Evaluation of kinetic effects on clumped isotope fractionation (Δ47) during inorganic calcite precipitation
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When fluid pH exceeds 9.5, 47 begins to deviate from known Ti relationships.
“When fluid pH exceeds 9.5 (Tang et al. 2014), 47 begins to deviate from known Ti relationships.”
From Frontiers of Carbonate Clumped Isotope Thermometry (2023) · cites this paper as Tang et al. 2014
The D47-T slope versus 1/T2 is about 3.80 (±0.07)×10^4 using only this study's results, and 3.97 (±0.03)×10^4 including the data of Dennis and Schrag (2010), Passey and Henkes (2012), and Tang et al. (2014).
“The D 47 -T slope versus 1/T 2 is about 3.80 (±0.07)Á10 4 using only the results of this study, and 3.97 (±0.03)Á10 4 including the data of Dennis and Schrag (2010), Passey and Henkes (2012), and Tang et al. (2014).”
From Laboratory calibration of the calcium carbonate clumped isotope thermometer in the 25–250 °C temperature range (2015) · cites this paper as Tang et al. (2014)
The new and extended empirical D47-T calibration curve provides a solid basis for the application of the carbonate clumped isotope proxy to the temperature range from 20 to 250 °C (from 7.5 to 800 °C, including the data of Dennis and Schrag (2010), Passey and Henkes (2012) and Tang et al. (2014)) and, thus, to relevant questions related to high-temperature geological processes.
“This new and extended empirical D 47 -T calibration curve provides a solid basis for the application of the carbonate clumped isotope proxy to the temperature range from 20 to 250 °C (from 7.5 to 800 °C, including the data of Dennis and Schrag (2010), Passey and Henkes (2012) and Tang et al. (2014)) and, thus, to relevant questions related to high-temperature geological processes.”
From Laboratory calibration of the calcium carbonate clumped isotope thermometer in the 25–250 °C temperature range (2015) · cites this paper as Tang et al. (2014)
Tang et al. (2014) concluded that there are no clear effects of variable pH, ionic strength, and growth rate on measured Δ47 values.
“The experimental study of Tang et al. (2014) (8.3 ≤ pH ≤ 10.5 at 5°C, 25°C and 40°C) concluded that there are no clear effects of variable pH, ionic strength and growth rate on the measured D 47 values.”
From Temperature dependence of oxygen- and clumped isotope fractionation in carbonates: A study of travertines and tufas in the 6-95 °C temperature range (2015) · cites this paper as Tang et al. (2014)
pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 and natural travertines at pH 5.6-9.
“Although this D 47 offset is similar to our measurements ( 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3-10.5 (Tang et al., 2014) and natural travertines at pH 5.6-9 (Kele et al., 2015).”
From Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks (2016) · cites this paper as Tang et al., 2014
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Background13C–18O bonds in carbonate minerals: a new kind of paleothermometer
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“…et al., 2011; Zaarur et al., 2011; Saenger et al., 2012; Dennis et al., 2013; Grauel et al., 2013; Henkes et al., 2013), inorganic synthetic carbonates (Dennis and Schrag, 2010; Zaarur et al., 2013), and theoretical calculations (Schauble et al., 2006; Guo et al., 2009; Hill et al., 2013).”
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Self-citationAn explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes
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“The abundance of this species is reported using the notation D47, representing the mass 47 enrichment in CO2 relative to the amount of mass 47 expected for a CO2 that has the same bulk isotopic composition but a stochastic distribution of isotopologues (Wang et al., 2004).”
MethodLinks between salinity variation in the Caribbean and North Atlantic thermohaline circulation
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Carbonate clumped isotope bond reordering and geospeedometry
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“Deviations of D47 from values predicted by the Ghosh et al. (2006) calibration are generally discussed in terms of non-equilibrium clumped isotopic fractionation (Affek et al., 2008; Daëron et al., 2011; Kluge and Affek, 2012; Dennis et al., 2013).”
BackgroundMethodClumped isotope thermometry of carbonatites as an indicator of diagenetic alteration
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“…then we derive the following D47-temperature calibration using average sample values for each temperature: D47 ¼ ð0:0387 0:0072Þ 106=T 2 þ ð0:2532 0:0829Þ ðr2 ¼ 0:9998; p ¼ 0:009Þ: This uses an acid digestion fractionation factor of 0.092& for the 90–25 C offset from Henkes et al. (2013).”
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“, 2013), and theoretical calculations (Schauble et al., 2006; Guo et al., 2009; Hill et al., 2013).”
