Quantifying kinetic fractionation in Bunker Cave speleothems using Δ47
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This inverse correlation was observed in modern speleothems, which are potentially more susceptible to kinetic isotope effects than carbonates precipitated in bulk solution.
“This inverse correlation was observed in modern speleothems (Daëron et al., 2011; Wainer et al., 2011; Kluge and Affek, 2012; Kluge et al., 2013), which are potentially more susceptible to kinetic isotope effects than carbonates precipitated in bulk solution (Affek et al., 2008).”
From Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6-95 °C temperature range (2015) · cites this paper as Kluge and Affek, 2012
Notable exceptions to equilibrium clumped-isotope temperatures include speleothems and low-temperature corals.
“Notable exceptions include speleothems (Kluge and Affek, 2012; Kluge et al., 2014) and low-temperature corals (Saenger et al., 2012).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Kluge and Affek, 2012
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Δ47-Δ48 systematics of speleothem carbonate
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- Authors
- Kluge, T., & Affek, H. P.
- Affiliations
- Yale University (US)
- Corresponding author
- Kluge, Tobias
- Venue
- Quaternary Science Reviews
- Publisher
- Elsevier BV
- Published
- 2012-08
- Volume
- 49
- Pages
- 82-94
- ISSN
- 0277-3791 (ISSN-L)
- OpenAlex
- W2122535176
- Cited by
- 86
- References
- 104
- Citations by year
- 2026: 3 · 2025: 2 · 2024: 4 · 2023: 7 · 2022: 5 · 2021: 9 · 2020: 4 · 2019: 10 · 2018: 6 · 2017: 2 · 2016: 5 · 2015: 12 · 2014: 9 · 2013: 5 · 2012: 3
- FWCI
- 6.34
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Quaternary Science Reviews (publishedVersion)
- Funders
- National Science Foundation
- Yale University
- Deutsche Forschungsgemeinschaft
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Karst Systems and Hydrogeology
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- kinetic isotope fractionation, clumped isotopes, speleothems, stalagmites, non-equilibrium effects, prior calcite precipitation, speleothem growth rate, paleoclimate, cave carbonates
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