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Total alkalinity: The explicit conservative expression and its application to biogeochemical processes
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“During that time, biological processes within the subducted water mass may consume some of the unequilibrated alkalinity, however this will have no impact on atmospheric CO2 until the water mass resurfaces. 64”
From A framework for understanding efficiency losses of Ocean Alkalinity Enhancement (2026) · cites this paper as [64]
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Cites
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Einige Bemerkungen über den Begriff der Säuren und Basen
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Denitrification and N2 fixation in the Pacific Ocean
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Cited by
Sorted by citations
Items 301–400 of 781
Cohen, S., Krueger, T., & Fine, M. (2017) · PeerJ · doi:10.7717/peerj.3749 · Cited by 23
Water membrane for carbon dioxide separation
Jung, W., Lee, J. S., Yoon, H., Kim, T., & Kim, Y. H. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.04.054 · Cited by 18
Primary producers may ameliorate impacts of daytime CO 2 addition in a coastal marine ecosystem
Bracken, M. E. S., Silbiger, N. J., Bernatchez, G., & Sorte, C. J. B. (2018) · PeerJ · doi:10.7717/peerj.4739 · Cited by 20
“…a constant salinity and corrected for dissolved inorganic nitrogen and phosphorus to account for their small contributions to the acid–base system (Wolf-Gladrow et al., 2007), including the potential for primary producers to change alkalinity via nutrient uptake (Brewer & Goldman, 1976; Stepien,…”
BackgroundRassmann, J., Lansard, B., Gazeau, F., Guidi-Guilvard, L. D., Pozzato, L., Alliouane, S., Grenz, C., & Rabouille, C. (2018) · Marine Chemistry · doi:10.1016/j.marchem.2018.05.006 · Cited by 20
Tison, J., Delille, B., & Papadimitriou, S. (2016) · Wiley eBooks · doi:10.1002/9781118778371.ch18 · Cited by 20
Biological Responses to Ocean Acidification Are Changing the Global Ocean Carbon Cycle
Barrett, R. C., Carter, B. R., Fassbender, A. J., Tilbrook, B., Woosley, R. J., Azetsu‐Scott, K., Feely, R. A., Goyet, C., Ishii, M., Murata, A. M., et al. (2025) · Global Biogeochemical Cycles · doi:10.1029/2024gb008358 · Cited by 17
Implications of salinity normalization of seawater total alkalinity in coral reef metabolism studies
Courtney, T. A., Cyronak, T. J., Griffin, A. J., & Andersson, A. J. (2021) · PLoS ONE · doi:10.1371/journal.pone.0261210 · Cited by 17
“Furthermore, TA is conservative with respect to mixing and changes in seawater temperature and pressure [8].”
BackgroundKerr, D. E., Turner, C., Grey, A., Keogh, J. A. B., Brown, P. J., & Kelleher, B. P. (2023) · Marine Chemistry · doi:10.1016/j.marchem.2023.104234 · Cited by 17
Corbett, T. D. W., Westholm, M., Rosling, A., Calogiuri, T., Poetra, R. P., Niron, H., Hagens, M., Vidal, A., van Groenigen, J. W., Hartmann, J., et al. (2024) · npj Materials Degradation · doi:10.1038/s41529-024-00454-w · Cited by 20
“Monitoring the release of appropriate olivine dissolution products can enable the determination of olivine dissolution rate 53,54 , given the non-stoichiometricreleaseofmagnesiumandothercations 52 ,totalalkalinitywas used to calculate weathering rate.”
MethodCarbonate system parameters and anthropogenic CO2 in the North Aegean Sea during October 2013
Krasakopoulou, Ε., Souvermezoglou, E., Giannoudi, L., & Goyet, C. (2017) · Continental Shelf Research · doi:10.1016/j.csr.2017.04.002 · Cited by 17
Ouyang, Z., Chen, R., Liu, Q., He, L., Cai, W., & Yin, K. (2018) · Marine Chemistry · doi:10.1016/j.marchem.2018.04.002 · Cited by 18
Potential Impacts of Climate Interventions on Marine Ecosystems
Roberts, K. D., Rohr, T. W., Raven, M. R., Diamond, M., Visioni, D., Kravitz, B., Heneghan, R., Petrik, C. M., Bianchi, D., Ortega‐Cisneros, K., et al. (2026) · Reviews of Geophysics · doi:10.1029/2024rg000876 · Cited by 21
Decomposition of fluoropolymers by their mineralization in subcritical water
Hori, H., & Honma, R. (2020) · Elsevier eBooks · doi:10.1016/b978-0-12-821966-9.00011-0 · Cited by 16
Biocement from the ocean: Hybrid microbial-electrochemical mineralization of CO2
Kludze, A., Solanki, D., Lejeune, M., Yanagi, R., Ishii, M., Raychaudhuri, N., Anastas, P. T., Boyle, N. R., & Hu, S. (2022) · iScience · doi:10.1016/j.isci.2022.105156 · Cited by 16
“By applying a charge-neutrality condition, an explicitly conservative TA, which defines alkalinity as the difference in its conservative cations and anions can be derived (Equation 9) (Wolf-Gladrow et al., 2007).”
