb, U., & Eiler, J. M. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1719681115 · Cited by 129
“Such compositions appear to be the product of rapid carbonate growth where CO2 outgassing or hydration/hydroxylation are rate-limiting processes (40, 41, 44, 45).”
BackgroundSelf-citationUpdated calibration of the clumped isotope thermometer in planktonic and benthic foraminifera
Peral, M., Daëron, M., Blamart, D., Bassinot, F., Dewilde, F., Smialkowski, N., Isguder, G., Bonnin, J., Jorissen, F., Kissel, C., et al. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.016 · Cited by 113
Dual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures
Bajnai, D., Guo, W., Spötl, C., Coplen, T. B., Methner, K., Löffler, N., Krsnik, E., Gischler, E., Hansen, M., Henkel, D., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-17501-0 · Cited by 147
Self-citationGuo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108
A process-based model for non-equilibrium clumped isotope effects in carbonates
Watkins, J. M., & Hunt, J. D. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.09.042 · Cited by 105
“28 (acid digestion at 25 ◦C; Tripati et al., 2015) for the comparison to experimental data.”
BackgroundMethodResultInfluentialCalibration of the dual clumped isotope thermometer for carbonates
Fiebig, J., Daëron, M., Bernecker, M., Guo, W., Schneider, G., Boch, R., Bernasconi, S. M., Jautzy, J., & Dietzel, M. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.07.012 · Cited by 110
Fernandez, A., Müller, I. A., Rodríguez‐Sanz, L., van Dijk, J., Looser, N., & Bernasconi, S. M. (2017) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007106 · Cited by 101
“Because external reproducibilities can vary over short time periods, we only Table 1 External Reproducibility of Carbonate Standards From Nine Different Clumped Isotope Laboratories Expressed as the Long-Term Standard Deviation (r) of Multiple Measurements in ppm Reference r 6 ppm Number of analyses (n) Standards Trip…”
MethodCenozoic evolution of deep ocean temperature from clumped isotope thermometry
Meckler, A. N., Sexton, P. F., Piasecki, A. M., Leutert, T. J., Marquardt, J., Ziegler, M., Agterhuis, T., Lourens, L. J., Rae, J. W. B., Barnet, J., et al. (2022) · Science · doi:10.1126/science.abk0604 · Cited by 120
“…influence on 47 , if present, would bias those temperatures in the same direction, but the effect should be approximately four times smaller than for 18 O-derived temperatures (Guo, 2020; Tripati et al., 2015) and has so far not been observed in the typical oceanic pH range (Tang et al., 2014).”
BackgroundSelf-citationLoyd, S. J., Sample, J., Tripati, R., Defliese, W. F., Brooks, K., Hovland, M. T., Torres, M. E., Marlow, J. J., Hancock, L. G., Martin, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms12274 · Cited by 92
Self-citationClumped isotope composition of cold-water corals: A role for vital effects?
Spooner, P. T., Guo, W., Robinson, L. F., Thiagarajan, N., Hendry, K. R., Rosenheim, B. E., & Leng, M. J. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.01.023 · Cited by 84
Assessing kinetic fractionation in brachiopod calcite using clumped isotopes
Bajnai, D., Fiebig, J., Tomášových, A., Garcia, S. A. M., Rollion‐Bard, C., Raddatz, J., Löffler, N., Primo, C., & Brand, U. (2018) · Scientific Reports · doi:10.1038/s41598-017-17353-7 · Cited by 84
Falk, E. S., Guo, W., Paukert, A. N., Matter, J. M., Mervine, E. M., & Kelemen, P. B. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.06.026 · Cited by 75
“…et al., 2011), consistent with the steepness of the 579 Ghosh et al. (2006) calibration produced at Caltech, which appears to remain valid for a 580 wide variety materials analyzed at Caltech regardless of updated digestion procedures at 581 90°C (Falk and Kelemen, 2015; Tripati et al., 2015).”
