Patterns and controls of disequilibrium isotope effects in speleothems: Insights from an isotope-enabled diffusion-reaction model and implications for quantitative thermometry

A High-Resolution Absolute-Dated Late Pleistocene Monsoon Record from Hulu Cave, China

Wang, Y., Cheng, H., Edwards, R. L., An, Z., Wu, J., Shen, C., & Dorale, J. A. (2001) · Science · doi:10.1126/science.1064618 · Cited by 3,218 · see citing works

Diffusion of ions in sea water and in deep-sea sediments

Yuan-Hui, L., & Gregory, S. (1974) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(74)90145-8 · Cited by 2,875 · see citing works

Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates

Kim, S.-T., & O'Neil, J. R. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00169-5 · Cited by 2,558 · see citing works

The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90°C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O

Plummer, L. N., & Busenberg, E. (1982) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(82)90056-4 · Cited by 1,886 · see citing works

Proton Transfer, Acid‐Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSES

Eigen, M. (1964) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196400011 · Cited by 1,844 · see citing works

The Asian monsoon over the past 640,000 years and ice age terminations

Cheng, H., Edwards, R. L., Sinha, A., Spötl, C., Yi, L., Chen, S., Kelly, M. J., Kathayat, G., Wang, X., Li, X., et al. (2016) · Nature · doi:10.1038/nature18591 · Cited by 1,762 · see citing works

Improvements in 230Th dating, 230Th and 234U half-life values, and U–Th isotopic measurements by multi-collector inductively coupled plasma mass spectrometry

Cheng, H., Edwards, R. L., Shen, C., Polyak, V. J., Asmerom, Y., Woodhead, J. D., Hellström, J., Wang, Y., Kong, X., Spötl, C., et al. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2013.04.006 · Cited by 1,573 · see citing works

238U234U230Th232Th systematics and the precise measurement of time over the past 500,000 years

Edwards, R. L., Chen, J. H., & Wasserburg, G. J. (1987) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(87)90154-3 · Cited by 1,326 · see citing works

The kinetics of calcite dissolution in CO 2 -water systems at 5 degrees to 60 degrees C and 0.0 to 1.0 atm CO 2

Plummer, L. N., Wigley, T. M. L., & Parkhurst, D. L. (1978) · American Journal of Science · doi:10.2475/ajs.278.2.179 · Cited by 1,190 · see citing works

Palaeo-climate reconstruction from stable isotope variations in speleothems: a review

McDermott, F. P. (2004) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2003.06.021 · Cited by 1,045 · see citing works

13C–18O bonds in carbonate minerals: a new kind of paleothermometer

Ghosh, P., Adkins, J., Affek, H., Balta, B., Guo, W., Schauble, E. A., Schrag, D., & Eiler, J. M. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.11.014 · Cited by 914 · see citing works

Measurement of the diffusion coefficients of sparingly soluble gases in water

Jähne, B., Heinz, G., & Dietrich, W. (1987) · Journal of Geophysical Research Atmospheres · doi:10.1029/jc092ic10p10767 · Cited by 864 · see citing works

Modification and preservation of environmental signals in speleothems

Fairchild, I. J., Smith, C. L., Baker, A., Fuller, L., Spötl, C., Mattey, D., McDermott, F. P., & E.I.M.F. (2005) · Earth-Science Reviews · doi:10.1016/j.earscirev.2005.08.003 · Cited by 854 · see citing works

Climatic and environmental controls on speleothem oxygen-isotope values

Lachniet, M. S. (2009) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2008.10.021 · Cited by 773 · see citing works

Pressure and temperature dependence of self-diffusion in water

Krynicki, K., Green, C. D., & Sawyer, D. W. (1978) · Faraday Discussions of the Chemical Society · doi:10.1039/dc9786600199 · Cited by 747 · see citing works

The kinetics of combination of carbon dioxide with hydroxide ions

Pinsent, B. R. W., Pearson, L., & Roughton, F. J. W. (1956) · Transactions of the Faraday Society · doi:10.1039/tf9565201512 · Cited by 688 · see citing works

Defining an absolute reference frame for ‘clumped’ isotope studies of CO2

Dennis, K. J., Affek, H. P., Passey, B. H., Schrag, D. P., & Eiler, J. M. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.09.025 · Cited by 627 · see citing works

Trace elements in speleothems as recorders of environmental change

Fairchild, I. J., & Treble, P. C. (2009) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2008.11.007 · Cited by 596 · see citing works

Cave air control on dripwater geochemistry, Obir Caves (Austria): Implications for speleothem deposition in dynamically ventilated caves

Spötl, C., Fairchild, I. J., & Tooth, A. F. (2005) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.12.009 · Cited by 485 · see citing works

Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions

DePaolo, D. J. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.11.020 · Cited by 451 · see citing works

Methods and limitations of ‘clumped’ CO ₂ isotope (Δ ₄₇ ) analysis by gas‐source isotope ratio mass spectrometry

Huntington, K. W., Eiler, J. M., Affek, H. P., Guo, W., Bonifacie, M., Yeung, L. Y., Thiagarajan, N., Passey, B., Tripati, A., Daëron, M., et al. (2009) · Journal of Mass Spectrometry · doi:10.1002/jms.1614 · Cited by 436 · see citing works

Speleothem calcite farmed in situ: modern calibration of δ18O and δ13C paleoclimate proxies in a continuously-monitored natural cave system

Tremaine, D. M., Froelich, P. N., & Wang, Y. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.06.005 · Cited by 395 · see citing works

Phosphoric acid fractionation factors for calcite and aragonite between 25 and 75 °C: Revisited

Kim, S.-T., Mucci, A., & Taylor, B. E. (2007) · Chemical Geology · doi:10.1016/j.chemgeo.2007.08.005 · Cited by 374 · see citing works

An explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes

Zeebe, R. E. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00091-5 · Cited by 368 · see citing works

Variations of 17O/16O and 18O/16O in meteoric waters

Luz, B., & Barkan, E. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.08.016 · Cited by 355 · see citing works

Calibration of the calcite–water oxygen-isotope geothermometer at Devils Hole, Nevada, a natural laboratory

Coplen, T. B. (2007) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2007.05.028 · Cited by 347 · see citing works

Large kinetic isotope effects in modern speleothems

Mickler, P. J., Stern, L. A., & Banner, J. L. (2006) · Geological Society of America Bulletin · doi:10.1130/b25698.1 · Cited by 308 · see citing works

Interhemispheric anti-phasing of rainfall during the last glacial period

Wang, X., Auler, A. S., Edwards, R. L., Cheng, H., Ito, E., & Solheid, M. (2006) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2006.02.009 · Cited by 307 · see citing works

Glacial/interglacial temperature variations in Soreq cave speleothems as recorded by “clumped isotope” thermometry

Affek, H. P., Bar-Matthews, M., Ayalon, A., Matthews, A., & Eiler, J. M. (2008) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.06.031 · Cited by 306 · see citing works