BackgroundMethodInfluentialCO 2 or Carbonates – What is the Active Species in Electrochemical CO 2 Reduction over Fe‐Porphyrin?
Khakpour, R., Lindberg, D., Laasonen, K. E., & Busch, M. (2023) · ChemCatChem · doi:10.1002/cctc.202201671 · Cited by 18
Devillier, V. M., Hall, E. R., Lovko, V., Pierce, R. H., Anderson, D. M., & Lewis, K. A. (2024) · Harmful Algae · doi:10.1016/j.hal.2024.102609 · Cited by 16
Humphreys, M. P., Griffiths, A., Achterberg, E. P., Holliday, N. P., Rérolle, V. M. C., Barraqueta, J. M., Couldrey, M. P., Oliver, K. I. C., Hartman, S. E., Espósito, M., et al. (2016) · Global Biogeochemical Cycles · doi:10.1002/2015gb005246 · Cited by 16
“SEAWATER DIC AT THE EXTENDED ELLETT LINE 8 from the Labrador Sea to the northeast Atlantic [Yashayaev et al., 2007].”
BackgroundSokołowski, A., Brulińska, D., Mirny, Z., Burska, D., & Pryputniewicz-Flis, D. (2017) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2017.09.037 · Cited by 16
“The supply seawater, its flow, and basic hydrological parameters (salinity, pH, temperature, dissolved oxygen concentration, total alkalinity (TA; Wolf-Gladrow et al., 2007) and carbonate hardness (KH)) were monitored above the sediment in each bucket every three days throughout the experiment.”
MethodSokołowski, A., & Brulińska, D. (2018) · Marine Environmental Research · doi:10.1016/j.marenvres.2018.06.018 · Cited by 16
Mortenson, E., Steiner, N. S., Monahan, A. H., Miller, L. A., Geilfus, N., & Brown, K. A. (2018) · Journal of Geophysical Research Oceans · doi:10.1029/2018jc014376 · Cited by 16
Roobaert, A., Resplandy, L., Laruelle, G. G., Liao, E., & Regnier, P. A. G. (2022) · Ocean science · doi:10.5194/os-18-67-2022 · Cited by 16
Gradoville, M. R., White, A., & Letelier, R. M. (2014) · PLoS ONE · doi:10.1371/journal.pone.0110660 · Cited by 16
“4:1 S:P uptake ratio (as in [33]), we estimate that the average PO4 drawdown of ,9 mM observed in our experiment (see Results and Discussion) increased TA by an average of ,52 mM by day 5, generating a maximum pCO2 error of ,2%.”
BackgroundMethodThe internal consistency of the North Sea carbonate system
Salt, L. A., Thomas, H., Bozec, Y., Borges, A. V., & de Baar, H. J. W. (2015) · Journal of Marine Systems · doi:10.1016/j.jmarsys.2015.11.008 · Cited by 16
“Calcification influences the AT/DIC (X) ratio of thewaters as it removes one mole of DIC per 2 moles of AT (Wolf-Gladrow et al., 2007).”
BackgroundWhen descriptive ecology meets physiology: a study in a South Atlantic rhodolith bed
de Carvalho, V. F., Silva, J., Kerr, R., Anderson, A. B., Bastos, E., Cabral, D. Q., Gouvêa, L. P., Peres, L., Martins, C. D. L., Silveira-Andrade, V. M., et al. (2020) · Journal of the Marine Biological Association of the United Kingdom · doi:10.1017/s0025315420000284 · Cited by 16
“Light and dark calcification rates were estimated using the alkalinity anomaly technique (Smith & Key, 1975), where for each mole of CaCO3 precipitated, total alkalinity (At) decreases by two equivalents: Ca + 2HCO3 →CaCO3 +H2O +CO2(aq) (Johansen, 1981; Wolf-Gladrow et al., 2007).”