ResultBurgener, L., Huntington, K. W., Hoke, G. D., Schauer, A. J., Ringham, M., Latorre, C., & Díaz, F. P. (2016) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2016.02.033 · Cited by 68
Clumped isotope fractionation during phosphoric acid digestion of carbonates at 70 °C
Müller, I. A., Violay, M. E. S., Storck, J.-C., Fernandez, A., van Dijk, J., Madonna, C., & Bernasconi, S. M. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2016.11.030 · Cited by 64
Frontiers of Carbonate Clumped Isotope Thermometry
Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66
Davies, A., & John, C. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.038 · Cited by 64
Modestou, S. E., Leutert, T. J., Fernandez, A., Lear, C. H., & Meckler, A. N. (2020) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa003927 · Cited by 57
“Changes in carbonate saturation state are not thought to affect carbonate Δ 47 compositions to a measurable extent (Eagle et al., 2013; Hill et al., 2014; Kelson et al., 2017; Tang et al., 2014; Tripati et al., 2015).”
BackgroundMurray, S. T., & Swart, P. K. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.021 · Cited by 52
Guo, Y., Deng, W., & Wei, G. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.01.012 · Cited by 50
Near Equilibrium 13C18O Bonding During Inorganic Calcite Precipitation Under Chemo‐Stat Conditions
Levitt, N. P., Eiler, J. M., Romanek, C. S., Beard, B. L., Xu, H., & Johnson, C. M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007089 · Cited by 48
“Recent work has argued that the ‘‘high slope’’ calibration curves are most likely to be correct, including those of Zaarur et al. (2013) and Tripati et al. (2015).”
BackgroundMethodResultInfluentialSelf-citationClumped-isotope thermometry of magnesium carbonates in ultramafic rocks
García del Real, P., Maher, K., Kluge, T., Bird, D. K., Brown, G. E., & John, C. M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.08.003 · Cited by 50
Clumped isotope temperature calibration for calcite: Bridging theory and experimentation
Jautzy, J. J., Savard, M. M., Dhillon, R. S., Bernasconi, S. M., & Smirnoff, A. (2020) · Geochemical Perspectives Letters · doi:10.7185/geochemlet.2021 · Cited by 50
“Recent studies (Coplen, 2007; Tang et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Levitt et al., 2018; Daëron et al., 2019) seem to agree regarding a dependence of the αcc/w 2.”
BackgroundSample, J., Torres, M. E., Fisher, A., Hong, W., Destrigneville, C., Defliese, W. F., & Tripati, A. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.013 · Cited by 46
Self-citationLiu, Y., Eagle, R. A., Aciego, S. M., Gilmore, R. E., & Ries, J. B. (2018) · Nature Communications · doi:10.1038/s41467-018-04463-7 · Cited by 46
Self-citationKatz, A., Bonifacie, M., Hermoso, M., Cartigny, P., & Calmels, D. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.025 · Cited by 44
“…values in inorganic carbonate minerals have been conducted (Ghosh et al., 2006; Dennis et Schrag, 2010; Zaarur et al., 2013; Fernandez et al., 2014; Tang et al., 2014; Defliese et al., 2015; Kele et al., 2015; Kluge et al., 2015; Tripati et al., 2015; Bonifacie et al., 2017; Kelson et al., 2017).”
BackgroundMethodInfluentialShuai, Y., Douglas, P., Zhang, S., Stolper, D. A., Ellis, G. S., Lawson, M. J., Lewan, M. D., Formolo, M. J., Mi, J., He, K., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.11.024 · Cited by 46
“…A. CombazInfluence of nature and diagenesis of organic matter in formation of petroleum AAPG Bull., 58 (3) (1974), pp. 499-506 View Record in Scopus Tripati et al., 2015 A.K. Tripati, P.S. Hill, R.A. Eagle, J.L. Mosenfelder, J. Tang, E.A. Schauble, J.M. Eiler, R.E.Zeebe, J. Uchikawa, T.B. Coplen,…”
Self-citationInfluence of water on clumped-isotope bond reordering kinetics in calcite
Brenner, D. C., Passey, B. H., & Stolper, D. A. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.12.026 · Cited by 41
“…isotopic equilibrium with water (and thus internal isotopic equilibrium between carbonate groups) and can result in non-equilibrium clumped isotope abundances (e.g., Affek et al., 2008, Daëron et al., 2011, Saenger et al., 2012, Kluge et al., 2014, Affek and Zaarur, 2014, Tripati et al., 2015).”
