Low-temperature and high-rate-charging lithium metal batteries enabled by an electrochemically active monolayer-regulated interface
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A Li/LiCoO2 cell using a propylene carbonate-based electrolyte with fluoroethylene carbonate and LiNO3 additives displayed high-rate charge capability and superior long-term cyclability at -15 °C when coupled with an electrochemically activated solid electrolyte interphase on a lithium metal anode.
“By coupling with the electrochemically activated SEI on a lithium metal anode (LMA), a Li/LiCoO 2 cell displayed high-rate charge capability and superior long-term cyclability at -15 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [32]
Cites
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High rate and stable cycling of lithium metal anode
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Irreversible Capacities of Graphite in Low‐Temperature Electrolytes for Lithium‐Ion Batteries
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Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature
Holoubek, J., Liu, H., Wu, Z., Yin, Y., Xing, X., Cai, G., Yu, S., Zhou, H., Pascal, T. A., Chen, Z., et al. (2021) · Nature Energy · doi:10.1038/s41560-021-00783-z · Cited by 851 · see citing works
Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries
Tan, S., Shadike, Z., Cai, X., Lin, R., Kludze, A., Borodin, O., Lucht, B. L., Wang, C., Hu, E., Xu, K., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00199-1 · Cited by 118 · see citing works
“Gao et al. [32] demonstrated a possible utilization of PC-based electrolytes with fluoroethylene carbonate (FEC) and LiNO 3 additives for LT lithium metal batteries (LMBs).”
Wu, J.-R., Gao, Z.-Y., Wang, Y., Yang, X., Liu, Q., Zhou, D., Wang, X.-S., Kang, F.-Y., & Li, B.-H. (2022) · Nano-Micro Letters · doi:10.1007/s40820-022-00896-4 · Cited by 71 · see citing works
Guo, R., & Han, W. (2022) · Materials Today Sustainability · doi:10.1016/j.mtsust.2022.100187 · Cited by 32 · see citing works
- Authors
- Gao, Y., Rojas, T., Wang, K., Liu, S., Wang, D., Chen, T., Wang, H., Ngo, A. T., & Wang, D.
- Affiliations
- Pennsylvania State University (US)
- Argonne National Laboratory (US)
- Corresponding author
- Wang, Daiwei
- Wang, Donghai
- Venue
- Nature Energy
- Published
- 2020-06-22
- Volume
- 5
- Issue
- 7
- Pages
- 534-542
- ISSN
- 2058-7546 (ISSN-L)
- OpenAlex
- W3036650777
- Cited by
- 471
- References
- 0
- Citations by year
- 2026: 30 · 2025: 78 · 2024: 105 · 2023: 98 · 2022: 78 · 2021: 69 · 2020: 13
- FWCI
- 22.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Nature Energy (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- DOE | Office of Energy Efficiency & Renewable Energy | Vehicle Technologies Office (DE-EE0008198)
- Computing resources provided on Bebop, a high-performance computing cluster operated by the Laboratory Computing Resource Center at Argonne National Laboratory
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- lithium metal batteries, low-temperature operation, fast charging, self-assembled monolayers, solid electrolyte interphase, lithium dendrite suppression, lithium fluoride, LiCoO2 cathode, galvanic corrosion, self-discharge
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