MethodOcean Carbon Dioxide Removal and Storage
Lee, C.-H., Subhas, A. V., Kim, J.-H., & Lee, K. (2026) · Chemical Reviews · doi:10.1021/acs.chemrev.5c00433 · Cited by 17
Growth response of Emiliania huxleyi to ocean alkalinity enhancement
Faucher, G., Haunost, M., Paul, A. J., Tietz, A. U. C., & Riebesell, U. (2025) · Biogeosciences · doi:10.5194/bg-22-405-2025 · Cited by 15
“The dissolution of the respective minerals consumes protons, and conservative cations are released, which leads to a shift of the carbonate chemistry species from CO 2 towards HCO 3-and CO 32-, thus to an increase in alkalinity (Wolf-Gladrow et al., 2007; Bach et al., 2019).”
Methods to evaluate CaCO 3 cycle modules in coupled global biogeochemical ocean models
Koeve, W., Duteil, O., Oschlies, A., Kähler, P., & Segschneider, J. (2014) · Geoscientific model development · doi:10.5194/gmd-7-2393-2014 · Cited by 16
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Dynamic Biological Functioning Important for Simulating and Stabilizing Ocean Biogeochemistry
Buchanan, P., Matear, R. J., Chase, Z., Phipps, S. J., & Bindoff, N. L. (2018) · Global Biogeochemical Cycles · doi:10.1002/2017gb005753 · Cited by 15
“The addition of NO3 molecules via nitrogen fixation and atmospheric deposition was accompanied by an addition of approximately equal amounts of protons to the water column (Wolf-Gladrow et al., 2007) and requires a reduction in alkalinity.”
BackgroundCoupling and decoupling of biogeochemical cycles in marine ecosystems
Hohn, S. (2009) · Helmholtz-Zentrum für Polar-und Meeresforschung (Alfred-Wegener-Institut) · Cited by 16
Autonomous Sensor for In Situ Measurements of Total Alkalinity in the Ocean
Schaap, A. M., Papadimitriou, S., Mawji, E., Walk, J., Hammermeister, E., Mowlem, M. C., & Loucaides, S. (2025) · ACS Sensors · doi:10.1021/acssensors.4c02349 · Cited by 14
Modelling the 13C and 12C isotopes of inorganic and organic carbon in the Baltic Sea
Gustafsson, E., Mörth, C., Humborg, C., & Gustafsson, B. G. (2015) · Journal of Marine Systems · doi:10.1016/j.jmarsys.2015.02.008 · Cited by 14
A Simplified Model to Estimate the Concentration of Inorganic Ions and Heavy Metals in Rivers
Nhantumbo, C. M. C., Larsson, R., Larson, M., Juízo, D., & Persson, K. M. (2016) · Water · doi:10.3390/w8100453 · Cited by 14
Ocean acidification state variability of the Atlantic Arctic Ocean around northern Svalbard
Jones, E. M., Chierici, M., Menze, S., Fransson, A., Ingvaldsen, R. B., & Lødemel, H. H. (2021) · Progress In Oceanography · doi:10.1016/j.pocean.2021.102708 · Cited by 14
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“1:1 eq/ mol) of organic matters, respectively (Wolf‐Gladrow et al., 2007).”
