Glacial/interglacial temperature variations in Soreq cave speleothems as recorded by “clumped isotope” thermometry
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Clumped isotope constraints on the terrestrial paleoenvironment have advanced understanding of the geosphere, atmosphere, biosphere, and their interactions.
“Clumped isotope constraints on the terrestrial paleoenvironment have advanced understanding of the geosphere, atmosphere, biosphere, and their interactions, setting the stage for future discoveries.”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Affek et al. 2008
Speleothems are a climate archive heavily leveraged for δ18O but displayed complicating disequilibrium signals in 47 due to rapid degassing and rapid precipitation.
“Speleothems are another climate archive that has been heavily leveraged for δ 18 O but displayed complicating disequilibrium signals in 47 due to rapid degassing and rapid precipitation (Affek et al. 2008, Daëron et al. 2011, Wainer et al. 2011, Kluge & Affek 2012; but see Meckler et al. 2015).”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Affek et al. 2008
In cases of limited degassing and very slow carbonate precipitation, the DIC can approach full oxygen isotope exchange with water, leading to equilibrium δ18O and Δ47 values.
“In cases of limited degassing and very slow carbonate precipitation, the DIC can approach full oxygen isotope exchange with water, leading to equilibrium δ 18 O and Δ 47 values (Affek et al., 2008).”
From Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6-95 °C temperature range (2015) · cites this paper as Affek et al., 2008
In pools, with slow carbonate deposition, oxygen isotope exchange between dissolved bicarbonate and H2O drives oxygen and clumped isotope values towards equilibrium.
“In pools, with slow carbonate deposition, oxygen isotope exchange between dissolved bicarbonate and H2O drives oxygen and clumped isotope values towards equilibrium.”
From Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6-95 °C temperature range (2015) · cites this paper as Affek et al., 2008
Cites
On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale
McCrea, J. M. (1950) · The Journal of Chemical Physics · doi:10.1063/1.1747785 · Cited by 3,742 · see citing works
Compilation of stable isotope fractionation factors of geochemical interest
Friedman, I., & O'Neil, J. R. (1977) · Professional Paper · doi:10.3133/pp440kk · Cited by 2,646 · see citing works
Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates
Kim, S.-T., & O'Neil, J. R. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00169-5 · Cited by 2,558 · see citing works
Revised Carbonate-water isotopic temperature scale
EPSTEIN, S., BUCHSBAUM, R., LOWENSTAM, H. A., & UREY, H. C. (1953) · Geological Society of America Bulletin · doi:10.1130/0016-7606(1953)64[1315:rcits]2.0.co;2 · Cited by 2,271 · cited 2× · see citing works
“Epstein et al., 1953; Emiliani, 1966; O’Neil et al., 1969; Kim and O’Neil, 1997).”
13C–18O bonds in carbonate minerals: a new kind of paleothermometer
Ghosh, P., Adkins, J., Affek, H., Balta, B., Guo, W., Schauble, E. A., Schrag, D., & Eiler, J. M. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.11.014 · Cited by 914 · see citing works
Self-citationMeasurement of ratios of total oxygen of carbonates
Sharma, T., & Clayton, R. N. (1965) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(65)90011-6 · Cited by 433 · see citing works
Phosphoric acid fractionation factors for calcite and aragonite between 25 and 75 °C: Revisited
Kim, S.-T., Mucci, A., & Taylor, B. E. (2007) · Chemical Geology · doi:10.1016/j.chemgeo.2007.08.005 · Cited by 374 · cited 4× · see citing works
“This value was recently corrected to 10.25& ( Kim et al., 2007 ) requiring a corresponding modification for acalcite–H2O .W e use the modification given by Bohm et al. (2000): 1000 lnacalcite–H2O = 18.03 � 10 3 /T � 32.17, with T in Kelvin.”
MethodInfluential18O13C16O in Earth’s atmosphere
Eiler, J. M., & Schauble, E. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2004.05.035 · Cited by 362 · cited 2× · see citing works
“C, which is assumed to have a random distribution of isotopes among all isotopologues (Eiler and Schauble, 2004; a detailed description of the method is given in Affek and Eiler, 2006).”