The kinetics of calcite dissolution and precipitation in geologically relevant situations of karst areas

Bühmann, D., & Dreybrodt, W. (1985) · Chemical Geology · doi:10.1016/0009-2541(85)90024-5 · Cited by 299 · see citing works

Carbon-13 fractionation between aragonite and calcite

Rubinson, M., & Clayton, R. N. (1969) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(69)90109-4 · Cited by 292 · see citing works

Carbon and oxygen isotope study of the active water-carbonate system in a karstic Mediterranean cave: Implications for paleoclimate research in semiarid regions

Bar‐Matthews, M., Ayalon, A., Matthews, A., Sass, E., & Halicz, L. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(95)00395-9 · Cited by 292 · see citing works

On the molecular diffusion coefficients of dissolved , and and their dependence on isotopic mass

Zeebe, R. E. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.02.010 · Cited by 290 · see citing works

Speleothem science: from process to past environments

(2012) · Choice Reviews Online · doi:10.5860/choice.50-2079 · Cited by 281 · see citing works

The kinetics of calcite dissolution and precipitation in geologically relevant situations of karst areas

Buhmann, D., & Dreybrodt, W. (1985) · Chemical Geology · doi:10.1016/0009-2541(85)90046-4 · Cited by 279 · see citing works

Annual growth banding in a cave stalagmite

Baker, A., Smart, P. L., Edwards, R. L., & Richards, D. A. (1993) · Nature · doi:10.1038/364518a0 · Cited by 274 · see citing works

Pressure and temperature dependence of the self diffusion coefficient of water and oxygen-18 water

Harris, K. R., & Woolf, L. A. (1980) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19807600377 · Cited by 273 · see citing works

Acidity measurements at elevated temperatures. VII. Dissociation of water

Sweeton, F. H., Mesmer, R. E., & Baes, C. F. (1974) · Journal of Solution Chemistry · doi:10.1007/bf00645633 · Cited by 264 · see citing works

Isotopic fractionations associated with phosphoric acid digestion of carbonate minerals: Insights from first-principles theoretical modeling and clumped isotope measurements

Guo, W., Mosenfelder, J. L., Goddard, W. A., & Eiler, J. M. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.05.071 · Cited by 262 · see citing works

Stable isotope variations in modern tropical speleothems: Evaluating equilibrium vs. kinetic isotope effects

Mickler, P. J., Banner, J. L., Stern, L. A., Asmerom, Y., Edwards, R. L., & Ito, E. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.02.012 · Cited by 253 · see citing works

Climatic dependence of stable carbon and oxygen isotope signals recorded in speleothems: From soil water to speleothem calcite

Dreybrodt, W., & Scholz, D. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.11.002 · Cited by 246 · see citing works

Testing Theoretically Predicted Stalagmite Growth Rate with Recent Annually Laminated Samples: Implications for Past Stalagmite Deposition

Baker, A., Genty, D., Dreybrodt, W., Barnes, W. L., Mockler, N. J., & Grapes, J. (1998) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00343-8 · Cited by 244 · see citing works

Predicting mineral solubility from rate data; application to the dissolution of magnesian calcites

Plummer, L. N., & Mackenzie, F. T. (1974) · American Journal of Science · doi:10.2475/ajs.274.1.61 · Cited by 239 · see citing works

Most Earth-surface calcites precipitate out of isotopic equilibrium

Daëron, M., Drysdale, R. N., Peral, M., Huyghe, D., Blamart, D., Coplen, T. B., Lartaud, F., & Zanchetta, G. (2019) · Nature Communications · doi:10.1038/s41467-019-08336-5 · Cited by 236 · see citing works

The Use of Electrolysis for Accurate δ17O and δ18O Isotope Measurements in Water

Meijer, H. A. J., & Li, W. J. (1998) · Isotopes in Environmental and Health Studies · doi:10.1080/10256019808234072 · Cited by 226 · see citing works

High-precision mass-spectrometric uranium-series dating of cave deposits and implications for palaeoclimate studies

Li, W.-X., Lundberg, J. A., Dickin, A. P., Ford, D., Schwarcz, H. P., McNutt, R. H., & Williams, D. (1989) · Nature · doi:10.1038/339534a0 · Cited by 219 · see citing works

Processes in karst systems: physics, chemistry, and geology

Dreybrodt, W. (1989) · Choice Reviews Online · doi:10.5860/choice.26-4499 · Cited by 214 · see citing works

Carbon mass-balance modelling and carbon isotope exchange processes in dynamic caves

Frisia, S., Fairchild, I. J., Fohlmeister, J., Miorandi, R., Spötl, C., & Borsato, A. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.10.021 · Cited by 212 · see citing works

Measurement of the isotope fractionation associated with diffusion of carbon dioxide in aqueous solution

O’Leary, M. H. (1984) · The Journal of Physical Chemistry · doi:10.1021/j150648a041 · Cited by 206 · see citing works

Determination of the rate constants for the carbon dioxide to bicarbonate inter-conversion in pH-buffered seawater systems

Schulz, K. G., Riebesell, U., Rost, B., Thoms, S., & Zeebe, R. E. (2006) · Marine Chemistry · doi:10.1016/j.marchem.2005.11.001 · Cited by 195 · see citing works

Very high-frequency and seasonal cave atmosphere PCO2 variability: Implications for stalagmite growth and oxygen isotope-based paleoclimate records

Baldini, J. U. L., McDermott, F. P., Hoffmann, D. L., Richards, D. A., & Clipson, N. (2008) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2008.04.031 · Cited by 184 · see citing works

13C18O clumping in speleothems: observations from natural caves and precipitation experiments

Daëron, M., Guo, W., Eiler, J., Genty, D., Blamart, D., Boch, R., Drysdale, R., Maire, R., Wainer, K., & Zanchetta, G. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.10.032 · Cited by 182 · see citing works

The influence of kinetics on the oxygen isotope composition of calcium carbonate

Watkins, J. M., Nielsen, L. C., Ryerson, F. J., & DePaolo, D. J. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2013.05.054 · Cited by 181 · see citing works

The influence of temperature, pH, and growth rate on the δ18O composition of inorganically precipitated calcite

Watkins, J. M., Hunt, J. D., Ryerson, F. J., & DePaolo, D. J. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.07.036 · Cited by 181 · see citing works

Seasonal Variations in Modern Speleothem Calcite Growth in Central Texas, U.S.A.