Oh, K., Han, Y., Cha, G.-Y., Valekar, A. H., Lee, M., Sivan, S. E., Kwon, Y., & Hwang, Y. K. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c03429 · Cited by 14
Simultaneous quantum yield measurements of carbon uptake and oxygen evolution in microalgal cultures
Du, N., Gholami, P., Kline, D. I., Dupont, C. L., Dickson, A. G., Mendola, D., Martz, T. R., Allen, A. E., & Mitchell, B. G. (2018) · PLoS ONE · doi:10.1371/journal.pone.0199125 · Cited by 14
Self-citationDeviation of Boron Concentration From Predictions Using Salinity in Coastal Environments
Lee, K., Lee, C., Lee, J. H., Han, I., & Kim, M. (2019) · Geophysical Research Letters · doi:10.1029/2019gl082520 · Cited by 14
Herath, I. K., Wu, S., Ma, M., & Huang, P. (2019) · The Science of The Total Environment · doi:10.1016/j.scitotenv.2019.134184 · Cited by 14
Subannual variability of total alkalinity distributions in the northeastern G ulf of M exico
Yang, B., Byrne, R. H., & Wanninkhof, R. H. (2015) · Journal of Geophysical Research Oceans · doi:10.1002/2015jc010780 · Cited by 14
Salt, L. A., Beaumont, L., Blain, S., Bucciarelli, E., Grossteffan, E., Guillot, A., L’Helguen, S., Merlivat, L., Répécaud, M., Quémener, L., et al. (2016) · Marine Chemistry · doi:10.1016/j.marchem.2016.09.003 · Cited by 14
“The change in AT is approximate as it depends on the chemical species of nitrogen used (Wolf-Gladrow et al., 2007) and it assumes accordance to fixed Redfield ratios although these are known to vary between different phytoplankton taxonomic groups (Schoemann et al.”
BackgroundComeau, S., Gattuso, J., Jeffree, R. A., & Gazeau, F. (2012) · doi:10.5194/bgd-9-6169-2012 · Cited by 14
“Net calcification rates were estimated using an adaptation of the alkalinity anomaly25 technique (Smith and Key, 1975), taking into account the contribution of NH+4 excretion on changes in AT (1 : 1 molar ratio; Wolf-Gladrow et al., 2007).”
MethodGiering, S. L. C., & Humphreys, M. P. (2017) · Encyclopedia of earth sciences series/Encyclopedia of earth sciences · doi:10.1007/978-3-319-39193-9_154-1 · Cited by 14
On calcium-to-alkalinity anomalies in the North Pacific, Red Sea, Indian Ocean and Southern Ocean
Steiner, Z., Sarkar, A., Liu, X., Berelson, W. M., Adkins, J. F., Achterberg, E. P., Sabu, P., Prakash, S., Vinaychandran, P. N., Byrne, R. H., et al. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.03.027 · Cited by 13
“In the deep-sea, and in high-nutrient low-chlorophyll regions of the ocean, AT is reduced by the production and release of nitrate, nitrite, soluble reactive phosphate (SRP), and sulfate during the oxidation of organic matter (Wolf-Gladrow et al., 2007).”
BackgroundPaquette, A. J., Vadlamani, A., Demirkaya, C., Strous, M., & Siegler, H. D. L. H. (2022) · Frontiers in Bioengineering and Biotechnology · doi:10.3389/fbioe.2022.942771 · Cited by 13
“This was caused by equilibration (outgassing) of dissolved CO2 with ambient air, increasing pH and leading to the production of CO3 2− (Wolf-Gladrow et al., 2007).”
BackgroundCryer, S. E., Evans, C., Fowell, S. E., Andrews, G., Brown, P. J., Carvalho, F., Degallerie, D., Ludgate, J., Rosado, S., SANDERS, R. J., et al. (2023) · Global Biogeochemical Cycles · doi:10.1029/2022gb007577 · Cited by 13
“During calcification TA and DIC are removed from seawater at a 2:1 ratio and hydrogen ions (H +) are released causing an overall decline in pH (Jokiel et al., 2014; Wolf-Gladrow et al., 2007).”
BackgroundAdvancing Enhanced Weathering Modeling in Soils: Critical Comparison With Experimental Data
Bertagni, M. B., Calabrese, S., Cipolla, G., Noto, L., & Porporato, A. M. (2024) · Journal of Advances in Modeling Earth Systems · doi:10.1029/2024ms004224 · Cited by 13
Gaspar, F., Pinheiro, B. R., Noriega, C., Araújo, M., Lefèvre, N., & Montes, M. D. J. F. (2018) · Ocean and Coastal Research · doi:10.1590/s1679-87592018149406601 · Cited by 14
“These processes decrease/increase the TCO2 in seawater, but not the total alkalinity since there is an adjustment of carbonate species and pH according to the equilibrium conditions (Zeebe and Wolf-Gladrow, 2001; Wolf-Gladrow et al., 2007).”
