A one-dimensional phenomenological model for the two-way shape-memory effect in semi-crystalline networks
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The two-way SME under constant tensile stress is based on elongation of the polymer network caused by entropy elasticity in the rubbery region and crystallization upon cooling below the crystallization temperature, and on contraction caused by melting of the temporary-oriented crystalline domain upon heating above the melting temperature.
“The two-way SME under constant tensile stress is based on the elongation of the polymer network, caused by an entropy elasticity effect in the rubbery region and the crystallization upon cooling below the crystallization temperature, and on the contraction of the polymer network, caused by the melting of the temporary-oriented crystalline domain upon heating above the melting temperature.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
Materials can achieve two-way reversible strain variations between 10% and 100% under moderate stresses, typically between hundreds of kPa and a few MPa.
“Particularly, the two-way SME was shown to be tailored by the applied stress, the cooling/heating rate, and the crosslink density, leading to materials capable of two-way reversible strain variations between 10% and 100% under the application of moderate stresses (typically, between hundreds of kPa and a few MPa) [103].”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
The two-way SME was shown to be tailored by the applied stress, the cooling/heating rate, and the crosslink density.
“Particularly, the two-way SME was shown to be tailored by the applied stress, the cooling/heating rate, and the crosslink density, leading to materials capable of two-way reversible strain variations between 10% and 100% under the application of moderate stresses (typically, between hundreds of kPa and a few MPa) [103].”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
Recovery effects in two-way SMPs were shown to be sharp and fast because they are triggered by melting instead of being activated by glassy-rubbery transition.
“Moreover, recovery effects were shown to be sharp and fast, since they are triggered by melting instead of being activated by glassy-rubbery transition.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
The model by Scalet et al. is validated on experiments on semi-crystalline networks based on poly( # -caprolactone) and demonstrates capability in describing the effect of crosslink density on SME, the dependence of microstructural evolution on applied load and heating/cooling rate, and the presence of thermal strains.
“The model is validated on experiments on semi-crystalline networks based on poly( # -caprolactone) and demonstrates model capability in describing material features such as the effect of the crosslink density on SME, the dependence of microstructural evolution on applied load and heating/cooling rate, and the presence of thermal strains.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
Few works consider the two-way SME under stress conditions in semi-crystalline crosslinked polymers.
“In fact, few works considering the two-way SME under stress conditions in semi-crystalline crosslinked polymers are available [103,104,167,277,278].”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [103]
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Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview
Scalet, G. (2020) · Actuators · doi:10.3390/act9010010 · Cited by 209 · see citing works
“Particularly, the two-way SME was shown to be tailored by the applied stress, the cooling/heating rate, and the crosslink density, leading to materials capable of two-way reversible strain variations between 10% and 100% under the application of moderate stresses (typically, between hundreds of kPa and a few MPa) [103…”
BackgroundInfluentialSelf-citation
- Authors
- Scalet, G., Pandini, S., Messori, M., Toselli, M., & Auricchio, F.
- Affiliations
- University of Pavia (IT)
- National Interuniversity Consortium of Materials Science and Technology (IT)
- University of Modena and Reggio Emilia (IT)
- University of Bologna (IT)
- Corresponding author
- Scalet, Giulia
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2018-12
- Volume
- 158
- Pages
- 130-148
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2897240774
- Cited by
- 38
- References
- 40
- Citations by year
- 2026: 5 · 2025: 4 · 2024: 5 · 2023: 5 · 2022: 6 · 2021: 4 · 2020: 6 · 2019: 3
- FWCI
- 2.08
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Polymer (publishedVersion)
- Archivio istituzionale della ricerca (Alma Mater Studiorum Università di Bologna) (submittedVersion)
- PORTO@Iris (submittedVersion)
- Institutional Research Information System (Università degli Studi di Brescia) (submittedVersion)
- IRIS UNIMORE (University of Modena and Reggio Emilia) (submittedVersion, cc-by)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- two-way shape memory effect, one-way shape memory effect, semicrystalline polymers, crosslinked polymer networks, polycaprolactone, thermoresponsive polymers, crosslink density, microstructure evolution, thermal strain, polymer actuators, stimuli-responsive materials
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