Banner, J. L., Guilfoyle, A. L., James, E. W., Stern, L. A., & Musgrove, M. (2007) · Journal of Sedimentary Research · doi:10.2110/jsr.2007.065 · Cited by 179 · see citing works

Toward a universal carbonate clumped isotope calibration: Diverse synthesis and preparatory methods suggest a single temperature relationship

Kelson, J. R., Huntington, K. W., Schauer, A. J., Saenger, C., & Lechler, A. R. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.010 · Cited by 177 · see citing works

Advancements in the use of speleothems as climate archives

Wong, C. I., & Breecker, D. O. (2015) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2015.07.019 · Cited by 170 · see citing works

A revised calibration of the clumped isotope thermometer

Zaarur, S., Affek, H. P., & Brandon, M. T. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2013.07.026 · Cited by 163 · see citing works

Theoretical constraints on the effects of pH, salinity, and temperature on clumped isotope signatures of dissolved inorganic carbon species and precipitating carbonate minerals

Hill, P. S., Tripati, A. K., & Schauble, E. A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.06.018 · Cited by 155 · see citing works

Modelling fractionation of stable isotopes in stalagmites

Mühlinghaus, C., Scholz, D., & Mangini, A. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.09.010 · Cited by 152 · see citing works

Isotope disequilibrium effects: The influence of evaporation and ventilation effects on the carbon and oxygen isotope composition of speleothems – A model approach

Deininger, M., Fohlmeister, J., Scholz, D., & Mangini, A. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.08.013 · Cited by 145 · see citing works

Speleothem record of the last 180 ka in Villars cave (SW France): Investigation of a large δ18O shift between MIS6 and MIS5

Wainer, K., Genty, D., Blamart, D., Daëron, M., Bar-Matthews, M., Vonhof, H., Dublyansky, Y., Pons-Branchu, E., Thomas, L., van Calsteren, P., et al. (2011) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2010.07.004 · Cited by 133 · see citing works

Modelling δ13C and δ18O in the solution layer on stalagmite surfaces

Scholz, D., Mühlinghaus, C., & Mangini, A. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.02.015 · Cited by 127 · see citing works

Modelling stalagmite growth and δ13C as a function of drip interval and temperature

Mühlinghaus, C., Scholz, D., & Mangini, A. (2007) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2007.03.018 · Cited by 118 · see citing works

Evolution of the isotopic composition of carbon and oxygen in a calcite precipitating H2O–CO2–CaCO3 solution and the related isotopic composition of calcite in stalagmites

Dreybrodt, W. (2008) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.07.022 · Cited by 118 · see citing works

A first evaluation of the spatial gradients in δ18O recorded by European Holocene speleothems

McDermott, F. P., Atkinson, T. C., Fairchild, I. J., Baldini, L. M., & Mattey, D. P. (2011) · Global and Planetary Change · doi:10.1016/j.gloplacha.2011.01.005 · Cited by 116 · see citing works

Dependence of water viscosity on temperature and pressure

Лихачев, Е. Р. (2003) · Technical Physics · doi:10.1134/1.1568496 · Cited by 114 · see citing works

A high-resolution gas-source isotope ratio mass spectrometer

Eiler, J. M., Clog, M., Magyar, P., Piasecki, A. M., Sessions, A. L., Stolper, D. A., Deerberg, M., Schlueter, H.-J., & Schwieters, J. B. (2012) · International Journal of Mass Spectrometry · doi:10.1016/j.ijms.2012.10.014 · Cited by 113 · see citing works

Speleothem Science: From Process to Past Environments

Faulkner, T. (2013) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2013.07.029 · Cited by 113 · see citing works

Kinetic clumped isotope fractionation in the DIC-H2O-CO2 system: Patterns, controls, and implications

Guo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108 · see citing works

A process-based model for non-equilibrium clumped isotope effects in carbonates

Watkins, J. M., & Hunt, J. D. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.09.042 · Cited by 105 · see citing works

A large-radius high-mass-resolution multiple-collector isotope ratio mass spectrometer for analysis of rare isotopologues of O2, N2, CH4 and other gases

Young, E., Rumble, D., Freedman, P., & Mills, M. (2016) · International Journal of Mass Spectrometry · doi:10.1016/j.ijms.2016.01.006 · Cited by 98 · see citing works

Combined high-precision ∆48 and ∆47 analysis of carbonates

Fiebig, J., Bajnai, D., Löffler, N., Methner, K., Krsnik, E., Mulch, A., & Hofmann, S. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2019.05.019 · Cited by 97 · see citing works

Kinetic isotope effect in CO2 degassing: Insight from clumped and oxygen isotopes in laboratory precipitation experiments

Affek, H. P., & Zaarur, S. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.005 · Cited by 96 · see citing works

Simulating speleothem growth in the laboratory: Determination of the stable isotope fractionation (δ13C and δ18O) between H2O, DIC and CaCO3

Hansen, M., Scholz, D., Schöne, B. R., & Spötl, C. (2019) · Chemical Geology · doi:10.1016/j.chemgeo.2018.12.012 · Cited by 95 · see citing works

Oxygen isotopes in calcite grown under cave-analogue conditions

Day, C., & Henderson, G. M. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.04.026 · Cited by 95 · see citing works

Glacial–interglacial temperature change in the tropical West Pacific: A comparison of stalagmite-based paleo-thermometers

Meckler, A. N., Affolter, S., Dublyansky, Y. V., Krüger, Y., Vogel, N., Bernasconi, S. M., Frenz, M., Kipfer, R., Leuenberger, M., Spötl, C., et al. (2015) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2015.06.015 · Cited by 87 · see citing works

Disequilibrium carbon and oxygen isotope fractionation in recent cave calcite: Comparison of cave precipitates and model data

Riechelmann, D. F. C., Deininger, M., Scholz, D., Riechelmann, S., Schröder‐Ritzrau, A., Spötl, C., Richter, D., Mangini, A., & Immenhauser, A. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.11.002 · Cited by 87 · see citing works

Quantifying kinetic fractionation in Bunker Cave speleothems using Δ47

Kluge, T., & Affek, H. P. (2012) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2012.06.013 · Cited by 86 · see citing works

A global model for cave ventilation and seasonal bias in speleothem paleoclimate records

James, E. W., Banner, J. L., & Hardt, B. F. (2015) · Geochemistry Geophysics Geosystems · doi:10.1002/2014gc005658 · Cited by 86 · see citing works

Stable isotopes in caves over altitudinal gradients: fractionation behaviour and inferences for speleothem sensitivity to climate change

Johnston, V., Borsato, A., Spötl, C., Frisia, S., & Miorandi, R. (2012) · Climate of the past · doi:10.5194/cp-9-99-2013 · Cited by 83 · see citing works

Oxygen isotope variations in rainfall, drip-water and speleothem calcite from a well-ventilated cave in Texas, USA: Assessing a new speleothem temperature proxy

Feng, W., Casteel, R., Banner, J., & Heinze-Fry, A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.11.039 · Cited by 80 · see citing works

Investigation of the stable isotope fractionation in speleothems with laboratory experiments

Wiedner, E. A., Scholz, D., Mangini, A., Polag, D., Mühlinghaus, C., & Segl, M. (2007) · Quaternary International · doi:10.1016/j.quaint.2007.03.017 · Cited by 73 · see citing works

Calcium isotopes in caves as a proxy for aridity: Modern calibration and application to the 8.2 kyr event