BackgroundSelf-citation
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The geochemistry of carbonate diagenesis: The past, present and future
Swart, P. K. (2015) · Sedimentology · doi:10.1111/sed.12205 · Cited by 754 · see citing works
Defining an absolute reference frame for ‘clumped’ isotope studies of CO2
Dennis, K. J., Affek, H. P., Passey, B. H., Schrag, D. P., & Eiler, J. M. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.09.025 · Cited by 627 · see citing works
“7118 K.J. Dennis et al. / Geochimica et Cosmochimica Acta 75 (2011) 7117–7131”
BackgroundInfluentialSelf-citationPassey, B. H., Levin, N. E., Cerling, T. E., Brown, F. H., & Eiler, J. M. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1001824107 · Cited by 449 · see citing works
Self-citationHuntington, K. W., Eiler, J. M., Affek, H. P., Guo, W., Bonifacie, M., Yeung, L. Y., Thiagarajan, N., Passey, B., Tripati, A., Daëron, M., et al. (2009) · Journal of Mass Spectrometry · doi:10.1002/jms.1614 · Cited by 436 · see citing works
“it is shared by all unknown samples) and may differ for different classes of carbonates for unknown reasons, such as kinetic isotope effects[18,19] or crystal-structural controls on 13C-18O ‘clumping’.”
BackgroundSelf-citationPaleoclimate reconstruction using carbonate clumped isotope thermometry
Eiler, J. M. (2011) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2011.09.001 · Cited by 436 · see citing works
Self-citationBernasconi, S. M., Müller, I. A., Bergmann, K. D., Breitenbach, S. F. M., Fernandez, A., Hodell, D. A., Jaggi, M., Meckler, A. N., Millan, I., & Ziegler, M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2017gc007385 · Cited by 301 · see citing works
“…deep time (Came et al., 2007; Cummins et al., 2014; Finnegan et al., 2011; Rodriguez-Sanz et al., 2017), past changes in continental temperatures (Affek et al., 2008; Meckler et al., 2015; Passey et al., 2010; Snell et al., 2013; Zaarur et al., 2011, 2016), palaeoelevation and uplift rates of…”
BackgroundClumped isotope thermometry of carbonatites as an indicator of diagenetic alteration
Dennis, K. J., & Schrag, D. P. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.04.005 · Cited by 292 · see citing works
“While clumped isotope paleothermometry has been used to analyze CM chondrites (Guo and Eiler, 2007) and samples from the Pleistocene (Affek et al., 2008), Miocene (Ghosh et al., 2006a) and Paleozoic (Came et al., 2007), no study has thoroughly assessed the integrity of the clumped isotope proxy over long (107–109 year…”
MethodBar-Matthews, M., & Ayalon, A. (2011) · The Holocene · doi:10.1177/0959683610384165 · Cited by 292 · see citing works
“Sr isotopic composition and trace elements (Frumkin and Stein, 2004), the isotopic composition of the fluid inclusions (Matthews et al., 2000; McGarry et al., 2004), and most recently, paleotemperature estimation using the mass 47 anomaly (‘clumped isotopes’) (Affek et al., 2008).”
BackgroundMethodSelf-citation100,000 Years of African monsoon variability recorded in sediments of the Nile margin
Revel, M., Ducassou, E., Grousset, F., Bernasconi, S., Migeon, S., Révillon, S., Mascle, J., Murat, A., Zaragosi, S., & Bosch, D. (2010) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2010.02.006 · Cited by 272 · see citing works
Kele, S., Breitenbach, S. F. M., Capezzuoli, E., Meckler, A. N., Ziegler, M., Millan, I. M., Kluge, T., Deák, J., Hanselmann, K., John, C. M., et al. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.06.032 · Cited by 261 · see citing works
“In cases of limited degassing and very slow carbonate559 precipitation, the DIC can approach full oxygen isotope exchange with water, leading to560 equilibrium δ18O and Δ47 values (Affek et al., 2008).”
