Cited by 781Marine Plankton and BiogeochemistryOcean Acidification Effects and ResponsesOceanographic and Atmospheric Processes

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Total alkalinity: The explicit conservative expression and its application to biogeochemical processes

Wolf-Gladrow, Dieter A., Zeebe, Richard E., Klaas, Christine, Körtzinger, Arne, Dickson, Andrew G.·2007·Marine Chemistry

DOI 10.1016/j.marchem.2007.01.006

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“2016b mapped product nitrate field multiplied by 1.36 (Wolf-Gladrow et al., 2007) from the TA field to account for the minor influence of remineralization on TA.”
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On the biogeochemical response of a glacierized High Arctic watershed to climate change: revealing patterns, processes and heterogeneity among micro‐catchments
Nowak, A., & Hodson, A. (2014) · Hydrological Processes · doi:10.1002/hyp.10263 · Cited by 21
When can ocean acidification impacts be detected from decadal alkalinity measurements?
Carter, B. R., Frölicher, T. L., Dunne, J. P. P., Rodgers, K. B., Slater, R. D., & Sarmiento, J. L. (2016) · Global Biogeochemical Cycles · doi:10.1002/2015gb005308 · Cited by 21
Ocean carbon and nitrogen isotopes in CSIRO Mk3L-COAL version 1.0: a tool for palaeoceanographic research
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“Alkalinity ratios for both the general and nitrogen-fixing groups are the negative of the N : P ratio, such that for a loss of 1 mmol of NO3, alkalinity will increase at 1 mmol eq m−3 (Wolf-Gladrow et al., 2007).”
Background
Autonomous in situ measurements of freshwater alkalinity
Shangguan, Q., Lai, C., Beatty, C. M., Young, F. L., Spaulding, R. S., & DeGrandpre, M. D. (2020) · Limnology and Oceanography Methods · doi:10.1002/lom3.10404 · Cited by 21
“1) (Dickson 1981; Wolf-Gladrow et al. 2007) and is dominated in most freshwaters by carbonate equilibria (Stumm and Morgan 1996): AT = HCO−3 +2 CO2−3 + OH−½ − H+½ ð1Þ AT in running waters is sourced from chemical weathering (Raymond and Cole 2003; Torres et al. 2016) as well as aerobic and…”
Background
Decadal Dynamics of the CO2 System and Associated Ocean Acidification in Coastal Ecosystems of the North East Atlantic Ocean
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Mediterranean Sea general biogeochemistry
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Metabolic alkalinity release from large port facilities (Hamburg, Germany) and impact on coastal carbon storage
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“NO 3 - , Fe 3+ , Mn 4+ , SO 4 2) to respire organic matter, which are of particular interest as they release alkalinity in varying stoichiometry (Brewer and Goldman, 1976;Chen and Wang, 1999;Hu and Cai, 2011;Wolf-Gladrow et al., 2007).”
Background
Nutrient release and flux dynamics of CO 2 , CH 4 , and N 2 O in a coastal peatland driven by actively induced rewetting with brackish water from the Baltic Sea
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Experimental evaluation of black liquor carbonation for carbon dioxide capture
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Mixing and remineralization in waters detrained from the surface into Subantarctic Mode Water and Antarctic Intermediate Water in the southeastern Pacific
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Self-citation
Recycling of Organic Matter in the Sediments of Santa Monica Basin, California Borderland
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“5 follows the explicit conservative alka- linity formulation of Wolf-Gladrow et al. (2007).”
Background
Estimating surface water mixing ratios using salinity and potential alkalinity in the K uroshio‐ O yashio mixed water regions
Kakehi, S., Ito, S., & Wagawa, T. (2017) · Journal of Geophysical Research Oceans · doi:10.1002/2016jc012268 · Cited by 21
Bottom Water Acidification and Warming on the Western Eurasian Arctic Shelves: Dynamical Downscaling Projections
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“Dissolved inorganic carbon (DIC) and total alkalinity (Alk) are fully prognostic state variables that are input by rivers, exchanged with the atmosphere (DIC only), and produced/consumed by plankton and bacteria following the nutrient-H1 compensation principle (Wolf-Gladrow et al., 2007).”
Background
The recent state and variability of the carbonate system of the Canadian Arctic Archipelago and adjacent basins in the context of ocean acidification
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“…carbon (DIC) concentration (the sum of [H2CO∗3], [HCO − 3 ] and [CO 2− 3 ]) in the surface ocean is expected to increase relative to the total alkalinity (TA; the capacity of a solution to neutralize protons), as the latter is nearly conservative in the surface ocean (Wolf-Gladrow et al., 2007).”
Background
Cultivation of Emiliania huxleyi for coccolith production