Owen, R., Day, C., Hu, C.-Y., Liu, Y.-X., Pointing, M., Blättler, C., & Henderson, G. (2016) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2016.03.027 · Cited by 72 · see citing works

Stable isotope fractionation in speleothems: Laboratory experiments

Polag, D., Scholz, D., Mühlinghaus, C., Spötl, C., Schröder‐Ritzrau, A., Segl, M., & Mangini, A. (2010) · Chemical Geology · doi:10.1016/j.chemgeo.2010.09.016 · Cited by 69 · see citing works

Chemical evolution of dissolved inorganic carbon species flowing in thin water films and its implications for (rapid) degassing of CO2 during speleothem growth

Hansen, M., Dreybrodt, W., & Scholz, D. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.01.006 · Cited by 66 · see citing works

Coherency of late Holocene European speleothem δ18O records linked to North Atlantic Ocean circulation

Deininger, M., McDermott, F. P., Manfred Mudelsee, A., Werner, M., Frank, N., & Mangini, A. (2016) · Climate Dynamics · doi:10.1007/s00382-016-3360-8 · Cited by 66 · see citing works

Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide

Zeebe, R. E. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.05.005 · Cited by 65 · see citing works

Variations of the carbon and oxygen isotopic composition in stalagmites and stalactites: Evidence of non-equilibrium isotopic fractionation

Fantidis, J., & Ehhalt, D. H. (1970) · Earth and Planetary Science Letters · doi:10.1016/0012-821x(70)90075-0 · Cited by 64 · see citing works

Reconstruction of drip-water δ 18 O based on calcite oxygen and clumped isotopes of speleothems from Bunker Cave (Germany)

Kluge, T., Affek, H., Marx, T., Aeschbach-Hertig, W., Riechelmann, D., Scholz, D., Riechelmann, S., Immenhauser, A., Richter, D., Fohlmeister, J., et al. (2013) · Climate of the past · doi:10.5194/cp-9-377-2013 · Cited by 64 · see citing works

Clumped isotope fractionation during phosphoric acid digestion of carbonates at 70 °C

Müller, I. A., Violay, M. E. S., Storck, J.-C., Fernandez, A., van Dijk, J., Madonna, C., & Bernasconi, S. M. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2016.11.030 · Cited by 64 · see citing works

Accounting for kinetic isotope effects in Soreq Cave (Israel) speleothems

Affek, H. P., Matthews, A., Ayalon, A., Bar‐Matthews, M., Burstyn, Y., Zaarur, S., & Zilberman, T. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.008 · Cited by 62 · see citing works

δ13C profiles along growth layers of stalagmites: Comparing theoretical and experimental results

Romanov, D., Kaufmann, G., & Dreybrodt, W. (2007) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2007.09.039 · Cited by 62 · see citing works

Temperature-driven seasonal calcite growth and drip water trace element variations in a well-ventilated Texas cave: Implications for speleothem paleoclimate studies

Casteel, R. C., & Banner, J. L. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2014.11.002 · Cited by 56 · see citing works

Oxygen isotopic fractionation between drip water and speleothem calcite: A 10-year monitoring study, central Texas, USA

Feng, W., Banner, J. L., Guilfoyle, A. L., Musgrove, M., & James, E. W. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.02.004 · Cited by 55 · see citing works

Triple oxygen isotope fractionation in the DIC-H2O-CO2 system: A numerical framework and its implications

Guo, W., & Zhou, C. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.11.018 · Cited by 55 · see citing works

Kinetic effects during the experimental transition of aragonite to calcite in aqueous solution: Insights from clumped and oxygen isotope signatures

Guo, Y., Deng, W., & Wei, G. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.01.012 · Cited by 50 · see citing works

Quantifying carbon isotope disequilibrium during in-cave evolution of drip water along discreet flow paths

Mickler, P. J., Carlson, P. E., Banner, J. L., Breecker, D. O., Stern, L. A., & Guilfoyle, A. L. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.09.027 · Cited by 50 · see citing works

Temporal Variability of Cave-Air CO2 in Central Texas

Cowan, B., Osborne, M. C., & Banner, J. L. (2013) · Journal of Cave and Karst Studies · doi:10.4311/2011es0246 · Cited by 48 · see citing works

The impact of evaporation to the isotope composition of DIC in calcite precipitating water films in equilibrium and kinetic fractionation models

Dreybrodt, W., & Deininger, M. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.10.004 · Cited by 41 · see citing works

Processes affecting the stable isotope composition of calcite during precipitation on the surface of stalagmites: Laboratory experiments investigating the isotope exchange between DIC in the solution layer on top of a speleothem and the CO2 of the cave atmosphere

Dreybrodt, W., Hansen, M., & Scholz, D. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.11.012 · Cited by 38 · see citing works

Kinetics of CO2(g)–H2O(1) isotopic exchange, including mass 47 isotopologues

Clog, M., Stolper, D., & Eiler, J. (2015) · Chemical Geology · doi:10.1016/j.chemgeo.2014.11.023 · Cited by 37 · see citing works

New constraints on kinetic isotope effects during CO2(aq) hydration and hydroxylation: Revisiting theoretical and experimental data

Sade, Z., & Halevy, I. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.07.035 · Cited by 37 · see citing works

CaveCalc: A new model for speleothem chemistry & isotopes

Owen, R., Day, C., & Henderson, G. M. (2018) · Computers & Geosciences · doi:10.1016/j.cageo.2018.06.011 · Cited by 36 · see citing works

Carbon isotope exchange between gaseous CO2 and thin solution films: Artificial cave experiments and a complete diffusion-reaction model

Hansen, M., Scholz, D., Froeschmann, M.-L., Schöne, B. R., & Spötl, C. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.05.005 · Cited by 35 · see citing works

The potential of near-entrance stalagmites as high-resolution terrestrial paleoclimate proxies: Application of isotope and trace-element geochemistry to seasonally-resolved chronology

Carlson, P. E., Miller, N. R., Banner, J. L., Breecker, D. O., & Casteel, R. C. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.04.036 · Cited by 31 · see citing works

North Atlantic Oscillation controls on oxygen and hydrogen isotope gradients in winter precipitation across Europe; implications for palaeoclimate studies

Deininger, M., Werner, M., & McDermott, F. P. (2016) · Climate of the past · doi:10.5194/cp-12-2127-2016 · Cited by 29 · see citing works

Optical clumped isotope thermometry of carbon dioxide

Prokhorov, I., Kluge, T., & Janssen, C. (2019) · Scientific Reports · doi:10.1038/s41598-019-40750-z · Cited by 29 · see citing works

The evolution of 13C and 18O isotope composition of DIC in a calcite depositing film of water with isotope exchange between the DIC and a CO2 containing atmosphere, and simultaneous evaporation of the water. Implication to climate proxies from stalagmites: A theoretical model

Dreybrodt, W., & Romanov, D. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.07.034 · Cited by 25 · see citing works

A Kinetic Difference Between 12C‐ and 13C‐Bound Oxygen Exchange Rates Results in Decoupled δ18O and Δ47 Values of Equilibrating DIC Solutions