Background13C–18O isotope signatures and ‘clumped isotope’ thermometry in foraminifera and coccoliths
Tripati, A. K., Eagle, R. A., Thiagarajan, N., Gagnon, A. C., Bauch, H., Halloran, P. R., & Eiler, J. M. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.07.006 · Cited by 240 · see citing works
“…(Ghosh et al., 2006b; Quade et al., 2007; Huntington et al., 2010), (b) constraining variations in terrestrial temperature using speleothems (Affek et al., 2008), (c) reconstructing Pennsylvanian and Silurian temperature and seawater d18O using well-preserved molluscs and brachiopods, to…”
BackgroundMethodSelf-citationBonifacie, M., Calmels, D., Eiler, J. M., Horita, J., Chaduteau, C., Vasconcelos, C., Agrinier, P., Katz, A., Passey, B. H., Ferry, J. M., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.11.028 · Cited by 233 · see citing works
“…bias) characteristics of the carbonate clumped isotope systematics as for example: i/ isotopic disequilibrium of 13C–18O clumping (as observed by Affek et al., 2008; Daëron et al., 2011; Saenger et al., 2012); ii/ ∆47 vital effects for some biogenic minerals; iii/ variations in 13C–18O…”
BackgroundSelf-citationThe clumped isotope geothermometer in soil and paleosol carbonate
Quade, J., Eiler, J., Daëron, M., & Achyuthan, H. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.11.031 · Cited by 226 · see citing works
Self-citationPetersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., et al. (2019) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2018gc008127 · Cited by 209 · see citing works
“, shallowwater corals, nautiloids, and brachiopods) and speleothems have been shown to deviate significantly from the generally established clumped isotope calibration line and thus were not included (Affek et al., 2008; Bajnai et al., 2018; Daëron et al., 2011; Davies & John, 2019; Dennis et al., 2013; Kluge & Affek,…”
InfluentialAlmogi-Labin, A., Bar-Matthews, M., Shriki, D., Kolosovsky, E., Paterne, M., Schilman, B., Ayalon, A., Aizenshtat, Z., & Matthews, A. (2009) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2009.07.017 · Cited by 202 · see citing works
Self-citationVaks, A., Bar-Matthews, M., Matthews, A., Ayalon, A., & Frumkin, A. (2010) · doi:10.1016/j.quascirev.2010.06.014 · Cited by 192
Self-citationGrant, K., Grimm, R., Mikolajewicz, U., Marino, G., Ziegler, M., & Rohling, E. (2016) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2016.03.026 · Cited by 184 · see citing works
“, 2012), ii) temperature variations in eastern Mediterranean surface waters and Soreq cave are coupled (Bar-Matthews et al., 2003; Affek et al., 2008), and iii) the d(18)Ospeleo and d(18)Oruber records have been previously synchronised (Grant et al.”
13C18O clumping in speleothems: observations from natural caves and precipitation experiments
Daëron, M., Guo, W., Eiler, J., Genty, D., Blamart, D., Boch, R., Drysdale, R., Maire, R., Wainer, K., & Zanchetta, G. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.10.032 · Cited by 182 · see citing works
Self-citationPronounced zonal heterogeneity in Eocene southern high-latitude sea surface temperatures
Douglas, P., Affek, H., Ivany, L., Houben, A., Sijp, W., Sluijs, A., Schouten, S., & Pagani, M. (2014) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.1321441111 · Cited by 177 · see citing works
Self-citationA revised calibration of the clumped isotope thermometer
Zaarur, S., Affek, H. P., & Brandon, M. T. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2013.07.026 · Cited by 163 · see citing works
“…to their use for monitoring instrument stability, standards are also used for establishing a reference frame for 47 data (Dennis et al., 2011; Huntington et al., 2009) and have been applied for data correction in some cases (e.g., Affek et al., 2008; Passey et al., 2010; Tripati et al., 2010).”
MethodSelf-citationAdvancements in the use of speleothems as climate archives
Wong, C. I., & Breecker, D. O. (2015) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2015.07.019 · Cited by 170 · see citing works
NALPS: a precisely dated European climate record 120–60 ka
Boch, R., Cheng, H., Spötl, C., Edwards, R., Wang, X., & Häuselmann, P. (2011) · Climate of the past · doi:10.5194/cp-7-1247-2011 · Cited by 162 · see citing works
Carbonate clumped isotope thermometry of deep-sea corals and implications for vital effects
Thiagarajan, N., Adkins, J., & Eiler, J. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.05.004 · Cited by 159 · see citing works
Self-citationBody temperatures of modern and extinct vertebrates from 13C-18O bond abundances in bioapatite
Eagle, R., Schauble, E., Tripati, A., Tütken, T., Hulbert, R., & Eiler, J. (2010) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.0911115107 · Cited by 158 · see citing works
Self-citationHill, P. S., Tripati, A. K., & Schauble, E. A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.06.018 · Cited by 155 · see citing works
“…signatures have been reported, first in warm-water aragonitic corals (Ghosh et al., 2006) and subsequently in other biogenic carbonates (Tripati et al., 2010; Thiagarajan et al., 2011; Eagle et al., 2013; Saenger et al., 2012), as well as spe-leothems (Affek et al., 2008; Daeron et al., 2011).”