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“…as determined on replicate analyses of samples and standards is 0.005– 0.009& (1 s.e.), equivalent to about 1–2 C and consistent with other studies (Eiler, 2007; Huntington et al., 2009; Eagle et al., 2010, 2011, 2013; Tripati et al., 2010; Thiagarajan et al., 2011; Rosenheim et al., 2013).”
ResultInfluentialSelf-citationHill, P. S., Tripati, A. K., & Schauble, E. A. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.06.018 · Cited by 155 · see citing works
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“A similar argument was also proposed by Saenger et al. (2012) to interpret negative d18O and positive D47 offsets observed in their coral samples.”
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“Many biogenic carbonates (Ghosh et al., 2006, 2007; Came et al., 2007; Eagle et al., 2010; Tripati et al., 2010; Thiagarajan et al., 2011; Grauel et al., 2013) exhibit a D47 sensitivity to temperature that is similar to the original inorganic calibration of Ghosh et al.”
BackgroundResultInfluentialPaleo-environmental implication of clumped isotopes in land snail shells
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Siderite “clumped” isotope thermometry: a new paleoclimate proxy for humid continental environments
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Self-citationQuantifying kinetic fractionation in Bunker Cave speleothems using Δ47
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Self-citationTheoretical estimation of the equilibrium distribution of clumped isotopes in nature
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Self-citationEvidence of multidecadal salinity variability in the eastern tropical North Atlantic
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Self-citationCalibration of sclerosponge oxygen isotope records to temperature using high-resolution δ18O data
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Self-citation
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Microbially catalyzed dolomite formation: From near-surface to burial
Petrash, D. A., Bialik, O. M., Bontognali, T. R. R., Vasconcelos, C., Roberts, J. A., McKenzie, J. A., & Konhauser, K. O. (2017) · Earth-Science Reviews · doi:10.1016/j.earscirev.2017.06.015 · Cited by 338 · see citing works
“The carbonate clumped isotope thermometer has been calibrated for synthetic inorganic calcite and a variety of biogenic carbonates (e.g., Ghosh et al., 2006; Dennis and Schrag, 2010; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015; Kluge et al., 2015; Ghosh et al., 2007; Eagle et al., 2013; Henkes et al.…”
BackgroundMethodEocene greenhouse climate revealed by coupled clumped isotope-Mg/Ca thermometry
Evans, D., Sagoo, N., Renema, W., Cotton, L., Müller, W., Todd, J. A., Saraswati, P. K., Stassen, P., Ziegler, M., Pearson, P. N., et al. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1714744115 · Cited by 268 · see citing works
“…advantage over existing geochemical temperature proxies is that there is no resolvable dependence on seawater elemental or isotopic composition (28), and uncertainty is dominated by analytical noise so that, unlike other carbonate-bound proxies, paleotemperature errors are random rather than…”
Hollis, C. J., Jones, T. D., Anagnostou, E., Bijl, P. K., Cramwinckel, M. J., Cui, Y., Dickens, G. R., Edgar, K. M., Eley, Y. L., Evans, D., et al. (2019) · Geoscientific model development · doi:10.5194/gmd-12-3149-2019 · Cited by 268 · see citing works
Self-citationKele, S., Breitenbach, S. F. M., Capezzuoli, E., Meckler, A. N., Ziegler, M., Millan, I. M., Kluge, T., Deák, J., Hanselmann, K., John, C. M., et al. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.06.032 · Cited by 261 · see citing works
“…temperature calibrations (Ghosh et al.,75 2006a, 2007; Guo et al., 2009; Dennis and Schrag, 2010; Tripati et al., 2010; Eagle et al.,76 2010; Thiagarajan et al., 2011; Henkes et al., 2013; Grauel et al., 2013; Zaarur et al., 2013;77 Tang et al., 2014; Came et al., 2014; Fernandez et al., 2014).”
BackgroundInfluentialBonifacie, M., Calmels, D., Eiler, J. M., Horita, J., Chaduteau, C., Vasconcelos, C., Agrinier, P., Katz, A., Passey, B. H., Ferry, J. M., et al. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.11.028 · Cited by 233 · see citing works
“…thermometer has 5 been experimentally calibrated for synthetic inorganic calcite (Ghosh et al., 2006; Dennis and Schrag, 2010; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015; Kluge et al., 2015), siderite (Fernandez et al., 2014) and a variety of biogenic carbonates: aragonitic…”
MethodResultPetersen, S. V., Defliese, W. F., Saenger, C., Daëron, M., Huntington, K. W., John, C. M., Kelson, J. R., Bernasconi, S. M., Colman, A. S., Kluge, T., et al. (2019) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2018gc008127 · Cited by 209 · see citing works
“These selection criteria result in the inclusion of eight published inorganic carbonate calibration studies (De fl iese et al., 2015; Fernandez et al., 2014; García del Real et al., 2016; Kelson et al., 2017; Kluge et al., 2015; Passey & Henkes, 2012; Tang et al., 2014; Winkelstern et al., 2016).”