BackgroundFan, M., Ayyash, S., Tripati, A., Passey, B. H., & Griffith, E. M. (2017) · Geological Society of America Bulletin · doi:10.1130/b31732.1 · Cited by 41
Self-citationHodson, K. R., Crider, J. G., & Huntington, K. W. (2016) · Tectonophysics · doi:10.1016/j.tecto.2016.04.032 · Cited by 40
“Differences among these calibrations are topics of ongoing research (e.g. Defliese et al., 2015; Kluge et al., 2015; Tripati et al., 2015).”
BackgroundKimball, J., Eagle, R., & Dunbar, R. (2016) · Biogeosciences · doi:10.5194/bg-13-6487-2016 · Cited by 36
“Recent experimental and theoretical studies have suggested that mineral equilibrium with respect to147 might not always be attained, however (Saenger et al., 2012; Tripati et al., 2015).”
BackgroundMethodResultInfluentialSelf-citationA Combined Model for Kinetic Clumped Isotope Effects in the CaCO3‐DIC‐H2O System
Watkins, J. M., & Devriendt, L. S. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010200 · Cited by 34
Upadhyay, D., Lucarelli, J., Arnold, A., Flores, R., Bricker, H., Ulrich, R. N., Jesmok, G., Santi, L., Defliese, W., Eagle, R. A., et al. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9143 · Cited by 33
“Carbonate clumped isotope thermometry has been used to probe the temperature history of surface(8) and subsurface environments,(9) paleophysiology,(10) biomineralization processes,(11) and the alteration history of meteorites, as well as the origin of possible kinetic effects.(3,15) However, a range of instrumentation…”
MethodSelf-citationHill, P. S., Schauble, E. A., & Tripati, A. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.10.016 · Cited by 29
Self-citationHudson, A. M., Quade, J., Ali, G., Boyle, D., Bassett, S., Huntington, K. W., De los Santos, M. G., Cohen, A. S., Lin, K., & Wang, X. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.06.024 · Cited by 32
Evaluation of meteoric calcite cements as a proxy material for mass-47 clumped isotope thermometry
Defliese, W. F., & Lohmann, K. C. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.10.022 · Cited by 31
Oxygen isotope fractionation in the siderite-water system between 8.5 and 62 °C
van Dijk, J., Fernandez, A., Müller, I. A., Lever, M., & Bernasconi, S. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.10.009 · Cited by 30
Holdsworth, C. M., John, C. M., Snæbjörnsdóttir, S. Ó., Johnson, G., Sigfússon, B., Leslie, R., Haszeldine, R. S., & Gilfillan, S. M. V. (2024) · Applied Geochemistry · doi:10.1016/j.apgeochem.2024.105925 · Cited by 32
Came, R. E., Azmy, K., Tripati, A., & Olanipekun, B.-J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.028 · Cited by 29
Self-citationZhang, N., Lin, M., Snyder, G. T., Kakizaki, Y., Yamada, K., Yoshida, N., & Matsumoto, R. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.02.005 · Cited by 29
Daëron, M., & Vermeesch, P. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121881 · Cited by 28
Optical clumped isotope thermometry of carbon dioxide
Prokhorov, I., Kluge, T., & Janssen, C. (2019) · Scientific Reports · doi:10.1038/s41598-019-40750-z · Cited by 29
Uchikawa, J., Chen, S., Eiler, J. M., Adkins, J. F., & Zeebe, R. E. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.08.014 · Cited by 29
Self-citationBöttcher, M. E., Neubert, N., Escher, P., von Allmen, K., Samankassou, E., & Nägler, T. F. (2018) · Geochemistry · doi:10.1016/j.chemer.2018.01.001 · Cited by 28
Burgener, L., Huntington, K. W., Sletten, R. S., Watkins, J. M., Quade, J., & Hallet, B. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.06.006 · Cited by 28
Dietzel, M., Purgstaller, B., Kluge, T., Leis, A., & Mavromatis, V. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.02.032 · Cited by 28
Leutert, T. J., Modestou, S., Bernasconi, S. M., & Meckler, A. N. (2021) · Climate of the past · doi:10.5194/cp-17-2255-2021 · Cited by 28
“On the basis of current knowledge, other environmental variables such as pH and salinity appear to be of minor importance for measured 147 values over the range of natural variation (Tripati et al., 2015; Watkins and Hunt, 2015).”