BackgroundChlorella vulgaris growth on anaerobically digested sugarcane vinasse: influence of turbidity
Serejo, M. L., Ruas, G., BRAGA, G. B., Paulo, P. L., & Boncz, M. Á. (2021) · Anais da Academia Brasileira de Ciências · doi:10.1590/0001-3765202120190084 · Cited by 13
Contribution of Marine Phytoplankton and Bacteria to Alkalinity: An Uncharacterized Component
Lee, C., Lee, K., Ko, Y. H., & Lee, J. (2021) · Geophysical Research Letters · doi:10.1029/2021gl093738 · Cited by 13
Zeldis, J., Currie, K., Graham, S. L., & Gall, M. P. (2022) · Frontiers in Marine Science · doi:10.3389/fmars.2021.803439 · Cited by 13
Zhang, Y., Gao, Y., Kirchman, D., Cottrell, M. T., Chen, R., Wang, K., Ouyang, Z., Xu, Y., Bingzhang Chen, A., Yin, K., et al. (2018) · Marine Ecology Progress Series · doi:10.3354/meps12836 · Cited by 15
Holzer, M., Kwon, E. Y., & Pasquier, B. (2021) · Global Biogeochemical Cycles · doi:10.1029/2020gb006863 · Cited by 13
Leventaki, E., Baena‐Moreno, F. M., Sardina, G., Ström, H., Ghahramani, E., Naserifar, S., Ho, P. H., Kozlowski, A. M., & Bernin, D. (2022) · Sustainability · doi:10.3390/su141710795 · Cited by 13
“…transition of CO 2 from the gas bubble to the liquid, and the chemical reaction between the absorbed CO 2 and the − − The following three different forms, the carbonate ion CO 32 − , the bicarbonate ion HCO 3 − and carbonic acid H 2 CO 3 , exist in an aqueous solution depending on the pH [32].”
Gómez-Batista, M., Métian, M., Oberhänsli, F., Pouil, S., Swarzenski, P. W., Tambutté, É., Gattuso, J., Alonso-Hernandez, C. M., & Gazeau, F. (2020) · Biogeosciences · doi:10.5194/bg-17-887-2020 · Cited by 12
The marine carbonate system variability in high meltwater season (Spitsbergen Fjords, Svalbard)
Koziorowska‐Makuch, K., Szymczycha, B., Thomas, H., & Kuliński, K. (2023) · Progress In Oceanography · doi:10.1016/j.pocean.2023.102977 · Cited by 13
Drivers of Marine CO2‐Carbonate Chemistry in the Northern Antarctic Peninsula
Santos‐Andrade, M., Kerr, R., Orselli, I. B. M., Monteiro, T., MATA, M. M., & Goyet, C. (2023) · Global Biogeochemical Cycles · doi:10.1029/2022gb007518 · Cited by 12
High-Precision In Situ Total Alkalinity Analyzer Capable of Month-Long Observations in Seawaters
Qiu, L., Li, Q., Yuan, D., Chen, J., Xie, J., Jiang, K., Guo, L., Zhong, G., Yang, B., & Achterberg, E. P. (2023) · ACS Sensors · doi:10.1021/acssensors.3c00552 · Cited by 12
Carbonate chemistry seasonality in a tropical mangrove lagoon in La Parguera, Puerto Rico
García-Troche, E., Morell, J. M., Meléndez, M., & Salisbury, J. E. (2021) · PLoS ONE · doi:10.1371/journal.pone.0250069 · Cited by 13
“Sulfate reduction produces one mole of TA per mole of organic carbon oxidized, assuming that the sulfur species are not re-oxidized to sulfate [67].”
BackgroundHori, H., Oishi, S., Kato, H., & Kodama, R. (2020) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.9b06198 · Cited by 12
Mishra, A. K., Cabaço, S. L. F., Santos, C. B. D. L., Apostolaki, E. T., Vizzini, S., & Santos, R. (2020) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2020.111824 · Cited by 12
Distributions and air-sea fluxes of CO2 in the summer Bering Sea
Chen, L., Gao, Z., Sun, H., Chen, B., & Cai, W. (2014) · Acta Oceanologica Sinica · doi:10.1007/s13131-014-0483-9 · Cited by 12
Reimagining acidic CO2 electroreduction via anion-mediated proton transfer
Wang, X., Wu, Z., Li, Z., Xie, K., Wu, Y., Yue, Y., Zhu, P., Han, Z., Gao, J., Jiang, G., et al. (2025) · National Science Review · doi:10.1093/nsr/nwaf334 · Cited by 12
“To minimize the interference of bicarbonate/carbonate ions [7 ,37 ], the electrolyte pH was initially adjusted to 4, as lowering the pH of a 0. acidic conditions, whereas non-hydrolyzable ones remain fully ionized.”