Staudigel, P. T., & Swart, P. K. (2018) · Geochemistry Geophysics Geosystems · doi:10.1029/2018gc007500 · Cited by 25 · see citing works

ISOLUTION 1.0: an ISOtope evoLUTION model describing the stable oxygen (δ18O) and carbon (δ13C) isotope values of speleothems

Mainz, J. G.-U., Deininger, M., Scholz, D., & Mainz, J. G.-U. (2019) · International Journal of Speleology · doi:10.5038/1827-806x.48.1.2219 · Cited by 24 · see citing works

Comments on processes contributing to the isotope composition of 13C and 18O in calcite deposited to speleothems

Dreybrodt, W. (2011) · Acta Carsologica · doi:10.3986/ac.v40i2.8 · Cited by 19 · see citing works

Concentration and stable carbon isotopic composition of CO2in cave air of Postojnska jama, Slovenia

Mandić, M., Mihevc, A., Leis, A., & Bronić, I. K. (2013) · International Journal of Speleology · doi:10.5038/1827-806x.42.3.11 · Cited by 17 · see citing works

Spatiotemporal distribution of δ13C CO2 in a shallow cave and its potential use as indicator of anthropic pressure

Gázquez, F., Quindós-Poncela, L. S., Sàinz, C., Villar, A. F., Merino, I. F., & Celaya, S. (2016) · Journal of Environmental Management · doi:10.1016/j.jenvman.2016.05.078 · Cited by 16 · see citing works

Corrigendum to “New constraints on kinetic isotope effects during CO2(aq) hydration and hydroxylation: Revisiting theoretical and experimental data” [Geochim. Cosmochim. Acta 214 (2017) 246–265]

Sade, Z., & Halevy, I. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.01.030 · Cited by 8 · see citing works

Problems in using the approach of Rayleigh distillation to interpret the 13C and 18O isotope compositions in stalagmite calcite

Dreybrodt, W. (2016) · Acta Carsologica · doi:10.3986/ac.v45i3.4698 · Cited by 7 · see citing works

Subtropical Atlantic Climate Variability Record in Speleothems from the Bahamas

Arienzo, M. M. (2014) · Cited by 4 · see citing works

Carbonate Clumped Isotope Thermometry: Applications to Carbonaceous Chondrites and Effects of Kinetic Isotope Fractionation

Guo, W. (2009) · California Institute of Technology · doi:10.7907/bwc2-rh54

Dual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures

Bajnai, D., Guo, W., Spötl, C., Coplen, T. B., Methner, K., Löffler, N., Krsnik, E., Gischler, E., Hansen, M., Henkel, D., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-17501-0 · Cited by 147 · see citing works

Kinetic clumped isotope fractionation in the DIC-H2O-CO2 system: Patterns, controls, and implications

Guo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108 · see citing works

Calibration of the dual clumped isotope thermometer for carbonates

Fiebig, J., Daëron, M., Bernecker, M., Guo, W., Schneider, G., Boch, R., Bernasconi, S. M., Jautzy, J., & Dietzel, M. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.07.012 · Cited by 110 · see citing works

Triple Oxygen Isotopes in Meteoric Waters, Carbonates, and Biological Apatites: Implications for Continental Paleoclimate Reconstruction

Passey, B. H., & Levin, N. E. (2021) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2021.86.13 · Cited by 79 · see citing works

Frontiers of Carbonate Clumped Isotope Thermometry

Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66 · see citing works

North Iberian temperature and rainfall seasonality over the Younger Dryas and Holocene

Baldini, L. M., Baldini, J. U. L., McDermott, F. P., Cabal, P. A., Cueto, M., Fairchild, I. J., Hoffmann, D. L., Mattey, D. P., Müller, W., Niţă, D. C., et al. (2019) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2019.105998 · Cited by 60 · see citing works

Ubiquitous karst hydrological control on speleothem oxygen isotope variability in a global study

Treble, P. C., Baker, A., Abram, N. J., Hellström, J., Crawford, J., Gagan, M. K., Borsato, A., Griffiths, A. D., Bajo, P., Markowska, M., et al. (2022) · Communications Earth & Environment · doi:10.1038/s43247-022-00347-3 · Cited by 58 · see citing works

Detecting and quantifying palaeoseasonality in stalagmites using geochemical and modelling approaches

Baldini, J. U. L., Lechleitner, F. A., Breitenbach, S. F. M., van Hunen, J., Baldini, L. M., Wynn, P., Jamieson, R. A., Ridley, H. E., Baker, A. J., Walczak, I. W., et al. (2021) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2020.106784 · Cited by 49 · see citing works

Eastern Mediterranean climate change deduced from the Soreq Cave fluid inclusion stable isotopes and carbonate clumped isotopes record of the last 160 ka

Matthews, A., Affek, H., Ayalon, A., Vonhof, H., & Bar-Matthews, M. (2021) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2021.107223 · Cited by 36 · see citing works

Dual clumped isotope thermometry of coral carbonate

Davies, A., Guo, W., Bernecker, M., Tagliavento, M., Raddatz, J., Gischler, E., Flögel, S., & Fiebig, J. (2022) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2022.10.015 · Cited by 42 · see citing works

A framework for triple oxygen isotopes in speleothem paleoclimatology

Huth, T. E., Passey, B. H., Cole, J. E., Lachniet, M. S., McGee, D., Denniston, R. F., Truebe, S. A., & Levin, N. E. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.11.002 · Cited by 39 · see citing works

Carbonate 17Oexcess as a paleo-hydrology proxy: Triple oxygen isotope fractionation between H2O and biogenic aragonite, derived from freshwater mollusks

Bergel, S., Barkan, E., Stein, M., & Affek, H. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.02.005 · Cited by 34 · see citing works

A Combined Model for Kinetic Clumped Isotope Effects in the CaCO3‐DIC‐H2O System

Watkins, J. M., & Devriendt, L. S. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010200 · Cited by 34 · see citing works

Isotopic disequilibrium in brachiopods disentangled with dual clumped isotope thermometry

Davies, A., Brand, U., Tagliavento, M., Bitner, M. A., Bajnai, D., Staudigel, P. T., Bernecker, M., & Fiebig, J. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.08.005 · Cited by 31 · see citing works

Constraining speleothem oxygen isotope disequilibrium driven by rapid CO2 degassing and calcite precipitation: Insights from monitoring and modeling

Carlson, P. E., Noronha, A. L., Banner, J. L., Jenson, J. W., Moore, M. W., Partin, J. W., Deininger, M., Breecker, D. O., & Bautista, K. K. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.06.012 · Cited by 28 · see citing works

Contemporaneously growing speleothems and their value to decipher in-cave processes – A modelling approach

Skiba, V., & Fohlmeister, J. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.03.016 · Cited by 30 · see citing works