Self-citationHorton, T. W., Defliese, W. F., Tripati, A. K., & Oze, C. (2016) · Quaternary Science Reviews · doi:10.1016/j.quascirev.2015.06.030 · Cited by 203 · see citing works
“…were converted to temperatures (see Supplementary Information) using a variety of calibrations, (Ghosh et al., 2006; Eagle et al., 2013; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015), which have been adjusted to a common acid fractionation reference frame (Defliese et al., 2015).”
Self-citationDefliese, W. F., Hren, M. T., & Lohmann, K. C. (2015) · Chemical Geology · doi:10.1016/j.chemgeo.2014.12.018 · Cited by 190 · see citing works
Watkins, J. M., Hunt, J. D., Ryerson, F. J., & DePaolo, D. J. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.07.036 · Cited by 181 · see citing works
“This is in contrast to a recent analysis by Tang et al. (2014), who reported that there is no resolvable pH dependence on 18Oc−w for pH ≤ 9 in their inorganic calcite experiments conducted in the absence of the enzyme CA.”
ResultKelson, J. R., Huntington, K. W., Schauer, A. J., Saenger, C., & Lechler, A. R. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.010 · Cited by 177 · see citing works
Lunt, D. J., Huber, M. S., Anagnostou, E., Baatsen, M., Caballero, R., Deconto, R. M., Dijkstra, H. A., Yannick Donnadieu, A., Evans, D., Feng, R., et al. (2017) · Geoscientific model development · doi:10.5194/gmd-10-889-2017 · Cited by 169 · see citing works
Self-citationKluge, T., John, C. M., Jourdan, A.-L., Davis, S., & Crawshaw, J. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.02.028 · Cited by 155 · see citing works
Chang, B., Li, C., Liu, D., Foster, I., Tripati, A., Lloyd, M. K., Maradiaga, I., Luo, G., An, Z., She, Z., et al. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1916673117 · Cited by 152 · see citing works
Self-citationTripati, A. K., Hill, P. S., Eagle, R. A., Mosenfelder, J. L., Tang, J., Schauble, E. A., Eiler, J. M., Zeebe, R. E., Uchikawa, J., Coplen, T. B., et al. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.06.021 · Cited by 139 · see citing works
Self-citationA robust calibration of the clumped isotopes to temperature relationship for foraminifers
Meinicke, N., Ho, S. L., Hannisdal, B., Nürnberg, D., Tripati, A., Schiebel, R., & Meckler, A. N. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.11.022 · Cited by 121 · see citing works
“In contrast to this hypothesis, however, Tang et al. (2014) observed in inorganic calcite precipitation experiments that the D47-T relationship is largely insensitive to pH and growth rate at the external and internal conditions expected during foraminifer calcification.”
ResultSelf-citationCarbonate clumped isotope thermometry in continental tectonics
Huntington, K. W., & Lechler, A. R. (2015) · Tectonophysics · doi:10.1016/j.tecto.2015.02.019 · Cited by 127 · see citing works
“…(Affek, 2013; Cao and Liu, 2012; Eiler, 2013; Eiler et al., 2014; Guo et al., 2009; Hill et al., 2014; Ma et al., 2008; Schauble et al., 2006; Tang et al., 2014; Wang et al., 2004) and analytical methods (Bernasconi et al., 2013; Cao and Liu, 2012; Cui andWang, 2014; Dennis et al., 2011;…”
MethodGuo, W. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.07.055 · Cited by 108 · see citing works
Updated calibration of the clumped isotope thermometer in planktonic and benthic foraminifera
Peral, M., Daëron, M., Blamart, D., Bassinot, F., Dewilde, F., Smialkowski, N., Isguder, G., Bonnin, J., Jorissen, F., Kissel, C., et al. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.016 · Cited by 113 · see citing works
Calibration of the dual clumped isotope thermometer for carbonates
Fiebig, J., Daëron, M., Bernecker, M., Guo, W., Schneider, G., Boch, R., Bernasconi, S. M., Jautzy, J., & Dietzel, M. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.07.012 · Cited by 110 · see citing works
Self-citationFernandez, A., Müller, I. A., Rodríguez‐Sanz, L., van Dijk, J., Looser, N., & Bernasconi, S. M. (2017) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007106 · Cited by 101 · see citing works
A process-based model for non-equilibrium clumped isotope effects in carbonates
Watkins, J. M., & Hunt, J. D. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.09.042 · Cited by 105 · see citing works
“According to our model, the data from Tang et al. (2014) would be unable to resolve the expected pH- or rate-dependence on 47xtl, consistent with their findings.”