Jakob, I., Weggenmann, F., & Posten, C. H. (2018) · Algal Research · doi:10.1016/j.algal.2018.01.013 · Cited by 23
“2 g L/42 g L; 1 mol HCO3 equals 1mol TA [66]).”
Background
The characteristics of the CO2 system of the Oder River estuary (Baltic Sea)
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Nutrient pollution enhances productivity and framework dissolution in algae- but not in coral-dominated reef communities
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“Biocalcification is a source of atmospheric CO2 because it reduces total alkalinity (TA), concurrently removing dissolved inorganic carbon (DIC) from the water column (2:1 stoichiometric ratio; Wolf-Gladrow et al. 2007), altering the marine carbonate system releasing CO2 to the atmosphere (Fig.”
Background
Seasonality and spatial heterogeneity of the surface ocean carbonate system in the northwest European continental shelf
Hartman, S. E., Humphreys, M. P., Kivimäe, C., Woodward, E. M. S., Kitidis, V., McGrath, T., Hydes, D. J., Greenwood, N., Hull, T., Ostle, C., et al. (2018) · Progress In Oceanography · doi:10.1016/j.pocean.2018.02.005 · Cited by 20
“The exact definition of TA is complicated but it can be summarised as the stoichiometric sum of bases in solution (Wolf-Gladrow et al., 2007).”
Background
Oyster reefs' control of carbonate chemistry—Implications for oyster reef restoration in estuaries subject to coastal ocean acidification
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Modeling Ocean Biogeochemical Processes and the Resulting Tracer Distributions
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Alkalinity to calcium flux ratios for corals and coral reef communities: variances between isolated and community conditions
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“…coral reef processes such as organic matter production from photosynthesis (Kim & Lee, 2009), anaerobic diagenesis in sediments (Emerson & Hedges, 2003; Thomas et al., 2009;Mackenzie et al., 2011), and nutrient transformation (Brewer & Goldman, 1976 ;Wolf-Gladrow et al., 2007 ) as shown by Eq.”
Background
Seasonal variability of the carbonate system and coccolithophore Emiliania huxleyi at a Scottish Coastal Observatory monitoring site
León, P., Walsham, P., Bresnan, E., Hartman, S. E., Hughes, S. L., Mackenzie, K. S., & Webster, L. (2018) · Estuarine Coastal and Shelf Science · doi:10.1016/j.ecss.2018.01.011 · Cited by 20
“Observed coccolithophore abundances were not sufficient to affect TA concentrations 404 M AN US CR IP T AC CE PT ED (Wolf-Gladrow et al., 2007) and dismiss the impact of large coccolithophore blooms on TA 405 during the study period.”
Background
Online‐Bestimmung der elektrochemischen Kohlenstoffkorrosion in alkalischen Elektrolyten durch differentielle elektrochemische Massenspektrometrie
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Impact of shifting abiotic factors in aquaculture on fish breeding and reproduction: a review
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“Alkalinity represents the total concentration of negatively charged ions, particularly carbonate and bicarbonate, that neutralize hydrogen ions in natural waters [1].”
Detection and quantification of CO2 seepage in seawater using the stoichiometric Cseep method: Results from a recent subsea CO2 release experiment in the North Sea
Omar, A. M., García‐Ibáñez, M. I., Schaap, A. M., Oleynik, A., Espósito, M., Jeansson, E., Loucaides, S., Thomas, H., & Alendal, G. (2021) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2021.103310 · Cited by 18
Physical and biological effects on the carbonate system during summer in the Northern Argentine Continental Shelf (Southwestern Atlantic)
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Constraining CaCO3 Export and Dissolution With an Ocean Alkalinity Inverse Model
Liang, H., Lunstrum, A. M., Dong, S., Berelson, W. M., & John, S. G. (2023) · Global Biogeochemical Cycles · doi:10.1029/2022gb007535 · Cited by 18
Integrating bicarbonate-based microalgal production with alkaline sewage for ocean negative carbon emissions
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The role of marine bivalves in the oceanic carbon cycle: Physiological processes, carbon budgets and ecosystem perspectives
Zhou, X., Li, H., Liang, J., Liu, H., Wang, X., Gao, L., Chen, L., Li, Y., Guo, Y., & Liang, S. (2024) · Regional Studies in Marine Science · doi:10.1016/j.rsma.2024.103815 · Cited by 18
Simulating the effects of light intensity and carbonate system composition on particulate organic and inorganic carbon production in Emiliania huxleyi
Holtz, L., Wolf-Gladrow, D. A., & Thoms, S. (2015) · Journal of Theoretical Biology · doi:10.1016/j.jtbi.2015.02.024 · Cited by 18
“Last but not least, the principle of charge neutrality has to be ensured when trans-membrane fluxes of ions are considered (Wolf-Gladrow et al., 2007), i.”
BackgroundSelf-citation

