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Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition
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“This means that in extreme pH environments (such as where [CO 3 2-] is dominant, pH > 9.5), shifts in the chemical and isotopic equilibrium of the H 2 O-DIC-CaCO 3 system cause carbonates to follow a different equilibrium Ti relationship (Tripati et al. 2015, Watkins & Hunt 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
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“Equilibrium clumped isotopic compositions of the DIC species depend on temperature, but at a given temperature fewer clumped isotopologues are found in CO 3 2-than in HCO 3 -or H 2 CO 3 (Hill et al. 2014, Tripati et al. 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tripati et al. 2015
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“Mineral precipitation occurring over a period of months removes the possibility of any pH-related disequilibrium effect being recorded in carbonate clumped isotope values (Hill et al., 2014;Kluge et al., 2018;Tripati et al., 2015).”
From Reconstructing the temperature and origin of CO2 mineralisation in CarbFix calcite using clumped, carbon and oxygen isotopes (2024) · cites this paper as Tripati et al., 2015
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“Deviations from this curve can suggest some kind of disequilibrium in the sample (see Tripati et al. 2015 for further discussion).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. 2015
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“Paired measurements of ∆ 63 and ∆ 64 can provide constraints on which processes shape observed isotopic signatures in experimental samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
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“Recently we hypothesized that solution chemistry may be an important factor influencing mineral clumped isotope signatures if a crystal precipitates too rapidly to achieve thermodynamic mineral lattice equilibrium (Tripati et al., 2010, 2015; Hill et al., 2014).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“we showed that at a given temperature, individual DIC species have distinct clumped isotope signatures”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“and impact the Δ 63 of the composite DIC pool and potentially measured carbonate mineral Δ 47 values.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“Kinetics will also have an effect on such fractionation (e.g., Hill et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Guo, 2019), but is beyond the scope of the present study.”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“However, a disagreement between the magnitude of predicted changes from theory and observations has been reported in other studies (e.g., Guo et al., 2009; Tripati et al., 2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al., 2015
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“Paired measurements of Δ 47 and Δ 48 can provide constraints on what processes shape observed isotopic signatures in samples, as described initially in Tripati et al. (2015).”
From Theoretical constraints on the effects of added cations on clumped, oxygen, and carbon isotope signatures of dissolved inorganic carbon species and minerals (2020) · cites this paper as Tripati et al. (2015)
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“Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tripati et al., 2015
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Flagged first, then by citations
1 of the 135 references couldn’t be matched to a known paper.
Research works printed but not linked: 3
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Cited by
Sorted by citations
Hollis, C. J., Jones, T. D., Anagnostou, E., Bijl, P. K., Cramwinckel, M. J., Cui, Y., Dickens, G. R., Edgar, K. M., Eley, Y. L., Evans, D., et al. (2019) · Geoscientific model development · doi:10.5194/gmd-12-3149-2019 · Cited by 276
“, 2006); (2) the technique involves the simultaneous measurement of Δ47 and δ18O, enabling the independent and direct calculation of ancient δ(18)Osw; (3) many biogenic carbonates and inorganic precipitates fall on the same calibration line, suggesting the absence of measurable ‘vital effects’ (e.g. Ghosh et al., 2006…”
MethodSelf-citationMost Earth-surface calcites precipitate out of isotopic equilibrium
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“However, a few studies have found mineralogy ‐ speci fi c behavior in Δ 47 (van Dijk et al., 2019; Müller et al., 2017; Murray et al., 2016; Tripati et al., 2015), such as 10.1029/2018GC008127 Geochemistry, Geophysics, Geosystems Müller et al. (2017) who found a measurable difference on the order of…”
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Lunt, D. J., Huber, M. S., Anagnostou, E., Baatsen, M., Caballero, R., Deconto, R. M., Dijkstra, H. A., Yannick Donnadieu, A., Evans, D., Feng, R., et al. (2017) · Geoscientific model development · doi:10.5194/gmd-10-889-2017 · Cited by 176
Self-citation
Metadata
- Authors
- Tripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., Ries, J. B., & Henry, D.
- Affiliations
- California Institute of Technology (US)
- University of California, Los Angeles (US)
- University of Minnesota (US)
- University of Hawaiʻi at Mānoa (US)
- United States Geological Survey (US)
- Northeastern University (US)
- Corresponding author
- Tripati, Aradhna K.
- ORCID
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2015-10
- Volume
- 166
- Pages
- 344-371
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W1823013860
- Cited by
- 139
- References
- 135
- Citations by year
- 2026: 5 · 2025: 10 · 2024: 9 · 2023: 16 · 2022: 12 · 2021: 19 · 2020: 10 · 2019: 15 · 2018: 13 · 2017: 12 · 2016: 16 · 2015: 2
- FWCI
- 16.83
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Geochimica et Cosmochimica Acta (acceptedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- NOAA Institutional Repository (submittedVersion, public-domain)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- National Science Foundation (EAR-1325054, ARC-1215551, EAR-0949191)
- National Oceanic and Atmospheric Administration (NA13OAR4310186)
- University of California, Los Angeles
- American Chemical Society (51182-DNI2, OCE-1437166, OCE09-27089, OCE-1357665)
- Basic Energy Sciences (DE-FG02-13ER16402)
- U.S. Department of Energy
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- clumped isotope thermometry, calcite, carbonic anhydrase, oxygen isotope exchange, coral calcification
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