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Total alkalinity: The explicit conservative expression and its application to biogeochemical processes
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“During that time, biological processes within the subducted water mass may consume some of the unequilibrated alkalinity, however this will have no impact on atmospheric CO2 until the water mass resurfaces. 64”
From A framework for understanding efficiency losses of Ocean Alkalinity Enhancement (2026) · cites this paper as [64]
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Cited by
Sorted by citations
Items 501–600 of 781
Holdsworth, A. M., Shao, A. E., & Christian, J. R. (2025) · Geophysical Research Letters · doi:10.1029/2024gl112591 · Cited by 4
“Data from (Devol, 1991; Seitzinger & Giblin, 1996) were used to estimate the denitrification fraction; alkalinity sources and sinks are based on (Wolf‐Gladrow et al., 2007).”
White, M. M., Drapeau, D., Lubelczyk, L. C., Abel, V., Bowler, B. C., & Balch, W. M. (2018) · Marine Ecology Progress Series · doi:10.3354/meps12639 · Cited by 4
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Alkalinity and nitrate dynamics reveal dominance of anammox in a hyper-turbid estuary
Norbisrath, M., Neumann, A., Dähnke, K., Sanders, T., Schöl, A., van Beusekom, J. V., & Thomas, H. (2023) · Biogeosciences · doi:10.5194/bg-20-4307-2023 · Cited by 4
Mahanty, B., Kim, S., & Kim, C. G. (2013) · Geomicrobiology Journal · doi:10.1080/01490451.2013.819051 · Cited by 4
“5) where the three main forms of alkalinity (bicarbonate, carbonate, and hydroxide) have been neutralized (Dickson et al. 2003; Wolf-Gladrow et al. 2007).”
BackgroundMethodInfluentialAn Assessment of Direct Dissolved Inorganic Carbon Injection to the Coastal Region: A Model Result
Huang, W., Kao, K., Liu, L., Liao, C.-W., & Han, Y.-L. (2018) · Sustainability · doi:10.3390/su10041174 · Cited by 6
“One unit of nitrate uptake can increase one unit of TA [16,17], suggesting an effect on the conservative mixing equation as the follows:”
BackgroundVieira, B. F., Rodriguez, R. P., de Paula, E. C., & Simões, G. F. (2021) · Journal of Environmental Management · doi:10.1016/j.jenvman.2021.112114 · Cited by 4
Soil carbon dioxide levels control salt marsh alkalinity generation
Tutiyasarn, P., Mueller, P., Mujalli, G. R., Dam, B. V., Hartmann, J., & Porada, P. (2025) · Limnology and Oceanography · doi:10.1002/lno.70062 · Cited by 3
“This effect leads to the carbonate or silicate dissolution process, releasing bicarbonate (HCO 3 (cid:1) ) and carbonate ion (CO 32 (cid:1) ) (Bricker et al. 1968; Guo et al. 2012; Hartmann et al. 2013; Saderne et al. 2019), consequently increasing TA (Wolf-Gladrow et al. 2007; Krumins et al. 2013).”
Drivers and Variability of Intensified Subsurface Ocean Acidification Trends at Station ALOHA
Knor, L. A. C. M., Sabine, C. L., Dore, J. E., White, A., & Potemra, J. T. (2025) · Journal of Geophysical Research Oceans · doi:10.1029/2024jc022251 · Cited by 3
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“Prior studies have also demonstrated a quasi-linear relationship between TA − DIC and carbonate system parameters, further supporting its application in aquaculture systems (Wolf-Gladrow et al. 2007; Xue and Cai 2020).”
Long‐Term Changes of Surface Total Alkalinity and Its Driving Mechanisms in the North Indian Ocean
Joshi, A. P., Ghoshal, P. K., Chakraborty, K., Roy, R., Jayaram, C., Sridevi, B., & Sarma, V. V. S. S. (2025) · Global Biogeochemical Cycles · doi:10.1029/2024gb008344 · Cited by 3
Riverine-coastal carbon dynamics, acidification, and CO2 outgassing in an intensive mariculture bay
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Modeling nitrogen species as a source of titratable alkalinity and dissolved gas pressure in water
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Carbonate system variability in the Mediterranean Sea: a modelling study
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Sulphate reduction and carbonate precipitation in a high-energy algal rim framework
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“2) (Wolf-Gladrow et al. 2007).”