Authors: Wolf-Gladrow, D. A., Zeebe, R. E., Klaas, C., Körtzinger, A., & Dickson, A. G.
Affiliations: Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung (DE)
Corresponding author: Wolf-Gladrow, Dieter A.
ORCID: Wolf-Gladrow, Dieter A.
Zeebe, Richard E.
Klaas, Christine
Körtzinger, Arne
Dickson, Andrew G.
Venue: Marine Chemistry
Publisher: Elsevier BV
Published: 2007-07
Volume: 106
Issue: 1-2
Pages: 287-300
ISSN: 0304-4203 (ISSN-L)
DOI: 10.1016/j.marchem.2007.01.006
OpenAlex: W2035240561
Cited by: 780
References: 25
Citations by year: 2026: 48 · 2025: 73 · 2024: 80 · 2023: 86 · 2022: 83 · 2021: 70 · 2020: 42 · 2019: 27 · 2018: 51 · 2017: 37 · 2016: 29 · 2015: 34 · 2014: 33 · 2013: 28 · 2012: 20
FWCI: 6.04
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
www.elsevier.com/legal/tdmrep-license (tdm)
Locations: Marine Chemistry (publishedVersion)
Helmholtz-Zentrum für Polar-und Meeresforschung (Alfred-Wegener-Institut) (acceptedVersion)
Helmholtz Centre for Ocean Research Kiel (GEOMAR) (acceptedVersion)
Funders: National Science Foundation (0137287)
U.S. Department of Energy (DE‐FG02‐, FG02-06ER64077)
European Commission (511176)
Topics: Physical Sciences › Earth and Planetary Sciences › Oceanography › Marine Plankton and Biogeochemistry
Physical Sciences › Earth and Planetary Sciences › Oceanography › Ocean Acidification Effects and Responses
Physical Sciences › Earth and Planetary Sciences › Oceanography › Oceanographic and Atmospheric Processes
Keywords: total alkalinity, carbonate system, dissolved inorganic carbon, charge neutrality, biogeochemical processes, microalgae, organic matter mineralization, calcium carbonate precipitation, nitrogen fixation, nitrification, nutrient uptake, ocean carbon cycle

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Total alkalinity: The explicit conservative expression and its application to biogeochemical processes

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