Cited by 137Geology and Paleoclimatology ResearchPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Evaluation of kinetic effects on clumped isotope fractionation (Δ47) during inorganic calcite precipitation

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Tang, Jianwu, Dietzel, Martin, Fernandez, Alvaro, Tripati, Aradhna K., Rosenheim, Brad E.·2014·Geochimica et Cosmochimica Acta

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Crossref · 10.1016/j.gca.2014.03.005

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  • When fluid pH exceeds 9.5, 47 begins to deviate from known Ti relationships.

    “When fluid pH exceeds 9.5 (Tang et al. 2014), 47 begins to deviate from known Ti relationships.”

    From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tang et al. 2014

  • The D47-T slope versus 1/T2 is about 3.80 (±0.07)×10^4 using only this study's results, and 3.97 (±0.03)×10^4 including the data of Dennis and Schrag (2010), Passey and Henkes (2012), and Tang et al. (2014).

    “The D 47 -T slope versus 1/T 2 is about 3.80 (±0.07)Á10 4 using only the results of this study, and 3.97 (±0.03)Á10 4 including the data of Dennis and Schrag (2010), Passey and Henkes (2012), and Tang et al. (2014).”
  • The new and extended empirical D47-T calibration curve provides a solid basis for the application of the carbonate clumped isotope proxy to the temperature range from 20 to 250 °C (from 7.5 to 800 °C, including the data of Dennis and Schrag (2010), Passey and Henkes (2012) and Tang et al. (2014)) and, thus, to relevant questions related to high-temperature geological processes.

    “This new and extended empirical D 47 -T calibration curve provides a solid basis for the application of the carbonate clumped isotope proxy to the temperature range from 20 to 250 °C (from 7.5 to 800 °C, including the data of Dennis and Schrag (2010), Passey and Henkes (2012) and Tang et al. (2014)) and, thus, to relevant questions related to high-temperature geological processes.”
  • Tang et al. (2014) concluded that there are no clear effects of variable pH, ionic strength, and growth rate on measured Δ47 values.

    “The experimental study of Tang et al. (2014) (8.3 ≤ pH ≤ 10.5 at 5°C, 25°C and 40°C) concluded that there are no clear effects of variable pH, ionic strength and growth rate on the measured D 47 values.”
  • pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 and natural travertines at pH 5.6-9.

    “Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”

    From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tang et al., 2014

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Authors
Tang, J., Dietzel, M., Fernandez, A., Tripati, A. K., & Rosenheim, B. E.
Affiliations
  • Tulane University (US)
  • Graz University of Technology (AT)
  • University of California, Los Angeles (US)
Corresponding author
Tang, Jianwu
Venue
Geochimica et Cosmochimica Acta
Publisher
Elsevier BV
Published
2014-06
Volume
134
Pages
120-136
ISSN
0016-7037 (ISSN-L)
OpenAlex
W2121761338
Cited by
137
References
64
Citations by year
2026: 4 · 2025: 4 · 2024: 4 · 2023: 6 · 2022: 15 · 2021: 11 · 2020: 9 · 2019: 16 · 2018: 18 · 2017: 12 · 2016: 13 · 2015: 18 · 2014: 6 · 2013: 1
FWCI
10.85
Type
journal article
Language
en
Open access
Locations
  • Geochimica et Cosmochimica Acta (acceptedVersion)
  • DIGITAL.CSIC (Spanish National Research Council (CSIC)) (acceptedVersion)
  • Digital Commons - University of South Florida (University of South Florida) (submittedVersion)
  • eScholarship (California Digital Library) (submittedVersion)
Funders
  • Deutsche Forschungsgemeinschaft (Ei272/20-1/-2)
  • Austrian Science Fund (I34-B06)
  • National Science Foundation
  • University of California, Los Angeles
  • American Chemical Society (51182-DNI2)
Topics
  • Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
  • Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
  • Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
Keywords
Δ47, calcite precipitation, precipitation kinetics, precipitation rate, ionic strength, pH effect, paleothermometry, carbonate mineralogy, acid digestion, oxygen isotopes

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