BackgroundSaenger, C., Affek, H. P., Felis, T., Thiagarajan, N., Lough, J. M., & Holcomb, M. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.09.035 · Cited by 152 · see citing works
Self-citationDual clumped isotope thermometry resolves kinetic biases in carbonate formation temperatures
Bajnai, D., Guo, W., Spötl, C., Coplen, T. B., Methner, K., Löffler, N., Krsnik, E., Gischler, E., Hansen, M., Henkel, D., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-17501-0 · Cited by 147 · see citing works
Huntington, K. W., Budd, D. A., Wernicke, B. P., & Eiler, J. M. (2011) · Journal of Sedimentary Research · doi:10.2110/jsr.2011.51 · Cited by 152 · see citing works
“…temperature and d18O of water data for ancient Earth-surface deposits to constrain paleoclimate and landscape evolution (e.g., Ghosh et al. 2006b; Affek et al. 2008; Huntington et al. 2010; Passey et al. 2010), but recent studies of altered fossil shells, carbonatites, and marbles suggest that…”
BackgroundSelf-citationHe, B., Olack, G., & Colman, A. (2012) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.6436 · Cited by 141 · see citing works
Tripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., et al. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.06.021 · Cited by 139 · see citing works
Self-citationTang, J., Dietzel, M., Fernandez, A., Tripati, A. K., & Rosenheim, B. E. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.03.005 · Cited by 137 · see citing works
“Deviations of D47 from values predicted by the Ghosh et al. (2006) calibration are generally discussed in terms of non-equilibrium clumped isotopic fractionation (Affek et al., 2008; Daëron et al., 2011; Kluge and Affek, 2012; Dennis et al., 2013).”
BackgroundMethodSarıkaya, M., Zreda, M., & Çiner, A. (2009) · doi:10.1016/j.quascirev.2009.04.015 · Cited by 137
“... of Mount Erciyes) (Fig. 1a), using hydrological and isotope mass balance models and reported that LGM precipitation was 16–60% lower than today (Fig. 6). Soreq Cave data indicate drier conditions (between 20 and 50%) during the same time interval (25–17 ka ago) (Bar-Matthews et al., 1997 )( Fig. 6), however, a rec…”
BackgroundInfluentialLanggut, D., Almogi-Labin, A., Bar-Matthews, M., & Weinstein-Evron, M. (2011) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2011.10.016 · Cited by 135 · see citing works
“0 ka) was high (Frumkin et al., 1999; Bar-Matthews et al., 2003) and the temperature both in Sea and land were similar to present (Emeis et al., 2003; McGarry et al., 2004; Affek et al., 2008; Almogi-Labin et al., 2009).”
BackgroundMethodSelf-citationFrumkin, A., Bar‐Yosef, O., & Schwarcz, H. P. (2010) · Journal of Human Evolution · doi:10.1016/j.jhevol.2010.03.010 · Cited by 135 · see citing works
Halevy, I., Fischer, W., & Eiler, J. (2011) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.1109444108 · Cited by 132 · see citing works
Self-citationWarm, not super-hot, temperatures in the early Eocene subtropics
Keating-Bitonti, C., Ivany, L., Affek, H., Douglas, P., & Samson, S. (2011) · Geology · doi:10.1130/g32054.1 · Cited by 128 · see citing works
Self-citationCarbonate clumped isotope thermometry in continental tectonics
Huntington, K. W., & Lechler, A. R. (2015) · Tectonophysics · doi:10.1016/j.tecto.2015.02.019 · Cited by 127 · see citing works
“…Keating-Bitonti et al., 2011; Price and Passey, 2013; Saenger et al., 2012; Thiagarajan et al., 2011, 2014; Tripati et al., 2010), speleothems (Affek et al., 2008, 2013, 2014; Daëron et al., 2011; Kluge and Affek, 2012; Kluge et al., 2014; Wainer et al., 2011), meteorites (Guo and Eiler,…”
BackgroundInfluentialAn automated method for ‘clumped-isotope` measurements on small carbonate samples
Schmid, T. W., & Bernasconi, S. M. (2010) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.4598 · Cited by 124 · see citing works
Dennis, K., Cochran, J., Landman, N., & Schrag, D. (2013) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2012.11.036 · Cited by 114 · see citing works
“These inorganic calcite cave deposits typically record apparent clumped isotope temperatures that are higher than the environmental growth temperature (Affek et al., 2008; Daëron et al., 2011; Meckler et al., 2009).”