BackgroundEquilibrated Gas and Carbonate Standard‐Derived Dual (Δ 47 and Δ 48 ) Clumped Isotope Values
Lucarelli, J. K., Carroll, H. M., Ulrich, R. N., Elliott, B. M., Coplen, T. B., Eagle, R. A., & Tripati, A. (2023) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2022gc010458 · Cited by 27
Self-citationClumped isotope acid fractionation factors for dolomite and calcite revisited: Should we care?
Lu, C., Murray, S. T., Koeshidayatullah, A., & Swart, P. K. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120637 · Cited by 26
Saenger, C., Gabitov, R. I., Farmer, J. R., Watkins, J. M., & Stone, R. P. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.02.014 · Cited by 25
Katō, H., Amekawa, S., Kano, A., Mori, T., Kuwahara, Y., & Quade, J. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.10.016 · Cited by 25
Zhang, N., Yamada, K., Kano, A., Matsumoto, R., & Yoshida, N. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.05.001 · Cited by 25
Li, H., Liu, X., Arnold, A., Elliott, B. M., Flores, R., Kelley, A. M., & Tripati, A. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116840 · Cited by 24
Self-citationThe role of temperature in the initiation of the end-Triassic mass extinction
Petryshyn, V. A., Greene, S. E., Farnsworth, A., Lunt, D. J., Kelley, A. M., Gammariello, R., Ibarra, Y., Bottjer, D. J., Tripati, A., & Corsetti, F. A. (2020) · Earth-Science Reviews · doi:10.1016/j.earscirev.2020.103266 · Cited by 21
Self-citationProteinaceous corals as proxy archives of paleo-environmental change
Williams, B. (2020) · Earth-Science Reviews · doi:10.1016/j.earscirev.2020.103326 · Cited by 20
Lloyd, M. K., Eldridge, D. L., & Stolper, D. A. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.10.008 · Cited by 21
Hermoso, M. (2016) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2016.02.003 · Cited by 24
“…this proxy has permitted, it is laudable that we are continuously developing this isotopic tool to generate more reliable SST estimates (Zeebe et al., 2008; Arbuszewski et al., 2010; Watkins et al., 2013; Minoletti et al., 2014; Prentice et al., 2014; Reghellin et al., 2015; Tripati et al., 2015).”
