Synthesis of low-density polyethylene derived carbon nanotubes for activation of persulfate and degradation of water organic micropollutants in continuous mode
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Plastic derived carbon nanotubes (CNTs) were tested as catalysts in persulfate activation for the first time. Four catalysts were prepared by wetness impregnation and co-precipitation (using Al2O3, Ni, Fe and/or Al) and implemented to grow CNTs by chemical vapour deposition (CVD) using low-density polyethylene (LDPE) as carbon feedstock. A catalyst screening was performed in batch mode and the best performing CNTs ([email protected]+Fe/Al2O3-cp) led to a high venlafaxine mass removal rate (3.17 mg g−1 h−1) in ultrapure water after 90 min (even with a mixture of micropollutants). Its degradation increased when the matrix was replaced by drinking water and negligibly affected in surface water. A composite polymeric membrane was then fabricated with [email protected]+Fe/Al2O3-cp and polyvinylidene fluoride (PVDF), a high venlafaxine mass removal rate in surface water being also observed in 24 h of continuous operation. Therefore, the results herein reported open a window of opportunity for the valorisation of plastic wastes in this catalytic application performed in continuous mode.
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Catalysts containing Ni, Co, Al and Fe can be used in the catalytic process to convert waste plastics into carbon materials such as carbon nanotubes, carbon nanoflakes, and layered porous carbon.
“Catalysts containing Ni, Co, Al and Fe can be used in the catalytic process to convert waste plastics into carbon materials such as carbon nanotubes (Ribeiro et al. 2022), carbon nanoflakes (Liu et al. 2021b), and layered porous carbon (Ma et al. 2020).”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Ribeiro et al. 2022
Carbon nanotubes grown from low-density polyethylene on Al2O3, Ni, Fe and Al catalysts by chemical vapor deposition showed the best performance of venlafaxine removal of 3.17 mg/g/h in ultrapure water.
“Using low-density polyethylene as carbon source, carbon nanotubes were grown on Al 2 O 3 , Ni, Fe and Al catalysts by chemical vapor deposition, and the carbon nanotubes showed the best performance of venlafaxine removal of 3.17 mg/g/h in ultrapure water.”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Ribeiro et al. 2022
Catalytic carbonization of low-density polyethylene in a tubular furnace at 723 K and 1123 K for 1 h produces carbon nanotubes (Ribeiro et al., 2022).
“| Catalytic carboni- | Low-density poly- | Tubular furnace | 723 K and 1123 | Carbon nanotubes - | Ribeiro et al. (2022) | |”
From Conversion of waste plastics into value-added carbon materials (2023) · cites this paper as Ribeiro et al. (2022)
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- Authors
- Ribeiro, R. S., Vieira, O., Fernandes, R., Roman, F. F., Diaz de Tuesta, J. L., Silva, A. M. T., & Gomes, H. T.
- Affiliations
- Universidade do Porto (PT)
- Universidade Politécnica de Bragança (PT)
- Corresponding author
- Ribeiro, Rui S.
- ORCID
- Venue
- Journal of Environmental Management
- Publisher
- Elsevier BV
- Published
- 2022-04
- Volume
- 308
- Pages
- 114622
- ISSN
- 0301-4797 (ISSN-L)
- OpenAlex
- W4210793867
- Cited by
- 38
- References
- 57
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 11 · 2023: 11 · 2022: 3
- FWCI
- 2.41
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Journal of Environmental Management (publishedVersion, cc-by-nc-nd)
- PubMed (publishedVersion)
- Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT) (submittedVersion, other-oa)
- Funders
- Kansainvälisen Liikkuvuuden ja Yhteistyön Keskus (UIDB/00690/2020, COMPETE2020, UIDB/50020/2020)
- Ministério da Ciência, Tecnologia e Ensino Superior (UIDB/00,690/2020, NORTE 2020, UIDP/50020/2020, NORTE-01-0145-FEDER-000069, UIDB/50020/2020, POCI-01-0145, 01-0145-FEDER-000069)
- Fundação para a Ciência e a Tecnologia (01-0145, POCI-01-0145, PTDC/EAM-AMB/31049/2017, PORTUGAL 2020, Programmatic-UIDP/50020/2020, SFRH/BD/143224/2019, POCI-01-0145-FEDER-, COMPETE_2020, NORTE2020, NORTE-01-0145-FEDER-031049, POCI-01-, /2017, UIDB/50020/2020, UIDP/50020/2020, UIDB/00690, NORTE-01-0145, NORTE-01-0145-FEDER-000069, UIDB/00690/2020)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- carbon nanotubes, low-density polyethylene, persulfate activation, advanced oxidation processes, organic micropollutants, plastic waste valorization, chemical vapor deposition, polymer membranes, polyvinylidene fluoride, continuous operation, surface water treatment, drinking water treatment
- MeSH terms
- Catalysis, Water, Water Pollutants, Chemical, Polyethylene, Nanotubes, Carbon
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