BackgroundInfluentialGuo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108 · see citing works
Grauel, A.-L., Schmid, T. W., Hu, B., Bergami, C., Capotondi, L., Zhou, L., & Bernasconi, S. M. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.12.049 · Cited by 111 · see citing works
Dirghangi, S. S., Pagani, M., Hren, M., & Tipple, B. (2013) · Organic Geochemistry · doi:10.1016/j.orggeochem.2013.03.009 · Cited by 109 · see citing works
“Reconstruction of ancient ocean and terrestrial temperature values is a fundamental aspect of paleoclimate research and several methodologies based on inorganic proxies (Epstein et al., 1953; Shackleton, 1967; Kennett and Shackleton, 1975; Wefer and Berger, 1991; Nürnberg et al., 1995; Rosenthal et al., 1997; Podlaha…”
BackgroundSeasonal resolution of Eastern Mediterranean climate change since 34ka from a Soreq Cave speleothem
Orland, I. J., Bar‐Matthews, M., Ayalon, A., Matthews, A., Kozdon, R., Ushikubo, T., & Valley, J. W. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.04.035 · Cited by 108 · see citing works
“…2004), the conventionally sampled 185 ka record of d18O from Soreq Cave speleothems (Bar-Matthews et al., 2003; Almogi-Labin et al., 2009), and analyses of both fluid inclusions (McGarry et al., 2004) and mass-47 CO2 isotopologue anomalies (D47) in Soreq speleothem calcite (Affek et al., 2008).”
BackgroundSelf-citationPaleo-environmental implication of clumped isotopes in land snail shells
Zaarur, S., Olack, G., & Affek, H. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.08.044 · Cited by 106 · see citing works
Self-citationA process-based model for non-equilibrium clumped isotope effects in carbonates
Watkins, J. M., & Hunt, J. D. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.09.042 · Cited by 105 · see citing works
“There are clear instances, for example in speleothems and surface corals, where clumped isotope compositions yield significant over- or under-estimates of temperature, representing clear departures from equilibrium (Affek et al., 2008; Daëron et al., 2011; Saenger et al., 2012; Affek, 2012; Eiler et al., 2014).”
BackgroundLi, T., Shen, C., Li, H., Li, J., Chiang, H., Song, S., Yuan, D., Lin, C. D.-J., Gao, P., Zhou, L., et al. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.04.003 · Cited by 121 · see citing works
Empirical calibration of the clumped isotope paleothermometer using calcites of various origins
Wacker, U., Fiebig, J., Tödter, J., Schöne, B. R., Bahr, A., Friedrich, O., Tütken, T., Gischler, E., & Joachimski, M. M. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.06.004 · Cited by 101 · see citing works
Non‐linear mixing effects on mass‐47 CO 2 clumped isotope thermometry: Patterns and implications
Defliese, W. F., & Lohmann, K. C. (2015) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7175 · Cited by 93 · see citing works
The isotopic anatomies of molecules and minerals
Eiler, J. M. (2013) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-042711-105348 · Cited by 96 · see citing works
Self-citationAffek, H. P., & Zaarur, S. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.005 · Cited by 96 · see citing works
Self-citationClumped isotope analysis of carbonates: comparison of two different acid digestion techniques
Wacker, U., Fiebig, J., & Schoene, B. R. (2013) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.6609 · Cited by 92 · see citing works
Orland, I., Burstyn, Y., Bar-Matthews, M., Kozdon, R., Ayalon, A., Matthews, A., & Valley, J. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2013.11.011 · Cited by 88 · see citing works
“Furthermore, measurements of mass-47 CO2 isotopologue anomalies (Δ47) in modern Soreq speleothems indicate that modern calcite precipitated in near-equilibrium conditions for δ(18)O although Δ47 values are not fully equilibrated (Affek et al., 2008).”