BackgroundResultInfluentialCenozoic evolution of deep ocean temperature from clumped isotope thermometry
Meckler, A. N., Sexton, P. F., Piasecki, A. M., Leutert, T. J., Marquardt, J., Ziegler, M., Agterhuis, T., Lourens, L. J., Rae, J. W. B., Barnet, J., et al. (2022) · Science · doi:10.1126/science.abk0604 · Cited by 120 · see citing works
“…2018; Piasecki et al., 2019; Tripati et al., 2010), appears to not be measurably affected by seawater pH within the range typical for the ocean (Tang et al., 2014; Tripati et al., 2015), and is largely robust to diagenetic overprinting in benthic foraminifera from typical ocean settings…”
Self-citationBergmann, K., Finnegan, S., Creel, R. C., Eiler, J. M., Hughes, N. C., Popov, L. E., & Fischer, W. W. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.11.015 · Cited by 98 · see citing works
“…is a composite of both synthetic and biogenic calcite, aragonite and dolomite minerals reacted at 70–90 C in 8 different laboratories (Bonifacie et al., 2017; Defliese et al., 2015; Fernandez et al., 2014; Henkes et al., 2013; Kele et al., 2015; Tang et al., 2014; Wacker et al., 2014) (Fig.”
BackgroundAffek, H. P., & Zaarur, S. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.005 · Cited by 96 · see citing works
Loyd, S. J., Sample, J., Tripati, R., Defliese, W. F., Brooks, K., Hovland, M. T., Torres, M. E., Marlow, J. J., Hancock, L. G., Martin, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms12274 · Cited by 92 · see citing works
Self-citationSiderite “clumped” isotope thermometry: a new paleoclimate proxy for humid continental environments
Fernandez, A., Tang, J., & Rosenheim, B. E. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.11.006 · Cited by 89 · see citing works
“A growing number of datasets coming from other laboratories (Dennis and Schrag, 2010; Eagle et al., 2013; Henkes et al., 2013; Tang et al., 2013; and this work) are beginning to challenge this assertion.”
BackgroundMethodResultInfluentialSelf-citationEagle, R., Enriquez, M., Grellet-Tinner, G., Pérez-Huerta, A., Hu, D., Tütken, T., Montanari, S., Loyd, S., Ramírez, P., Tripati, A., et al. (2015) · Nature Communications · doi:10.1038/ncomms9296 · Cited by 79 · see citing works
Self-citationClumped isotope composition of cold-water corals: A role for vital effects?
Spooner, P. T., Guo, W., Robinson, L. F., Thiagarajan, N., Hendry, K. R., Rosenheim, B. E., & Leng, M. J. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.01.023 · Cited by 84 · see citing works
“The existence of other inorganic carbonate calibration lines in the literature further complicates the interpretation of our results (Dennis and Schrag, 2010; Kim et al., 2010; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015; Kluge et al., 2015).”
InfluentialSelf-citationGallagher, T. M., & Sheldon, N. (2016) · Chemical Geology · doi:10.1016/j.chemgeo.2016.04.023 · Cited by 70 · see citing works
Assessing kinetic fractionation in brachiopod calcite using clumped isotopes
Bajnai, D., Fiebig, J., Tomášových, A., Garcia, S. A. M., Rollion‐Bard, C., Raddatz, J., Löffler, N., Primo, C., & Brand, U. (2018) · Scientific Reports · doi:10.1038/s41598-017-17353-7 · Cited by 80 · see citing works
Falk, E. S., Guo, W., Paukert, A. N., Matter, J. M., Mervine, E. M., & Kelemen, P. B. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.06.026 · Cited by 75 · see citing works
“…relative to the expected equilibrium, 567 are similar to those observed in carbonates derived from high-pH laboratory precipitation 568 experiments (~0.12-0.25‰, Schmid, 2011; ~0.26-0.31‰, Tang et al., 2014) and in 569 travertines from hyperalkaline springs in Liguria (~0.19-0.24‰, Schmid, 2011).”