Carbonate clumped isotope values compromised by nitrate-derived NO2 interferent

Fiebig, J., Bernecker, M., Meijer, N., Methner, K., Staudigel, P. T., Davies, A., Bayarjargal, L., Spahr, D., Winkler, B., Hofmann, S., et al. (2024) · Chemical Geology · doi:10.1016/j.chemgeo.2024.122382 · Cited by 29 · see citing works

Trajectory and timescale of oxygen and clumped isotope equilibration in the dissolved carbonate system under normal and enzymatically-catalyzed conditions at 25 °C

Uchikawa, J., Chen, S., Eiler, J. M., Adkins, J. F., & Zeebe, R. E. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.08.014 · Cited by 27 · see citing works

Equilibrated Gas and Carbonate Standard‐Derived Dual (Δ ₄₇ and Δ ₄₈ ) Clumped Isotope Values

Lucarelli, J. K., Carroll, H. M., Ulrich, R. N., Elliott, B. M., Coplen, T. B., Eagle, R. A., & Tripati, A. (2023) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2022gc010458 · Cited by 27 · see citing works

The impact of outgassing of CO2 and prior calcium precipitation to the isotope composition of calcite precipitated on stalagmites. Implications for reconstructing climate information from proxies

Dreybrodt, W., & Fohlmeister, J. (2021) · Chemical Geology · doi:10.1016/j.chemgeo.2021.120676 · Cited by 24 · see citing works

A robust methodology for triple (∆47, ∆48, ∆49) clumped isotope analysis of carbonates

Bernecker, M., Hofmann, S., Staudigel, P., Davies, A., Tagliavento, M., Meijer, N., Ballian, A., & Fiebig, J. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121803 · Cited by 22 · see citing works

Technical Note: Developments and Applications in Triple Oxygen Isotope Analysis of Carbonates

Fosu, B., Subba, R., Peethambaran, R., Bhattacharya, S., & Ghosh, P. (2020) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.9b00330 · Cited by 23 · see citing works

Evidence for heterothermic endothermy and reptile-like eggshell mineralization in Troodon, a non-avian maniraptoran theropod

Tagliavento, M., Davies, A., Bernecker, M., Staudigel, P., Dawson, R. R., Dietzel, M., Götschl, K., Guo, W.-F., Schulp, A., Therrien, F., et al. (2023) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.2213987120 · Cited by 22 · see citing works

Devils Hole Calcite Was Precipitated at ±1°C Stable Aquifer Temperatures During the Last Half Million Years

Bajnai, D., Coplen, T., Methner, K., Löffler, N., Krsnik, E., & Fiebig, J. (2021) · Geophysical Research Letters · doi:10.1029/2021gl093257 · Cited by 15 · see citing works

Resolving and correcting for kinetic biases on methane seep paleotemperature using carbonate ∆47/∆48 analysis

Staudigel, P., Feng, D., Peckmann, J., Bernecker, M., Davies, A., Tagliavento, M., & Fiebig, J. (2024) · Science Advances · doi:10.1126/sciadv.adn0155 · Cited by 16 · see citing works

The effects of drip rate and geometry on the isotopic composition of speleothems: Evaluation with an advection-diffusion-reaction model

Sade, Z., Hegyi, S., Hansen, M., Scholz, D., & Halevy, I. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.10.008 · Cited by 17 · see citing works

Temperature Reconstructions Using Speleothems

Meckler, A., Vonhof, H., & Martínez-García, A. (2021) · Elements · doi:10.2138/gselements.17.2.101 · Cited by 11 · see citing works

Characterization and Correction of Evaporative Artifacts in Speleothem Fluid Inclusion Isotope Analyses as Applied to a Stalagmite From Borneo

Fernández, Á., Løland, M. H., Maccali, J., Krüger, Y. S., Vonhof, H., Sodemann, H., & Meckler, A. N. (2023) · Geochemistry Geophysics Geosystems · doi:10.1029/2023gc010857 · Cited by 14 · see citing works

Precipitation of CaCO3 in natural and man-made aquatic environments - Mechanisms, analogues, and proxies

Dietzel, M., & Boch, R. (2024) · Geochemistry · doi:10.1016/j.chemer.2024.126206 · Cited by 14 · see citing works

Holocene Hydroclimate Variability Along the Southern Patagonian Margin (Chile) Reconstructed from Cueva Chica Speleothems

Nehmé, C., Todisco, D., Breitenbach, S. F. M., Couchoud, I., Marchegiano, M., Peral, M., Vonhof, H., Hellström, J., Tjallingii, R., Claeys, P., et al. (2022) · Global and Planetary Change · doi:10.1016/j.gloplacha.2023.104050 · Cited by 14 · see citing works

Dual clumped isotope data for amorphous carbonates and transformation products reveal a novel mechanism for disequilibrium clumped isotope effects

Lucarelli, J., Purgstaller, B., Ulrich, R., Parvez, Z. A., Leis, A., Goetschl, K. E., Eagle, R., Dietzel, M., & Tripati, A. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.07.027 · Cited by 12 · see citing works

Dual clumped isotopes (Δ47 and Δ48) reveal non-equilibrium formation of freshwater cements

Lu, C., Murray, S. T., Klaus, J. S., McNeill, D. F., & Swart, P. K. (2024) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2024.06.037 · Cited by 11 · see citing works

Biologically driven isotopic fractionations in bivalves: from palaeoenvironmental problem to palaeophysiological proxy

Curley, A. N., Petersen, S. V., Edie, S. M., & Guo, W. (2023) · Biological Reviews · doi:10.1111/brv.12940 · Cited by 11 · see citing works

Millennial-scale climate variability in the Northern Hemisphere influenced glacier dynamics in the Alps around 250,000 years ago

Skiba, V., Spötl, C., Trüssel, M., Schröder‐Ritzrau, A., Schröder, B., Frank, N., Eichstädter, R., Tjallingii, R., Marwan, N., Zhang, X., et al. (2023) · Communications Earth & Environment · doi:10.1038/s43247-023-01083-y · Cited by 11 · see citing works

Modeling and interpreting triple oxygen isotope variations in vertebrates, with implications for paleoclimate and paleoecology

Hu, H.-T., Passey, B., Lehmann, S., Levin, N., & Johnson, B. J. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121812 · Cited by 10 · see citing works

A clumped isotope calibration of coccoliths at well-constrained culture temperatures for marine temperature reconstructions

Clark, A. J., Torres-Romero, I., Jaggi, M., Bernasconi, S. M., & Stoll, H. M. (2024) · Climate of the Past · doi:10.5194/cp-20-2081-2024 · Cited by 10 · see citing works

Investigation of disequilibrium clumped isotope fractionation in (speleothem) CaCO3 with cave analogous laboratory experiments using thin films of flowing solution

Hansen, M., Kluge, T., & Scholz, D. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.12.019 · Cited by 10 · see citing works

Investigating the palaeoenvironmental context of Late Pleistocene human dispersals into Southeast Asia: a review of stable isotope applications