BackgroundInfluentialSelf-citationSpeleothem climate records from deep time? Exploring the potential with an example from the Permian
Woodhead, J., Reisz, R., Fox, D., Drysdale, R., Hellstrom, J., Maas, R., Cheng, H., & Edwards, R. (2010) · doi:10.1130/g30354.1 · Cited by 87
Quantifying kinetic fractionation in Bunker Cave speleothems using Δ47
Kluge, T., & Affek, H. P. (2012) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2012.06.013 · Cited by 86 · see citing works
Self-citationWilliams, M. A. J. (2018) · Cambridge University Press eBooks · doi:10.1017/9781316831885.007 · Cited by 2 · see citing works
Loyd, S. J., Sample, J., Tripati, R., Defliese, W. F., Brooks, K., Hovland, M. T., Torres, M. E., Marlow, J. J., Hancock, L. G., Martin, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms12274 · Cited by 92 · see citing works
Mathis, M., Sorrel, P., Klotz, S., Huang, X., & Oberhänsli, H. (2014) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2014.01.023 · Cited by 92 · see citing works
Determining the Δ47 acid fractionation in dolomites
Murray, S. T., Arienzo, M. M., & Swart, P. K. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.10.029 · Cited by 83 · see citing works
Eagle, R., Risi, C., Mitchell, J., Eiler, J., Seibt, U., Neelin, J., Li, G.-J., & Tripati, A. (2013) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.1213366110 · Cited by 81 · see citing works
Self-citationClumped isotopic equilibrium and the rate of isotope exchange between CO2 and water
Affek, H. P. (2013) · American Journal of Science · doi:10.2475/04.2013.02 · Cited by 76 · see citing works
Self-citationFeng, W., Casteel, R., Banner, J., & Heinze-Fry, A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.11.039 · Cited by 80 · see citing works
“Recent advances in extracting temperature related information from speleothems include application of clumped isotopes and isotopic and noble gas analysis of fluid inclusions (Affek et al., 2008; Kluge et al., 2008; Scheidegger et al., 2010).”
Douglas, P., Stolper, D., Smith, D. A., Anthony, K. W. W., Paull, C., Dallimore, S., Wik, M., Crill, P., Winterdahl, M., Eiler, J., et al. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.05.031 · Cited by 79 · see citing works
Self-citationGuo, W., & Zhou, C. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.028 · Cited by 78 · see citing works
Chapter 1 The Geochemistry of Continental Carbonates
Deocampo, D. M. (2010) · Developments in Sedimentology · doi:10.1016/s0070-4571(09)06201-3 · Cited by 77 · see citing works
Combinatorial effects on clumped isotopes and their significance in biogeochemistry
Yeung, L. Y. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.09.020 · Cited by 68 · see citing works
Falk, E. S., Guo, W., Paukert, A. N., Matter, J. M., Mervine, E. M., & Kelemen, P. B. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.06.026 · Cited by 75 · see citing works
“…clumped isotope effects also exist in nature, 120 especially for several types of carbonates, e.g. speleothems, cryogenic carbonates (e.g., 121 Affek et al., 2008; Guo 2008; Daeron et al., 2011; Wainer et al., 2011; Kluge and Affek, 122 2012; Kluge et al., 2014; Affek et al., 2014), some…”
BackgroundSorin, L., Anton, V., Miryam, B.-M., Roi, P., & Amos, F. (2010) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2010.01.018 · Cited by 75 · see citing works
Meckler, A., Affolter, S., Dublyansky, Y., Krüger, Y., Vogel, N., Bernasconi, S. M., Frenz, M., Kipfer, R., Leuenberger, M., Spötl, C., et al. (2015) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2015.06.015 · Cited by 73 · see citing works
Speleothem isotopic evidence of winter rainfall variability in northeast Turkey between 77 and 6 ka
Rowe, P., Mason, J., Andrews, J., Marca, A., Thomas, L., van Calsteren, P., Jex, C., Vonhof, H., & Al-Omari, S. (2012) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2012.04.013 · Cited by 73 · see citing works
Owen, R., Day, C., Hu, C.-Y., Liu, Y.-X., Pointing, M., Blättler, C., & Henderson, G. (2016) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2016.03.027 · Cited by 72 · see citing works
“…climate proxies have been developed and applied including δ18O and δ13C analyses (e.g. Hendy, 1971; Wang et al., 2001), trace metal contents (e.g. Ayalon et al., 1999; Gascoyne, 1983), fluid inclusion chemistry (e.g. Schwarcz et al., 1976) and clumped isotope measurements (e.g. Affek et al., 2008).”
MethodWhat do we really know about early diagenesis of non-marine carbonates?
Boever, E. D., Brasier, M., Foubert, A., & Kele, S. (2017) · Sedimentary Geology · doi:10.1016/j.sedgeo.2017.09.011 · Cited by 86 · see citing works
“However, speleothems, and also cryogenic cave carbonates, appear to be sensitive to kinetic effects during rapid CO2 degassing (Affek et al., 2008; Daëron et al., 2011; Eiler, 2011; Wainer et al., 2011; Kluge and Affek, 2012; Affek and Zaarur, 2014; Kluge et al., 2014).”