InfluentialCombinatorial effects on clumped isotopes and their significance in biogeochemistry
Yeung, L. Y. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.09.020 · Cited by 68 · see citing works
Frontiers of Carbonate Clumped Isotope Thermometry
Huntington, K. W., & Petersen, S. V. (2023) · Annual Review of Earth and Planetary Sciences · doi:10.1146/annurev-earth-031621-085949 · Cited by 66 · see citing works
Biological signatures in clumped isotopes of O2
Yeung, L., Ash, J., & Young, E. (2015) · Science · doi:10.1126/science.aaa6284 · Cited by 60 · see citing works
Li, L., Fan, M., Davila, N., Jesmok, G., Mitsunaga, B., Tripati, A., & Orme, D. (2018) · Geological Society of America Bulletin · doi:10.1130/b32060.1 · Cited by 65 · see citing works
Self-citationDavies, A., & John, C. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.038 · Cited by 61 · see citing works
Accounting for kinetic isotope effects in Soreq Cave (Israel) speleothems
Affek, H. P., Matthews, A., Ayalon, A., Bar‐Matthews, M., Burstyn, Y., Zaarur, S., & Zilberman, T. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.08.008 · Cited by 62 · see citing works
Swart, P. K., Murray, S. T., Staudigel, P. T., & Hodell, D. A. (2019) · Geochemistry, Geophysics, Geosystems · doi:10.1029/2019gc008209 · Cited by 60 · see citing works
“…at 90 °C (Bonifacie et al., 2017; Dennis & Schrag, 2010; Fernandez et al., 2014; Kelson et al., 2017; Kluge et al., 2015; B.H. Passey & Henkes, 2012; Tang et al., 2014) had reduced slopes compared to those published by Ghosh et al. (2007) and Zaarur et al. (2013), which were reacted at 25 °C.”
BackgroundResultModestou, S. E., Leutert, T. J., Fernandez, A., Lear, C. H., & Meckler, A. N. (2020) · Paleoceanography and Paleoclimatology · doi:10.1029/2020pa003927 · Cited by 57 · see citing works
“Past seawater pH, dissolved inorganic carbon, and carbonate saturation state have been shown to have no discernible effect outside analytical uncertainty in the range of pH expected in average marine environments (Eagle et al., 2013; Hill et al., 2014; Kelson et al., 2017; Tang et al., 2014; Tripati et al., 2015; Watk…”
BackgroundInfluentialDevils Hole paleotemperatures and implications for oxygen isotope equilibrium fractionation
Kluge, T., Affek, H., Dublyansky, Y., & Spötl, C. (2014) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2014.05.047 · Cited by 63 · see citing works
Murray, S. T., & Swart, P. K. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.021 · Cited by 52 · see citing works
Petersen, S., & Schrag, D. P. (2015) · Paleoceanography · doi:10.1002/2014pa002769 · Cited by 53 · see citing works
“The many published Δ47-T calibrations tend to fall into two groups, those with steeper slopes similar to GH06 and those with shallower slopes similar to DS10 [Came et al., 2014, and references therein; Tang et al., 2014, and references therein].”
ResultGuo, Y., Deng, W., & Wei, G. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.01.012 · Cited by 50 · see citing works
Mangenot, X., Bonifacie, M., Gasparrini, M., Götz, A., Chaduteau, C., Ader, M., & Rouchon, V. (2017) · Chemical Geology · doi:10.1016/j.chemgeo.2017.10.011 · Cited by 51 · see citing works
“…or composition of the analyzed carbonate (e.g., Bonifacie et al., 2017), or by the precipitation conditions including the precipitation rate (e.g., Tang et al. 2014 ; Kelson et al., 2017; Watkins and Hunt, 2015), the pH and the salinity of the carbonate parent fluids (e.g., (Hill et al., 2014;…”
Levitt, N. P., Eiler, J. M., Romanek, C. S., Beard, B. L., Xu, H., & Johnson, C. M. (2018) · Geochemistry, Geophysics, Geosystems · doi:10.1002/2017gc007089 · Cited by 48 · see citing works
Clumped-isotope thermometry of magnesium carbonates in ultramafic rocks
García del Real, P., Maher, K., Kluge, T., Bird, D. K., Brown, G. E., & John, C. M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.08.003 · Cited by 50 · see citing works
“Although this D 47 offset is similar to our measurements ( (cid:1) 0.03 ‰ ), pH effects proposed by Hill et al. (2014) and Tripati et al. (2015) appear not to affect experimentally grown carbonates at pH 8.3–10.5 (Tang et al., 2014) and natural travertines at pH 5.6–9 (Kele et al., 2015).”
InfluentialClumped isotope temperature calibration for calcite: Bridging theory and experimentation
Jautzy, J. J., Savard, M. M., Dhillon, R. S., Bernasconi, S. M., & Smirnoff, A. (2020) · Geochemical Perspectives Letters · doi:10.7185/geochemlet.2021 · Cited by 50 · see citing works
“Recent studies (Coplen, 2007; Tang et al., 2014; Tripati et al., 2015; Watkins and Hunt, 2015; Levitt et al., 2018; Daëron et al., 2019) seem to agree regarding a dependence of the αcc/w 2.”