Shaw, C., Ringham, M., Carter, B. R., Tyka, M. D., & Eisaman, M. D. (2025) · Frontiers in Climate · doi:10.3389/fclim.2025.1616362 · Cited by 11
Meléndez, M., Salisbury, J. E., Gledhill, D. K., Langdon, C., Morell, J. M., Manzello, D. P., & Sutton, A. J. (2022) · Limnology and Oceanography · doi:10.1002/lno.12009 · Cited by 11
“…(Kim and Lee, 2009), anaerobic sediment diagenesis (Yamamoto et al. 2015), CaCO3 sediment calcification/dissolution (Stoltenberg et al. 2021), and nutrient transformation in macroalgae, sediments, and plankton (Wolf-Gladrow et al. 2007) were also integrated into our metabolic measurements.”
BackgroundInfluence of Rivers, Tides, and Tidal Wetlands on Estuarine Carbonate System Dynamics
Da, F., Friedrichs, M. A. M., St‐Laurent, P., Najjar, R. G., Shadwick, E. H., & Stets, E. G. (2024) · Estuaries and Coasts · doi:10.1007/s12237-024-01421-z · Cited by 10
“Because phytoplankton uptake of NH 4+ and NO 3– has opposite influences on TA (Wolf-Gladrow et al. 2007) and each uptake process is strongly influenced by tidal cycles, the net impact on TA from phytoplankton production shows little quasi-monthly variability (Fig.”
Schreiber, R. E., & Goicoechea, J. M. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202013914 · Cited by 11
Wu, Z., Qiao, W., Li, Y., Yao, J., Sun, Y., & Dong, R. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.139075 · Cited by 11
Xu, K., Li, J., Liu, F., Chen, X., Zhao, T., & Cheng, F. (2023) · Angewandte Chemie · doi:10.1002/ange.202311968 · Cited by 11
An adapted flow injection analysis method of phosphate for estuarine samples avoiding matrix effects
Kortazar, L., Alberdi, S., Tynan, E., & Fernández, L. A. (2015) · Microchemical Journal · doi:10.1016/j.microc.2015.09.027 · Cited by 11
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“36 (Wolf-Gladrow et al., 2007).”
BackgroundInfluentialEvaluating Carbonate System Algorithms in a Nearshore System: Does Total Alkalinity Matter?
Jones, J. M., Sweet, J. A., Brzezinski, M. A., McNair, H. M., & Passow, U. (2016) · PLoS ONE · doi:10.1371/journal.pone.0165191 · Cited by 11
Ma, W., Wang, P., & Tian, J. (2017) · Global and Planetary Change · doi:10.1016/j.gloplacha.2017.04.001 · Cited by 11
Hori, H., Wachi, S., Iwamura, K., & Sano, T. (2017) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2017.10.015 · Cited by 11
Paulsen, M., Andersson, A. J., Aluwihare, L. I., Cyronak, T. J., D’Angelo, S., Davidson, C., Elwany, H., Giddings, S. N., Page, H. N., Porrachia, M., et al. (2017) · Estuaries and Coasts · doi:10.1007/s12237-017-0345-8 · Cited by 11
“Although dissolved inorganic nutrients contribute to TA (Wolf-Gladrow et al. 2007), the elevated nutrient concentrations observed in the inner lagoon of SDL cannot account for the high TA concentrations alone, and other constituents and processes must be responsible.”