MethodLu, C., & Swart, P. K. (2024) · Geology · doi:10.1130/g51576.1 · Cited by 21
Santi, L., Arnold, A., Ibarra, D. E., Whicker, C. A., Mering, J. A., Lomarda, R. B., Lora, J. M., & Tripati, A. (2020) · Geological Society of America Bulletin · doi:10.1130/b35484.1 · Cited by 19
Self-citationPeral, M., Bassinot, F., Daëron, M., Blamart, D., Bonnin, J., Jorissen, F. J., Kissel, C., Michel, É., Waelbroeck, C., Rebaubier, H., et al. (2022) · EarthArXiv (California Digital Library) · doi:10.1016/j.gca.2022.10.030
Warm deep-sea temperatures across Eocene Thermal Maximum 2 from clumped isotope thermometry
Agterhuis, T., Ziegler, M., de Winter, N. J., & Lourens, L. J. (2022) · Communications Earth & Environment · doi:10.1038/s43247-022-00350-8 · Cited by 28
Davies, A., Davis, S., & John, C. M. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120317 · Cited by 20
Bajnai, D., Coplen, T. B., Methner, K., Löffler, N., Krsnik, E., & Fiebig, J. (2021) · Geophysical Research Letters · doi:10.1029/2021gl093257 · Cited by 19
“7°C among Earth-surface carbonates (Coplen, 2007; Daëron et al., 2019; Tripati et al., 2015; Wostbrock et al., 2020).”
BackgroundSelf-citationThaler, C., Katz, A., Bonifacie, M., Ménez, B., & Ader, M. (2020) · Biogeosciences · doi:10.5194/bg-17-1731-2020 · Cited by 18
Guo, Y., Deng, W., Wei, G., Lo, L., & Wang, N. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.04.030 · Cited by 17
Chang, B., Defliese, W. F., Li, C., Huang, J., Tripati, A., & Algeo, T. J. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8678 · Cited by 17
Self-citationClumped isotopic compositions of cultured and natural land-snail shells and their implications
Dong, J., Eiler, J. M., An, Z., Li, X., Liu, W., & Hu, J. (2021) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2021.110530 · Cited by 17
Self-citationWierzbowski, H. (2021) · Geosciences · doi:10.3390/geosciences11100419 · Cited by 15
“Despite the common equilibrium precipitation of clumped isotopes in biogenic calcites and aragonites, kinetic effects, which induce Δ47 offsets, are observed or suggested in cold water benthic and planktic foraminifera [355,357], rapidly growing hermatypic corals [375,376], deep-water corals [359,377], and temperate-…”
BackgroundDietzel, M., & Boch, R. (2024) · Geochemistry · doi:10.1016/j.chemer.2024.126206 · Cited by 14
Sun, F., Wang, Y., Jablonski, N. G., Hou, S., Ji, X., Wolff, B., Tripati, A., Cao, J., & Yang, X. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120123 · Cited by 14
Self-citationAssessment of Factors Controlling Clumped Isotopes and δ18O Values of Hydrothermal Vent Calcites
Kluge, T., John, C. M., Boch, R., & Kele, S. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2017gc006969 · Cited by 14
Marchegiano, M., Peral, M., Venderickx, J., Martens, K., García‐Alix, A., Snoeck, C., Goderis, S., & Claeys, P. (2024) · Geophysical Research Letters · doi:10.1029/2023gl107426 · Cited by 16
“…variability in lacustrine environments and/or ostracod species environmental preferences, previous studies showed that the Δ 47 signal is not affected by parameters such as salinity, pH, and δ 18 O w (Grauel et al., 2013; Peral et al., 2018, 2022; Schauble et al., 2006; Tripati et al., 2015).”
BackgroundComplex Biomineralization Pathways of the Belemnite Rostrum Cause Biased Paleotemperature Estimates
Hoffmann, R., Linzmeier, B. J., Kitajima, K., Nehrke, G., Dietzel, M., Jöns, N., Stevens, K., & Immenhauser, A. (2021) · Minerals · doi:10.3390/min11121406 · Cited by 13
Lucarelli, J., Purgstaller, B., Ulrich, R. N., Parvez, Z., Leis, A., Goetschl, K. E., Eagle, R. A., Dietzel, M., & Tripati, A. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.07.027 · Cited by 12
Self-citationTaylor, V., Wilson, P. A., Bohaty, S. M., & Meckler, A. N. (2023) · Paleoceanography and Paleoclimatology · doi:10.1029/2023pa004650 · Cited by 10
“Lower ocean pH has been shown to increase planktic foraminiferal δ 18 O values (Spero et al., 1997; Uchikawa & Zeeve, 2010), while the influence on Δ 47 values is negligible by comparison (Guo, 2020; Tang et al., 2014; Tripati et al., 2015).”