BackgroundStaudigel, P. T., Murray, S. T., Dunham, D. P., Frank, T. D., Fielding, C. R., & Swart, P. K. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.01.002 · Cited by 48 · see citing works
A 600-Million-Year Carbonate Clumped-Isotope Record from the Sultanate of Oman
Bergmann, K. D., Al Balushi, S. A. K., Mackey, T. J., Grotzinger, J. P., & Eiler, J. M. (2018) · Journal of Sedimentary Research · doi:10.2110/jsr.2018.51 · Cited by 46 · see citing works
“…et al. (2017), a composite of both synthetic and biogenic calcite, aragonite, and dolomite minerals analyzed at 70–908C in eight different laboratories (Henkes et al. 2013; Fernandez et al. 2014; Tang et al. 2014; Wacker et al. 2014; Defliese et al. 2015; Kele et al. 2015; Bonifacie et al. 2017).”
BackgroundSample, J., Torres, M. E., Fisher, A., Hong, W., Destrigneville, C., Defliese, W. F., & Tripati, A. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.013 · Cited by 46 · see citing works
Self-citationLoyd, S. J., Corsetti, F. A., Eagle, R. A., Hagadorn, J. W., Shen, Y., Zhang, X., Bonifacie, M., & Tripati, A. K. (2015) · Precambrian Research · doi:10.1016/j.precamres.2015.04.010 · Cited by 45 · see citing works
“Published empirical calibrations extend from 1 to 65 ◦C (Ghosh et al., 2006; Dennis et al., 2011; Zaarur et al., 2013; Tang et al., 2014), and application to these samples would require a large extrapolation well beyond this temperature range.”
BackgroundSelf-citationKatz, A., Bonifacie, M., Hermoso, M., Cartigny, P., & Calmels, D. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.02.025 · Cited by 44 · see citing works
“experimental studies aiming at calibrating the temperature dependence of Δ47 values in inorganic carbonate minerals have been conducted (Ghosh et al., 2006; Dennis et Schrag, 2010; Zaarur et al., 2013; Fernandez et al., 2014; Tang et al., 2014; Defliese et al., 2015; Kele et al., 2015; Kluge et al., 2015; Tripati et a…”
BackgroundSpencer, C., & Kim, S.-T. (2015) · Geosciences Journal · doi:10.1007/s12303-015-0018-1 · Cited by 44 · see citing works
“Recent modifications to the McCrea-style reaction vessel have increased the reaction temperatures to 100 °C through submersion in boiling water, and have enabled the immediate collection of acid-liberated CO2 in an attached liquid nitrogen trap while carbonate is reacting with the phosphoric acid (Rosenheim et al., 20…”
BackgroundInfluentialBeaudoin, N. E., Olivier Lacombe, F., Hoareau, G., & Callot, J. (2022) · Geological Magazine · doi:10.1017/s0016756822001327 · Cited by 43 · see citing works
“Meanwhile, intensive calibration work has been conducted (Affek, 2012; Zaarur et al. 2013; Hough et al. 2014; Tang et al. 2014; Wacker et al. 2014; Bonifacie et al. 2017; Anderson et al. 2021), with notable recent effort to improve the analytical accuracy (Daëron, 2021) and to reduce the persistent…”
BackgroundClumped-isotope signatures at equilibrium of CH4, NH3, H2O, H2S and SO2
Liu, Q., & Liu, Y. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.11.040 · Cited by 41 · see citing works
Fan, M., Ayyash, S., Tripati, A., Passey, B. H., & Griffith, E. M. (2017) · Geological Society of America Bulletin · doi:10.1130/b31732.1 · Cited by 41 · see citing works
Self-citationThiagarajan, N., Crémière, A., Blättler, C., Lepland, A., Kirsimäe, K., Higgins, J., Brunstad, H., & Eiler, J. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.03.015 · Cited by 31 · see citing works
Dual clumped isotope thermometry of coral carbonate
Davies, A., Guo, W., Bernecker, M., Tagliavento, M., Raddatz, J., Gischler, E., Flögel, S., & Fiebig, J. (2022) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2022.10.015 · Cited by 42 · see citing works
Calibration of dolomite clumped isotope thermometry
Winkelstern, I. Z., Kaczmarek, S. E., Lohmann, K. C., & Humphrey, J. D. (2016) · Chemical Geology · doi:10.1016/j.chemgeo.2016.09.021 · Cited by 40 · see citing works
Kimball, J., Eagle, R., & Dunbar, R. (2016) · Biogeosciences · doi:10.5194/bg-13-6487-2016 · Cited by 36 · see citing works
“To date, at least seven synthetic calibrations have been published (Ghosh et al., 2006; Dennis and Schrag, 2010; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015; Kluge et al., 2015; Tripati et al., 2015).”