BackgroundHigh-Resolution Carbonate System Dynamics of Netarts Bay, OR From 2014 to 2019
Fairchild, W. W., & Hales, B. R. (2021) · Frontiers in Marine Science · doi:10.3389/fmars.2020.590236 · Cited by 11
Heinze, C., Blenckner, T., Brown, P. J., Fröb, F., Morée, A. L., New, A. L., Nissen, C., Rynders, S., Seguro, I., Aksenov, Y., et al. (2023) · BGD · doi:10.5194/bg-2023-182 · Cited by 11
Dupla, X., Bertagni, M. B., & Grand, S. (2025) · Environmental Science & Technology · doi:10.1021/acs.est.5c09820 · Cited by 10
Carbonate chemistry and CO2 dynamics in the Persian Gulf
Saleh, A., Ershadifar, H., Ghaemi, M., Vaighan, D. J., & Chen, C. A. (2025) · Marine Pollution Bulletin · doi:10.1016/j.marpolbul.2025.117804 · Cited by 10
Hammermeister, E., Papadimitriou, S., Arundell, M., Ludgate, J., Schaap, A. M., Mowlem, M. C., Fowell, S. E., Chaney, E., & Loucaides, S. (2025) · Environmental Science & Technology · doi:10.1021/acs.est.4c10139 · Cited by 10
Lammers, J. M., Schubert, C. J., Middelburg, J. J., & Reichart, G. (2017) · Biogeochemistry · doi:10.1007/s10533-017-0389-7 · Cited by 10
“2007), and oxidation of reduced nitrogen (nitrification) and sulfur, generated during remineralization of algae, will decrease alkalinity (Wolf-Gladrow et al. 2007).”
BackgroundSu, J., Cai, W., Testa, J. M., Brodeur, J., Chen, B., Scaboo, K. M., Li, M., Shen, C., Dolan, M., Xu, Y., et al. (2021) · Limnology and Oceanography · doi:10.1002/lno.11919 · Cited by 10
“Episodic wind events can cause large reductions in stratification and drive lateral circulation between the shoals and the main channel (Goodrich et al. 1987; Xie and Li 2018).”
BackgroundPiñango, A., Kerr, R., Orselli, I. B. M., Carvalho, A. D. C. D. O., Azar, E., Karstensen, J., & Garcia, C. A. E. (2022) · Global Biogeochemical Cycles · doi:10.1029/2021gb007196 · Cited by 11
“bias in our reconstruction of the Cant in the A10 section, a similar signal has been observed not only by Woosley et al. (2016) but more recently by Gao et al.”
MethodPasquier, B., Holzer, M., Chamberlain, M. A., Matear, R. J., Bindoff, N. L., & Primeau, F. (2023) · Biogeosciences · doi:10.5194/bg-20-2985-2023 · Cited by 10
“…of TA due to the cycling of carbonate, and the second term contains the contributions from nitrate, phosphate, and sulfate (for further details see Wolf-Gladrow et al., 2007) We approximate the TA inventory as being constant and hence set the global mean [TA] to 2420µM via the term, analogous to…”
Opländer, C., Volkmar, C. M., Paunel‐Görgülü, A., Fritsch, T., van Faassen, E. E., Mürtz, M., Grieb, G., Bozkurt, A., Hemmrich, K., Windolf, J., et al. (2012) · Nitric Oxide · doi:10.1016/j.niox.2012.01.007 · Cited by 10
Nhantumbo, C. M. C., Larsson, R., Larson, M., Juízo, D., & Persson, K. M. (2018) · Mine Water and the Environment · doi:10.1007/s10230-018-0515-3 · Cited by 10
Application of palm oil mill waste to enhance biogas upgrading and hornwort cultivation
Rattanaya, T., Kongjan, P., Cheewasedtham, C., Bunyakan, C., Yuso, P., Cheirsilp, B., & Jariyaboon, R. (2022) · Journal of Environmental Management · doi:10.1016/j.jenvman.2022.114678 · Cited by 10
Challener, R. C., McClintock, J. B., & Makowsky, R. (2013) · Journal of Applied Aquaculture · doi:10.1080/10454438.2013.791911 · Cited by 10
“The global impact of nutrients and organic matter on total alkalinity has been assessed (Wolf-Gladrow et al. 2007), yet fluctuations between containers and facilities is likely to occur under various conditions; future studies should investigate whether the impact these factors have on the…”
BackgroundHu, Y., Chen, L., Ren, H., & Liu, J. (2024) · Marine Environmental Research · doi:10.1016/j.marenvres.2024.106708 · Cited by 9
Water Oxidation and Degradation Mechanisms of BiVO 4 Photoanodes in Bicarbonate Electrolytes
Zhou, G., Aletsee, C. C., Lemperle, A., Rieth, T., Mengel, L., Gao, J., Tschurl, M., Heiz, U., & Sharp, I. D. (2025) · ACS Catalysis · doi:10.1021/acscatal.5c03025 · Cited by 9
Evaluating ocean alkalinity enhancement as a carbon dioxide removal strategy in the North Sea
Liu, F., Daewel, U., Kossack, J., Demir, K. T., Thomas, H., & Schrum, C. (2025) · Biogeosciences · doi:10.5194/bg-22-3699-2025 · Cited by 9
“The total alkalinity (TA) is prognostically calculated based on the contributions from nitric and phosphoric acid systems following its explicit conservative expression explained by Wolf-Gladrow et al. (2007), as is expressed:”
Antoni, D., Wichels, A., Boersma, M., & Gerdts, G. (2025) · Frontiers in Microbiomes · doi:10.3389/frmbi.2025.1606890 · Cited by 9
“Alkalization increases the pH, which reduces the availability of dissolved CO 2 and bicarbonate in the seawater (Wolf-Gladrow et al., 2007).”