InfluentialSynthetic Witherite for Standardisation of Clumped Isotope ( Δ47 ) Measurements
Kong, K., Guo, Y., Deng, W., & Wei, G. (2023) · Geostandards and Geoanalytical Research · doi:10.1111/ggr.12520 · Cited by 10
A Non-traditional Stable Isotope Perspective on Coral Calcification
Saenger, C., & Erez, J. (2016) · Springer eBooks · doi:10.1007/978-3-319-31305-4_12 · Cited by 11
Seep carbonate clumped isotopes revealing ocean warming-induced gas hydrate dissociation
Liu, L., Guan, H., Wu, N., Chang, B., Chen, F., Feng, D., & Li, S. (2024) · Global and Planetary Change · doi:10.1016/j.gloplacha.2024.104439 · Cited by 9
Microbial Autotrophy Recorded by Carbonate Dual Clumped Isotope Disequilibrium
Ingalls, M., Leapaldt, H. C., & Lloyd, M. K. (2024) · Geochemistry Geophysics Geosystems · doi:10.1029/2024gc011590 · Cited by 9
“…values than the line of mutual equilibrium during the re‐equilibration process, whereas addition of new CO 2 from an external pool produces positive ∆ 47 and/or negative ∆ 48 offsets from equilibrium (W. Guo, 2020; Tripati et al., 2015; Uchikawa et al., 2021; Watkins & Devriendt, 2022; Figure 1).”
BackgroundParvez, Z. A., Lucarelli, J. K., Matamoros, I. W., Rubi, J., Miguel, K., Elliott, B., Flores, R., Ulrich, R. N., Eagle, R. A., Watkins, J. M., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.022 · Cited by 9
“…moved away from the surface where the majority of rapid precipitation is occurring, isotopic equilibration of DIC within the detached layer is still hindered by the high pH of 11.5 (Beck et al., 2005), which favors hydroxylation and CO 3 2 – as the most abundant DIC species (Tripati et al., 2015).”
BackgroundMethodInfluentialSelf-citationParvez, Z. A., El-Shenawy, M., Lucarelli, J., Kim, S.-T., Johnson, K., Wright, K., Gebregiorgis, D., Montanez, I. P., Wortham, B., Asrat, A., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.11.017 · Cited by 9
Self-citationDefliese, W. F., & Tripati, A. (2019) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8666 · Cited by 10
Self-citationSavard, M., Jautzy, J., Lavoie, D., Dhillon, R., & Defliese, W. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.01.041 · Cited by 7
A multi-region study of carbonate clumped isotope data from terrestrial snails
Bricker, H., Bateman, J. B., Elliott, B. M., Mitsunaga, B., Mering, J. A., Foster, I. S., Yanes, Y., Oches, E. A., Eagle, R. A., & Tripati, A. (2023) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2023.111754 · Cited by 8
Self-citationFluid Mixing and Spatial Geochemical Variability in the Lost City Hydrothermal Field Chimneys
Aquino, K. A., Früh‐Green, G. L., Bernasconi, S. M., Rickli, J., Lang, S. Q., & Lilley, M. D. (2024) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2023gc011011 · Cited by 8
“Calcium carbonate minerals often precipitate under non‐equilibrium conditions in laboratory and most natural settings and thus display δ 18 O values that deviate from equilibrium (Daëron et al., 2019; Tripati et al., 2015; Watkins et al., 2013).”