BackgroundResultA calibration equation between Δ 48 values of carbonate and temperature
Swart, P. K., Lu, C., Moore, E. W., Smith, M. E., Murray, S. T., & Staudigel, P. T. (2021) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.9147 · Cited by 40 · see citing works
Petersen, S., Winkelstern, I., Lohmann, K. C., & Meyer, K. W. (2016) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.7438 · Cited by 34 · see citing works
Weger, R. J., Murray, S., McNeill, D., Swart, P., Eberli, G., Rodriguez-Blanco, L., Tenaglia, M., & Rueda, L. E. (2019) · American Association of Petroleum Geologists Bulletin · doi:10.1306/10021817384 · Cited by 29 · see citing works
Cui, J., Li, S., & Mao, Z. (2019) · Marine and Petroleum Geology · doi:10.1016/j.marpetgeo.2019.03.028 · Cited by 35 · see citing works
A Combined Model for Kinetic Clumped Isotope Effects in the CaCO3‐DIC‐H2O System
Watkins, J. M., & Devriendt, L. S. (2022) · Geochemistry Geophysics Geosystems · doi:10.1029/2021gc010200 · Cited by 34 · see citing works
“Summary of the Tang et al. (2014) Experiments The experimental setup is shown in Figure 4a. A polyethylene (PE) container houses an inner solution with no Ca 2+ but high CO2(aq). The PE container is placed in an outer solution with 10 mM CaCl2 and no DIC initially. The DIC is delivered to the outer solution by CO2 dif…”
BackgroundMethodInfluentialHudson, A. M., Quade, J., Ali, G., Boyle, D., Bassett, S., Huntington, K. W., De los Santos, M. G., Cohen, A. S., Lin, K., & Wang, X. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.06.024 · Cited by 32 · see citing works
“Additional calibrations for inorganic carbonates (Dennis and Schrag, 2010; Zaarur et al., 2013; Tang et al., 2014; Defliese et al., 2015; Kluge et al., 2015; Kele et al., 2015) comprise data that have been calculated using 17O correction parameters based on the quartzwater system (e.g., Santrock et…”
BackgroundMethodOxygen isotope fractionation in the siderite-water system between 8.5 and 62 °C
van Dijk, J., Fernandez, A., Müller, I. A., Lever, M., & Bernasconi, S. M. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2017.10.009 · Cited by 30 · see citing works
van Dijk, J., Fernandez, A., Storck, J. C., White, T. S., Lever, M., Müller, I. A., Bishop, S., Seifert, R. F., Driese, S. G., Krylov, A., et al. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2019.03.018 · Cited by 29 · see citing works
Isotopic disequilibrium in brachiopods disentangled with dual clumped isotope thermometry
Davies, A., Brand, U., Tagliavento, M., Bitner, M. A., Bajnai, D., Staudigel, P. T., Bernecker, M., & Fiebig, J. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.08.005 · Cited by 31 · see citing works
Came, R. E., Azmy, K., Tripati, A., & Olanipekun, B.-J. (2017) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.10.028 · Cited by 29 · see citing works
“…2015) provide improved constraints on the slope of the inorganic calcite calibration equation, and confirm earlier results (Dennis and Schrag, 2010; Tang et al., 2014; Wacker et al., 2014; Defliese et al., 2015) suggesting that calcites reacted in phosphoric acid at high temperature (70–90 C)…”
MethodResultInfluentialSelf-citationZhang, N., Lin, M., Snyder, G., Kakizaki, Y., Yamada, K., Yoshida, N., & Matsumoto, R. (2019) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2019.02.005 · Cited by 22 · see citing works
Uchikawa, J., Chen, S., Eiler, J. M., Adkins, J. F., & Zeebe, R. E. (2021) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2021.08.014 · Cited by 27 · see citing works
Warm deep-sea temperatures across Eocene Thermal Maximum 2 from clumped isotope thermometry
Agterhuis, T., Ziegler, M., de Winter, N. J., & Lourens, L. J. (2022) · Communications Earth & Environment · doi:10.1038/s43247-022-00350-8 · Cited by 28 · see citing works
Zaarur, S., Affek, H., & Stein, M. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.12.034 · Cited by 24 · see citing works
Dietzel, M., Purgstaller, B., Kluge, T., Leis, A., & Mavromatis, V. (2020) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2020.02.032 · Cited by 28 · see citing works
Self-citationKluge, T., & John, C. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.03.031 · Cited by 29 · see citing works
“Furthermore, the D47-T slope agrees with recent synthetic calibration studies that acid-reacted carbonates at elevated temperatures of 90 C or 100 C (Dennis and Schrag, 2010; Passey and Henkes, 2012; Fernandez et al., 2014; Tang et al., 2014) and is discussed in Kluge et al. (2015).”