Sun, Y., & Ellwood, M. J. (2025) · Limnology and Oceanography Letters · doi:10.1002/lol2.10457 · Cited by 3
“Total alkalinity is also in fl uenced by proton fl uxes associated with nutrient production during organic matter decomposition (Brewer and Goldman 1976; Wolf-Gladrow et al. 2007).”
Steiner, Z., Benaltabet, T., & Torfstein, A. (2025) · Limnology and Oceanography · doi:10.1002/lno.12781 · Cited by 3
“…of CaCO 3 consumes two charge equivalents per mol of Ca: Calculation of CaCO 3 precipitation using the A T data requires normalization of the A T data to a constant salinity (40.66 in our case) and correction for release of nitrite, nitrate, SRP, and sulfate (Wolf-Gladrow et al. 2007).”
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Earth system carbon cycle dynamics through time
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Assessment of an automated titration system for batch measurements of total alkalinity
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“Because of the impact of equation (2) on proton balance, SR results in a stoichiometric increase of DIC:TA by 1:2, thus having significant impact on pCO2, pH, and in the BBL [Berner et al., 1970; Wolf-Gladrow et al., 2007].”
BackgroundA Biogeochemical Alkalinity Sink in a Shallow, Semiarid Estuary of the Northwestern Gulf of Mexico
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“(Wolf-Gladrow et al., 2007) The titrimetric method was used to determine both the alkalinity and ammonia content.”
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Total alkalinity change: The perspective of phytoplankton stoichiometry
Wolf-Gladrow, D. A., & Klaas, C. (2024) · Limnology and Oceanography · doi:10.1002/lno.12597 · Cited by 2
“H + - compensation principle (Wolf-Gladrow et al. 2007).”
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The dominant sink of oceanic calcium carbonate occurs in undersaturated seawater
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“6 where 0.5 represents a change in TA of 2 mol caused by the dissolution of 1 mol CaCO 3 , and 0.63 is a coefficient used to account for TA contributions from the oxidation of organic matter (46).”
InfluentialLisle, J. T., Reich, C. D., & Halley, R. B. (2014) · Marine Ecology Progress Series · doi:10.3354/meps10844 · Cited by 2
“The diffusion coefficient for DIC was also used for alkalinity, as the majority of alkalinity (i.e. HCO3−, CO32−) is accounted for by DIC in marine water (Wolf-Gladrow et al. 2007).”
MethodSources of Corrosive Bottom Water to Bellingham Bay, Washington State
Shull, D. H. (2021) · Estuaries and Coasts · doi:10.1007/s12237-020-00859-1 · Cited by 2
“of DIC and different alkalinities are mixed, one can calculate the concentrations in the resulting mixture using the principle of conservation of mass (Wolf-Gladrow et al. 2007).”
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Sub-annual and inter-annual variations of total alkalinity in the northeastern Gulf of Mexico
Yang, B., & Byrne, R. H. (2022) · Marine Chemistry · doi:10.1016/j.marchem.2022.104195 · Cited by 2
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“Collectively, these processes facilitate the vertical redistribution of alkalinity and consequently affect carbonate saturation states (Ω) throughout the water column (Zeebe and Wolf-Gladrow 2001; Wolf-Gladrow et al. 2007).”
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“Although total alkalinity is conservative with respect to mixing, CO 2 atmospheric exchange and physical perturbations, it changes in response to reactions such as nitrification, calcification, and organic matter remineralization (Middelburg et al., 2020; Wolf‐Gladrow et al., 2007).”
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“For example, OH−, HCO3 , CO 2− 3 , and other ions can all react with strong acids to buffer the effect of these acids on the pH of the solution (Wolf-Gladrow et al. 2007).”