McAllister-Hayward, M. S., Morley, M. W., Tyler, J. J., McInerney, F. A., & Blyth, A. J. (2022) · Archaeological and Anthropological Sciences · doi:10.1007/s12520-022-01540-3 · Cited by 10 · see citing works

Speleothems in subglacial caves: An emerging archive of glacial climate history and mountain glacier dynamics

Spötl, C., Baker, J. L., Skiba, V., Honiat, A., Fohlmeister, J., Luetscher, M., & Trüssel, M. (2024) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2024.108684 · Cited by 9 · see citing works

Microbial Autotrophy Recorded by Carbonate Dual Clumped Isotope Disequilibrium

Ingalls, M., Leapaldt, H. C., & Lloyd, M. K. (2024) · Geochemistry Geophysics Geosystems · doi:10.1029/2024gc011590 · Cited by 9 · see citing works

Dual carbonate clumped isotopes (Δ47-Δ48) constrains kinetic effects and timescales in peridotite-associated springs at the Cedars, Northern California

Parvez, Z. A., Lucarelli, J. K., Matamoros, I. W., Rubi, J., Miguel, K., Elliott, B., Flores, R., Ulrich, R. N., Eagle, R. A., Watkins, J. M., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.022 · Cited by 9 · see citing works

Paired Δ47-Δ48 measurements constrain different sources of kinetic isotope effects and quasi-equilibrium signatures in cave carbonates

Parvez, Z. A., El-Shenawy, M., Lucarelli, J., Kim, S.-T., Johnson, K., Wright, K., Gebregiorgis, D., Montanez, I. P., Wortham, B., Asrat, A., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.11.017 · Cited by 9 · see citing works

The influence of hydrodynamics on the carbon isotope composition of inorganically precipitated calcite

Yan, H., Dreybrodt, W., Bao, H., Peng, Y., Wei, Y., Ma, S., Mo, B., Sun, H., & Liu, Z. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116932 · Cited by 8 · see citing works

Most bivalves and gastropods calcify indistinguishably from dual clumped isotope equilibrium

Schlidt, V., Evans, D., de Winter, N. J., Bernecker, M., Arndt, I., Staudigel, P. T., Davies, A., Brand, U., Müller, W., & Fiebig, J. (2025) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2025.10.008 · Cited by 10 · see citing works

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Affek, H., Vieten, R., Barkan, E., Levi, Y., Ayalon, A., Bar-Matthews, M., Fishman, E., & Assor, A. (2023) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2023.118366 · Cited by 6 · see citing works

Speleothem growth and stable carbon isotopes as proxies of the presence and thermodynamical state of glaciers compared to modelled glacier evolution in the Alps

Skiba, V., Jouvet, G., Marwan, N., Spötl, C., & Fohlmeister, J. (2023) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2023.108403 · Cited by 6 · see citing works

Geothermometry of calcite spar at 10–50 °C

Koltai, G., Kluge, T., Krüger, Y. S., Spötl, C., Rinyu, L., Audra, P., Honiat, C., Leél‐Őssy, S., & Dublyansky, Y. V. (2024) · Scientific Reports · doi:10.1038/s41598-024-51937-4 · Cited by 6 · see citing works

Coevolutions of terrestrial temperature and monsoonal precipitation amounts from the latest Pleistocene to the mid-Holocene in Japan: Carbonate clumped isotope record of a stalagmite

Kato, H., Mori, T., Amekawa, S., Wu, C.-C., Shen, C.-C., & Kano, A. (2023) · Chemical Geology · doi:10.1016/j.chemgeo.2023.121390 · Cited by 6 · see citing works

Extreme triple oxygen isotope fractionation in Equisetum

Sharp, Z. D., Wostbrock, J. A. G., Gargano, A. M., Hare, V., Johnson, J., Cerling, T. E., Banerjee, P., Peshek, C., Knutson, C., Hartzell, L., et al. (2025) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2507455122 · Cited by 5 · see citing works

17Oexcess in Devils Hole calcite: an indicator of equilibrium fractionation and paleo moisture sources

Affek, H. P., Barkan, E., Tal, Y., Steidle, S. D., Wendt, K. A., Spötl, C., Edwards, R. L., Fishman, E., & Dublyansky, Y. V. (2025) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2025.119528 · Cited by 6 · see citing works

Kinetic fractionation of the isotope composition of 18O, 13C, and of clumped isotope 18O13C in calcite deposited to speleothems. Implications to the reliability of the 18O and Δ47 paleothermometers

Dreybrodt, W. (2019) · Acta Carsologica · doi:10.3986/ac.v48i3.7710 · Cited by 5 · see citing works

Non-Linear Clumped Isotopes from DIC Endmember Mixing and Kinetic Isotope Fractionation in High pH Anthropogenic Tufa

Holdsworth, C., MacDonald, J., & John, C. M. (2022) · Minerals · doi:10.3390/min12121611 · Cited by 5 · see citing works

Characterization and correction of evaporative artefacts in speleothem fluid inclusion isotope analyses as applied to a stalagmite from Borneo.Preprint

Fernández, Á., Løland, M. H., Maccali, J., Krüger, Y. S., Vonhof, H., Sodemann, H., & Meckler, A. N. (2023) · doi:10.22541/essoar.167340715.57808428/v1 · Cited by 5 · see citing works

Experimental Constraints on Clumped Isotope Fractionation During BaCO3 Precipitation

Guo, Y., Deng, W., & Wei, G. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010249 · Cited by 4 · see citing works

Assessing the effects of embedding resins on carbonate stable and clumped isotope analyses

Guo, J., Zong, X., de Winter, N. J., Goudsmit, B., Peterse, F., & Ziegler, M. (2023) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9597 · Cited by 4 · see citing works

Development of a quantum cascade laser absorption spectrometer for simultaneous measurement of 13C–18O and 18O–18O clumping in CO2

Wieman, S., Kapit, J., Michel, A. P. M., & Guo, W.-F. (2024) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9836 · Cited by 2 · see citing works

Holocene Temperature Trend Inferred From Oxygen and Carbonate Clumped Isotope Profiles of a Stalagmite Collected From a Maritime Area of Central Honshu, Japan

Murata, A., Mori, T., Kato, H., Hu, H.-M., Shen, C.-C., Senda, R., Kashiwagi, K., & Kano, A. (2024) · Island Arc · doi:10.1111/iar.70002 · Cited by 2 · see citing works

Equilibrated gas and carbonate standard-derived paired clumped isotope (Δ47 and Δ48) values on the absolute reference framePreprint

Lucarelli, J., Carroll, H. M., Elliott, B. M., Eagle, R. A., & Tripati, A. (2021) · doi:10.31223/x5t318 · Cited by 2 · see citing works

Clumped Isotope Temperature Reconstruction Using Stalagmite Drip Cups

Umbo, S., Box, M., Intveld, A., Longman, J., Modestou, S., Carolin, S., James, D. H., Martínez-García, A., Lope, C., Brenner, M., et al. (2026) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.70027 · Cited by 1 · see citing works