BackgroundMethodInfluentialEffects of mineralogy on Δ47 and Δ48 of carbonate-derived CO2 below analytical resolution
Bernecker, M., Bonifacie, M., Staudigel, P. T., Meijer, N., Siebert, J., Wehr, N., Haussühl, E., Bernasconi, S. M., Petrash, D. A., Dietzel, M., et al. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.06.004 · Cited by 9
Calibration of the carbonate clumped isotope thermometer of land snail shells
Bao, R., Sheng, X., Li, C., Cui, C., Yan, H., Ji, J., & Chen, J. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121773 · Cited by 8
An “On-Line” Method for Oxygen Isotope Exchange Between Gas-Phase CO2 and Water
Levitt, N. P., & Romanek, C. S. (2016) · Aquatic Geochemistry · doi:10.1007/s10498-016-9291-5 · Cited by 8
“This innovative approach to understanding isotope equilibrium carries with it a need for new methods such as those described by Spencer and Kim (2015) that can keep pace with advanced analytical capabilities and computational power that permit the use of clumped isotopes in geosciences (Hill et al. 2014; Tripati et al…”
MethodMost bivalves and gastropods calcify indistinguishably from dual clumped isotope equilibrium
Schlidt, V., Evans, D., de Winter, N. J., Bernecker, M., Arndt, I., Staudigel, P. T., Davies, A., Brand, U., Müller, W., & Fiebig, J. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.10.008 · Cited by 10
Smith, M. E., McNeill, D. F., Murray, S. T., & Swart, P. K. (2023) · Sedimentology · doi:10.1111/sed.13087 · Cited by 9
Deep Heat: Proxies, Miocene Ice, and an End in Sight for Paleoclimate Paradoxes?
Evans, D. (2021) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa004174 · Cited by 6
Affek, H. P., Barkan, E., Tal, Y., Steidle, S. D., Wendt, K. A., Spötl, C., Edwards, R. L., Fishman, E., & Dublyansky, Y. V. (2025) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2025.119528 · Cited by 6
Lopez‐Maldonado, R., Bateman, J. B., Ellis, A. S., Bader, N. E., Ramírez, P. D., Arnold, A., Ajoku, O. F., Lee, H., Jesmok, G., Upadhyay, D., et al. (2023) · Paleoceanography and Paleoclimatology · doi:10.1029/2021pa004266 · Cited by 5
“, mean summer air temperatures), and the δ 18O of water in which the carbonate precipitated) can be compared to output from these three different models, in order to assess model-to-model accuracy in simulations of terrestrial hydroclimates (Eagle et al., 2013; Santi et al., 2020; Tripati et al., 2015).”
BackgroundSelf-citationHoldsworth, C., MacDonald, J., & John, C. M. (2022) · Minerals · doi:10.3390/min12121611 · Cited by 5
Development of clumped isotope techniques and their application to palaeoclimate studies
Kirk, R. (2017) · UEA Digital Repository (University of East Anglia) · Cited by 5
Metadata
- Authors
- Tripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., Ries, J. B., & Henry, D.
- Affiliations
- California Institute of Technology (US)
- University of California, Los Angeles (US)
- University of Minnesota (US)
- University of Hawaiʻi at Mānoa (US)
- United States Geological Survey (US)
- Northeastern University (US)
- Corresponding author
- Tripati, Aradhna K.
- ORCID
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-10
- Volume
- 166
- Pages
- 344-371
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1823013860
- Cited by
- 139
- References
- 135
- Citations by year
- 2026: 5 · 2025: 10 · 2024: 9 · 2023: 16 · 2022: 12 · 2021: 19 · 2020: 10 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 16 · 2015: 2
- FWCI
- 16.83
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Geochimica et Cosmochimica Acta (acceptedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- NOAA Institutional Repository (submittedVersion, public-domain)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- National Science Foundation (EAR-1325054, ARC-1215551, EAR-0949191)
- National Oceanic and Atmospheric Administration (NA13OAR4310186)
- University of California, Los Angeles
- American Chemical Society (51182-DNI2, OCE-1437166, OCE09-27089, OCE-1357665)
- Basic Energy Sciences (DE-FG02-13ER16402)
- U.S. Department of Energy
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- clumped isotope thermometry, calcite, carbonic anhydrase, oxygen isotope exchange, coral calcification
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