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The Marine Carbonate System: Ionic Interactions and Biogeochemical Processes
Ulfsbo, A. (2014) · Gothenburg University Publications Electronic Archive (Gothenburg University) · Cited by 1
Esteve, L. C. (2014) · RUA, Repositorio Institucional de la Universidad de Alicante (Universidad de Alicante)
Ocean acidification effects on marine microbial communities
Krause, E. (2013) · Helmholtz-Zentrum für Polar-und Meeresforschung (Alfred-Wegener-Institut)
Sett, S. (2010) · Helmholtz Centre for Ocean Research Kiel (GEOMAR)
ESTUDO COMPARATIVO DE MODELOS DE DETERMINAÇÃO DA ALCALINIDADE EM AMOSTRAS DE ÁGUA SUBTERRÂNEA
Souto, R. T., Brandão, F. G., Pinto, M. C. F., & Mourão, M. A. A. (2015) · LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas)
CO2 exchange in a temperate marginal sea of the Mediterranean Sea: processes and carbon budgetPreprint
Cossarini, G., Querin, S., & Solidoro, C. (2012) · doi:10.5194/bgd-9-10331-2012
“Since the solely nutrient in the model is phosphorus, its rate of change is multiplied by a coefficient that accounts for the contribution of the all nutrients (Wolf-Gladrow et al., 2007).”
BackgroundBoron in Foraminiferal Calcite as an Indicator of Seawater Carbonate Chemistry
Allen, K. A. (2013) · doi:10.7916/d8zk5pwd
“Natural seawater is not so simple, and many additional chemical species contribute to alkalinity, including borate, phosphate, and hydrogen silicate ions as well as organic acids (Dickson, 1981; Wolf-Gladrow et al., 2007; Zeebe and Wolfe-Gladrow, 2001).”
BackgroundMethodInfluentialResponse of the cold-water coral Desmophyllum dianthus to future CO 2 concentrations
Jantzen, C., & Arbizu, P. M. (2013)
Characterizing the controls on surface alkalinity in Nootka Sound, British Columbia
Miller, U. K. (2015) · ResearchWorks at the University of Washington (University of Washington)
Modelling the carbonate system to adequately quantify ocean acidification
Coughlan, C. (2013) · Joint Research Centre (European Commission) · doi:10.2788/58192
“, 2009) through processes such as calcium carbonate precipitation or production of particulate organic matter by microalgae (Wolf-Gladrow et al., 2007).”
BackgroundInfluentialSato, K. N., Elahi, R., Kapsenberg, L., Phillips, J., Pietsch, C., & Vaughn, C. (2011) · ResearchWorks at the University of Washington (University of Washington)
Impacts of hurricane Frances (2004) on vertical mixing and air-sea CO₂ exchange
Huang, P. (2010) · UWA Profiles and Research Repository (University of Western Australia)
Lammers, J. M. (2017) · Utrecht University Repository (Utrecht University)
Metadata
- Authors
- Wolf-Gladrow, D. A., Zeebe, R. E., Klaas, C., Körtzinger, A., & Dickson, A. G.
- Affiliations
- Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung (DE)
- Corresponding author
- Wolf-Gladrow, Dieter A.
- Venue
- Marine Chemistry
- Publisher
- Elsevier BV
- Published
- 2007-07
- Volume
- 106
- Issue
- 1-2
- Pages
- 287-300
- ISSN
- 0304-4203 (ISSN-L)
- OpenAlex
- W2035240561
- Cited by
- 780
- References
- 25
- Citations by year
- 2026: 48 · 2025: 73 · 2024: 80 · 2023: 86 · 2022: 83 · 2021: 70 · 2020: 42 · 2019: 27 · 2018: 51 · 2017: 37 · 2016: 29 · 2015: 34 · 2014: 33 · 2013: 28 · 2012: 20
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Marine Chemistry (publishedVersion)
- Helmholtz-Zentrum für Polar-und Meeresforschung (Alfred-Wegener-Institut) (acceptedVersion)
- Helmholtz Centre for Ocean Research Kiel (GEOMAR) (acceptedVersion)
- Funders
- National Science Foundation (0137287)
- U.S. Department of Energy (DE‐FG02‐, FG02-06ER64077)
- European Commission (511176)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Marine Plankton and Biogeochemistry
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Ocean Acidification Effects and Responses
- Physical Sciences › Earth and Planetary Sciences › Oceanography › Oceanographic and Atmospheric Processes
- Keywords
- total alkalinity, carbonate system, dissolved inorganic carbon, charge neutrality, biogeochemical processes, microalgae, organic matter mineralization, calcium carbonate precipitation, nitrogen fixation, nitrification, nutrient uptake, ocean carbon cycle
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