Integration of Geological, Mineralogical and Geochemical Methods in the Characterization of El Nitro and Las Alsacias Caves, Zapatoca (Colombia)

Zafra-Otero, D., & Rios, C. A. (2020) · Gestión y Ambiente · doi:10.15446/ga.v23n2.89675

Co-evolutions of terrestrial temperature and seasonal precipitation from the latest Pleistocene to the mid-Holocene in Japan: carbonate clumped isotope record of a stalagmitePreprint

Kato, H., Mori, T., Amekawa, S., Wu, C.-C., Shen, C.-C., & Kano, A. (2021) · Research Square · doi:10.21203/rs.3.rs-993823/v1 · Cited by 1 · see citing works

Do mesmo direito de amar ao direito de amar o mesmo: superando os óbices ao reconhecimento jurídico e social das familias homoafetivas no Brasil

Madeira, S. D., & Brauner, M. C. C. (2012) · LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas)

Co-evolutions of temperature and monsoonal precipitation patterns from the latest Pleistocene to the mid-Holocene in Japan: Carbonate clumped isotope record of a stalagmitePreprint

Katō, H., Mori, T., Amekawa, S., Chung‐Che, W., Shen, C., & Kano, A. (2022) · Research Square · doi:10.21203/rs.3.rs-1454058/v1

Holocene Hydroclimate Variability Along the Southern Patagonian Margin (Chile) Reconstructed from Cueva Chica SpeleothemsPreprint

Nehme, C., Todisco, D., Breitenbach, S., Couchoud, I., Marchegiano, M., Peral, M., Vonhof, H., Hellstrom, J., Tjallingi, R., Claeys, P., et al. (2023) · Social Science Research Network · doi:10.2139/ssrn.4172978 · Cited by 13 · see citing works

Dual carbonate clumped isotopes (Δ47-Δ48) constrains kinetic effects and timescales in peridotite-associated springs at The Cedars, Northern CaliforniaPreprint

Parvez, Z., Lucarelli, J., Matamoros, I., Rubi, J., Miguel, K., Elliott, B. M., Flores, R., Ulrich, R. N., Eagle, R. A., Watkins, J. M., et al. (2023) · doi:10.1002/essoar.10511830.2

Comment on egusphere-2023-2581

Clark, A. J., Torres-Romero, I., Jaggi, M., et al. (2024) · doi:10.5194/egusphere-2023-2581-rc1

Comment on egusphere-2023-2581

Clark, A. J., Torres-Romero, I., Jaggi, M., et al. (2024) · doi:10.5194/egusphere-2023-2581-rc2

Reply on RC2

Clark, A. J. (2024) · doi:10.5194/egusphere-2023-2581-ac2

Reply on RC1

Clark, A. J. (2024) · doi:10.5194/egusphere-2023-2581-ac1

Direct dating of a laminated speleothem coating a karst wall in southeastern Gaspé Peninsula, Quebec, Canada: Carboniferous, not Silurian

Pinet, N., Petts, D. C., Jautzy, J. J., Davis, W. J., & Larmagnat, S. (2025) · Canadian Journal of Earth Sciences · doi:10.1139/cjes-2024-0113

A Coral Biomineralization Model for Dual Clumped Isotopes

Watkins, J. M., Jia, Q., Zhang, S., Devriendt, L. S., & Chen, S. (2025) · Geochemistry Geophysics Geosystems · doi:10.1029/2025gc012263

Clumped isotope measurements on nanomoles of CO 2 using a hollow core fiber-based spectrometer

Wieman, S. T., Kapit, J., Guo, W., & Michel, A. P. M. (2025) · Optics Express · doi:10.1364/oe.582189

Spectroscopie optique haute performance pour l'étude des anomalies isotopiques du CO2 dans les carbonates naturels

Chaillot, J. (2022) · doi:10.70675/0719bdc2z305dz442cz8effz9aae5af9497e

Millennial‐Scale Temperature Evolution in East Asia During the Last Glacial: Constraints from Speleothem Δ 47 Thermometry

Xue, S., Liu, Y., Zhang, H., Chang, B., Griffiths, M. L., Defliese, W. F., Huang, J., Xu, Z., Luo, G., Zhu, Z., et al. (2026) · Journal of Geophysical Research Atmospheres · doi:10.1029/2025jd046164

Δ47-Δ48 systematics of speleothem carbonate

Fiebig, J., Spötl, C., Moreno, A., Zhang, H., Bernecker, M., Staudigel, P. T., Curley, A. N., Meckler, A. N., Markowska, M., Schröder, J., et al. (2026) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2026.05.007

Alpine speleothem records millennial-scale climate variability during Marine Isotope Stage 10

Honiat, A., Honiat, C., Luetscher, M., Edwards, R., & Spötl, C. (2026) · Quaternary Science Advances · doi:10.1016/j.qsa.2026.100332

The triple oxygen isotope compositions of land snail shells: implications for paleo-humidity and precipitation δ18O reconstructions

Wu, W.-J., Bao, R., Yan, H., Da, J., Xia, Z.-Y., Li, C.-L., Sheng, X.-F., & Chen, J. (2027) · Chemical Geology · doi:10.1016/j.chemgeo.2026.123780

Global high rates of anaerobic methane oxidation at marine cold seeps recorded by isotope bonding in seep carbonates

Wieman, S. T., & Guo, W. (2026) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2533639123

Accounting for kinetic isotope effects in Soreq Cave (Israel) speleothems

Affek, H. P., Matthews, A., Ayalon, A., Bar‐Matthews, M., Burstyn, Y., Zaarur, S., & Zilberman, T. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.008 · Cited by 62 · see citing works

ISOLUTION 1.0: an ISOtope evoLUTION model describing the stable oxygen (δ18O) and carbon (δ13C) isotope values of speleothems

Mainz, J. G.-U., Deininger, M., Scholz, D., & Mainz, J. G.-U. (2019) · International Journal of Speleology · doi:10.5038/1827-806x.48.1.2219 · Cited by 24 · see citing works

13C18O clumping in speleothems: observations from natural caves and precipitation experiments

Daëron, M., Guo, W., Eiler, J., Genty, D., Blamart, D., Boch, R., Drysdale, R., Maire, R., Wainer, K., & Zanchetta, G. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.10.032 · Cited by 182 · see citing works

An Introduction to Karst-Related Mineral Deposits

Bosák, P. (1989) · Developments in earth surface processes · doi:10.1016/b978-0-444-98874-4.50027-6 · Cited by 3 · see citing works

Absolute speleo-thermometry, using clumped isotope measurements to correct for kinetic isotope fractionations induced by CO_2 degassing

Daëron, M., Guo, W., Eiler, J. M., Genty, D., Wainer, K. A. I., Affek, H. P., Vonhof, H., & Blamart, D. (2008) · CaltechAUTHORS (California Institute of Technology) · doi:10.1016/j.gca.2008.05.006 · Cited by 5 · see citing works