Backgroundvon Strandmann, P. V., Vaks, A., Bar-Matthews, M., Ayalon, A., Jacob, E., & Henderson, G. (2017) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2017.04.014 · Cited by 69 · see citing works
“During the last glacial, the temperatures in the region were 5–10°C lower than today (Affek et al., 2008; Almogi-Labin et al., 2009; McGarry et al., 2004).”
BackgroundInfluentialSelf-citationDevelle, A., Herreros, J., Vidal, L., Sursock, A., & Gasse, F. (2010) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2009.12.005 · Cited by 65 · see citing works
Frontiers of Carbonate Clumped Isotope Thermometry
Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66 · see citing works
Kluge, T., Affek, H., Marx, T., Aeschbach-Hertig, W., Riechelmann, D., Scholz, D., Riechelmann, S., Immenhauser, A., Richter, D., Fohlmeister, J., et al. (2013) · Climate of the past · doi:10.5194/cp-9-377-2013 · Cited by 64 · see citing works
“Contrary to the early suggestion of a constant disequilibrium offset (in Soreq Cave; Affek et al., 2008), Kluge and Affek (2012) observed temporal variations in the degree of kinetic isotope fractionation that preclude the use of constant disequilibrium offsets at least for certain speleothems or in certain caves.”
BackgroundResultInfluentialSelf-citationDevils Hole paleotemperatures and implications for oxygen isotope equilibrium fractionation
Kluge, T., Affek, H., Dublyansky, Y., & Spötl, C. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.05.047 · Cited by 63 · see citing works
Self-citationRambeau, C. (2010) · Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2010.0190 · Cited by 62
Accounting for kinetic isotope effects in Soreq Cave (Israel) speleothems
Affek, H. P., Matthews, A., Ayalon, A., Bar‐Matthews, M., Burstyn, Y., Zaarur, S., & Zilberman, T. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.008 · Cited by 62 · see citing works
Self-citationThomas, E., Clemens, S., Prell, W., Herbert, T., Huang, Y.-S., Liu, Z.-Y., Damsté, J. S. S., Sun, Y., & Wen, X. (2014) · doi:10.1130/g36289.1 · Cited by 57
Modestou, S. E., Leutert, T. J., Fernandez, A., Lear, C. H., & Meckler, A. N. (2020) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa003927 · Cited by 57 · see citing works
“…all carbonates are within error of the same calibration line (Bernasconi et al., 2018; Bonifacie et al., 2017; Kele et al., 2015; Kelson et al., 2017; Tripati et al., 2010), with very few exceptions (e.g., some corals and speleothems; Affek et al., 2008; Eagle et al., 2013; Saenger et al., 2012).”
BackgroundGuo, W., & Zhou, C. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.11.018 · Cited by 55 · see citing works
A new Dead Sea pollen record reveals the last glacial paleoenvironment of the southern Levant
Miebach, A., Stolzenberger, S., Wacker, L., Hense, A., & Litt, T. (2019) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2019.04.033 · Cited by 54
Calibrating the glycerol dialkyl glycerol tetraether temperature signal in speleothems
Blyth, A., & Schouten, S. (2013) · doi:10.1016/j.gca.2013.02.009 · Cited by 54
Hunted gazelles evidence cooling, but not drying, during the Younger Dryas in the southern Levant
Hartman, G., Bar-Yosef, O., Brittingham, A., Grosman, L., & Munro, N. (2016) · Proceedings of the National Academy of Sciences of the United States of America · doi:10.1073/pnas.1519862113 · Cited by 52
Krüger, Y., Marti, D., Staub, R., Fleitmann, D., & Frenz, M. (2011) · Chemical Geology · doi:10.1016/j.chemgeo.2011.07.009 · Cited by 52 · see citing works
A novel application of triple oxygen isotope ratios of speleothems
Sha, L., Mahata, S., Duan, P.-Z., Luz, B., Zhang, P., Baker, J., Zong, B., Ning, Y.-F., Brahim, Y. A., Zhang, H.-W., et al. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.12.003 · Cited by 51 · see citing works
Ayalon, A., Bar-Matthews, M., Frumkin, A., & Matthews, A. (2013) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2012.10.047 · Cited by 51 · see citing works
Self-citationClumped Isotope Paleothermometry: Principles, Applications, and Challenges
Affek, H. (2012) · The Paleontological Society Papers · doi:10.1017/s1089332600002576 · Cited by 51 · see citing works