Bijma, J., Hagens, M., Hammes, J. S., Planavsky, N. J., von Strandmann, P. A. E. P., Reershemius, T., Reinhard, C. T., Renforth, P., Suhrhoff, T. J., Vicca, S., et al. (2026) · Biogeosciences · doi:10.5194/bg-23-53-2026 · Cited by 22
“The term “ −[ HNO 2 ] ” was later added by Dickson (Wolf-Gladrow et al., 2007) This expression is used/applied to measure TA by titration with a strong acid (HCl); therefore, it is also called titration alkalinity Add electrically neutral compounds (in bold) on both sides in order to obtain…”
InfluentialSelf-citationWeathering without realizing inorganic CO 2 removal revealed through base cation monitoring
Vienne, A., Frings, P. J., Rijnders, J., Suhrhoff, T. J., Reershemius, T., Poetra, R. P., Hartmann, J., Niron, H., Estrada, M. P., Steinwidder, L., et al. (2026) · SOIL · doi:10.5194/soil-12-421-2026 · Cited by 20
“…explicit conservative expression for TA in water, TA = [ HCO et al., 2026; Wolf-Gladrow et al., 2007) TA can also be approximated from the sum of base cation charges, minus the sum of conservative anion charges (e.g chloride, sulphate, phosphate, nitrate) (Barker, 2013; Wolf-Gladrow et al., 2007).”
Sokołowski, A., Brulińska, D., & Sokołowska, E. (2020) · Journal of Experimental Marine Biology and Ecology · doi:10.1016/j.jembe.2020.151433 · Cited by 9
Crustose coralline algae display sensitivity to near future global ocean change scenarios
Britton, D., MUNDY, C. N., Noisette, F., McGraw, C. M., & Hurd, C. L. (2021) · ICES Journal of Marine Science · doi:10.1093/icesjms/fsab220 · Cited by 9
Metadata
- Authors
- Wolf-Gladrow, D. A., Zeebe, R. E., Klaas, C., Körtzinger, A., & Dickson, A. G.
- Affiliations
- Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung (DE)
- Corresponding author
- Wolf-Gladrow, Dieter A.
- Venue
- Marine Chemistry
- Publisher
- Elsevier BV
- Published
- 2007-07
- Volume
- 106
- Issue
- 1-2
- Pages
- 287-300
- ISSN
- 0304-4203 (ISSN-L)
- OpenAlex
- W2035240561
- Cited by
- 780
- References
- 25
- Citations by year
- 2026: 48 · 2025: 73 · 2024: 80 · 2023: 86 · 2022: 83 · 2021: 70 · 2020: 42 · 2019: 27 · 2018: 51 · 2017: 37 · 2016: 29 · 2015: 34 · 2014: 33 · 2013: 28 · 2012: 20
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Marine Chemistry (publishedVersion)
- Helmholtz-Zentrum für Polar-und Meeresforschung (Alfred-Wegener-Institut) (acceptedVersion)
- Helmholtz Centre for Ocean Research Kiel (GEOMAR) (acceptedVersion)
- Funders
- National Science Foundation (0137287)
- U.S. Department of Energy (DE‐FG02‐, FG02-06ER64077)
- European Commission (511176)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Marine Plankton and Biogeochemistry
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Ocean Acidification Effects and Responses
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Oceanographic and Atmospheric Processes
- Keywords
- total alkalinity, carbonate system, dissolved inorganic carbon, charge neutrality, biogeochemical processes, microalgae, organic matter mineralization, calcium carbonate precipitation, nitrogen fixation, nitrification, nutrient uptake, ocean carbon cycle
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