Self-citationClumped-isotope thermometry of magnesium carbonates in ultramafic rocks
García del Real, P., Maher, K., Kluge, T., Bird, D. K., Brown, G. E., & John, C. M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.08.003 · Cited by 50 · see citing works
Woodhead, J., & Pickering, R. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.06.017 · Cited by 50 · see citing works
Controls on denudation rates in tectonically stable Mediterranean carbonate terrain
Ryb, U., Matmon, A., Erel, Y., Haviv, I., Katz, A., Starinsky, A., Angert, A., & A. Team (2014) · doi:10.1130/b30886.1 · Cited by 49
Paleoclimate Variability in the Mediterranean Region
Abrantes, F., Voelker, A., Sierro, F., Naughton, F., Rodrigues, T., Cacho, I., Ariztegui, D., Brayshaw, D., Sicre, M., & Batista, L. (2010) · Elsevier eBooks · doi:10.1016/b978-0-12-416042-2.00001-x · Cited by 49 · see citing works
Levitt, N. P., Eiler, J. M., Romanek, C. S., Beard, B. L., Xu, H., & Johnson, C. M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007089 · Cited by 48 · see citing works
Self-citationMorin, E., Ryb, T., Gavrieli, I., & Enzel, Y. (2018) · Quaternary Research · doi:10.1017/qua.2018.98 · Cited by 48
Langgut, D., Almogi‐Labin, A., Bar‐Matthews, M., Pickarski, N., & Weinstein‐Evron, M. (2018) · Journal of Human Evolution · doi:10.1016/j.jhevol.2018.08.002 · Cited by 55 · see citing works
Self-citationTheoretical estimation of the equilibrium distribution of clumped isotopes in nature
Cao, X., & Liu, Y. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.11.021 · Cited by 47 · see citing works
“…2004; Wang et al., 2004; Affek and Eiler, 2006; Ghosh et al., 2006a,b; Schauble et al., 2006; Affek et al., 2007; Came et al., 2007; Eiler, 2007; Ghosh et al., 2007; Guo and Eiler, 2007; Affek et al., 2008; Guo et al., 2009; Huntington et al., 2009; Yeung et al., 2009; Eagle et al., 2010).”
Shuai, Y., Douglas, P., Zhang, S., Stolper, D. A., Ellis, G. S., Lawson, M. J., Lewan, M. D., Formolo, M. J., Mi, J., He, K., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.11.024 · Cited by 46 · see citing works
“…during isotope-exchange reactions and during the generation and destruction of carbonate minerals, CO2, CH4, C2H6, N2O and O2 (e.g., Eiler, 2007, Affek et al., 2008, Daëron et al., 2011, Passey and Henkes, 2012, Saenger et al., 2012, Clog et al., 2014, Stolper and Eiler, 2015, Stolper et al.,…”
BackgroundMethodSelf-citationGasse, F., Vidal, L., Develle, A., & Campo, E. V. (2011) · doi:10.5194/cp-7-1261-2011 · Cited by 47
Sample, J., Torres, M. E., Fisher, A., Hong, W., Destrigneville, C., Defliese, W. F., & Tripati, A. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.013 · Cited by 46 · see citing works
Loyd, S. J., Corsetti, F. A., Eagle, R. A., Hagadorn, J. W., Shen, Y., Zhang, X., Bonifacie, M., & Tripati, A. K. (2015) · Precambrian Research · doi:10.1016/j.precamres.2015.04.010 · Cited by 45 · see citing works
- Authors
- Affek, H. P., Bar-Matthews, M., Ayalon, A., Matthews, A., & Eiler, J. M.
- Affiliations
- Yale University (US)
- Geological Survey of Israel (IL)
- Hebrew University of Jerusalem (IL)
- California Institute of Technology (US)
- Corresponding author
- Affek, Hagit P.
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2008-11
- Volume
- 72
- Issue
- 22
- Pages
- 5351-5360
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2133060148
- Cited by
- 306
- References
- 0
- Citations by year
- 2026: 7 · 2025: 5 · 2024: 14 · 2023: 17 · 2022: 12 · 2021: 20 · 2020: 12 · 2019: 19 · 2018: 44 · 2017: 12 · 2016: 19 · 2015: 25 · 2014: 17 · 2013: 21 · 2012: 19
- FWCI
- 8.87
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Geochimica et Cosmochimica Acta (publishedVersion)
- CaltechAUTHORS (California Institute of Technology) (submittedVersion)
- Funders
- Israel Science Foundation
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Karst Systems and Hydrogeology
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Marine and environmental studies
- Keywords
- clumped isotope thermometry, speleothems, Last Glacial Maximum, Holocene temperature, deuterium excess, relative humidity, fluid inclusions, calcite
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