BackgroundPetryshyn, V. A., Rivera, M. J., Agić, H., Frantz, C. M., Corsetti, F. A., & Tripati, A. (2016) · Palaeogeography Palaeoclimatology Palaeoecology · doi:10.1016/j.palaeo.2016.02.054 · Cited by 27 · see citing works
“…0.5 3.222 1.7 0.4 AC C EP TE D M AN U SC R IP T 53 δ α δ δ δ Δ AC C EP TE D M AN U SC R IP T 54 Zon e δ18O water (reconstructed) Ave Δ47 T (K)- Tang et al., 2014 Ave Δ47 T (C)- Tang et al., 2014 Lake dept h (m) Lake vol (km3 ) Change in lake depth from previou s layer(m ) Change in…”
InfluentialSelf-citationStaudigel, P. T., & Swart, P. K. (2018) · Geochemistry Geophysics Geosystems · doi:10.1029/2018gc007500 · Cited by 25 · see citing works
“…the Δ47 value of the crystalizing carbonate minerals, and the kinetic effects on oxygen isotope abundance and the abundance of clumped isotope bonds do not necessarily need to correlate with one another, despite relying upon the same exchange mechanisms (Tang et al., 2014; Watkins & Hunt, 2015).”
BackgroundKatō, H., Amekawa, S., Kano, A., Mori, T., Kuwahara, Y., & Quade, J. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.10.016 · Cited by 25 · see citing works
Petrizzo, D., Young, E., & Runnegar, B. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2014.07.017 · Cited by 24 · see citing works
“…and this study agree closely with each other (Table 2), and with the inorganic calibrations of Dennis and Schrag (2010), Fernandez et al. (2014), Tang et al. (2014), and the theoretical calibrations of Schauble et al. (2006) and Guo et al. (2009), these are clearly different from the steeper…”
ResultZhang, N., Yamada, K., Kano, A., Matsumoto, R., & Yoshida, N. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.05.001 · Cited by 21 · see citing works
Li, H., Liu, X., Arnold, A., Elliott, B. M., Flores, R., Kelley, A. M., & Tripati, A. (2021) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2021.116840 · Cited by 23 · see citing works
Self-citationAcid digestion of carbonates using break seal method for clumped isotope analysis
Fosu, B. R., Ghosh, P., Mishra, D., Banerjee, Y., Prasanna, K., & Sarkar, A. (2018) · Rapid Communications in Mass Spectrometry · doi:10.1002/rcm.8304 · Cited by 21 · see citing works
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Self-citationDennis, P., Myhill, D. J., Marca, A., & Kirk, R. (2018) · Journal of the Geological Society · doi:10.1144/jgs2016-117 · Cited by 14 · see citing works
“At present there exist many different calibrations (e.g. Ghosh et al. 2006; Dennis & Schrag 2010; Henkes et al. 2013; Petrizzo et al. 2014; Tang et al. 2014; Wacker et al. 2014; Kelson et al. 2017; Kirk 2017) with a range in both the temperature sensitivity and offset of the different studies.”
BackgroundClumped isotopic compositions of cultured and natural land-snail shells and their implications
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“The acid digestion correction varies in different experimental studies from 0.07 to 0.09& (e.g., Defliese et al., 2015; Passey & Henkes, 2012; Tang et al., 2014; Wacker et al., 2013).”
BackgroundInfluentialTheoretical and Experimental Principles
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“Lower ocean pH has been shown to increase planktic foraminiferal δ 18 O values (Spero et al., 1997; Uchikawa & Zeeve, 2010), while the influence on Δ 47 values is negligible by comparison (Guo, 2020; Tang et al., 2014; Tripati et al., 2015).”
Parvez, Z. A., Lucarelli, J. K., Matamoros, I. W., Rubi, J., Miguel, K., Elliott, B., Flores, R., Ulrich, R. N., Eagle, R. A., Watkins, J. M., et al. (2023) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2023.06.022 · Cited by 9 · see citing works
“Tang et al. (2014) hypothesized that kinetic fractionation observed in inorganic calcite precipitation experiments at pH ≥ 10 occurred due to the DIC pool not having sufficient time to achieve isotopic equilibrium prior to mineral precipitation, and DIC speciation favoring CO 32 – at higher pH.…”
BackgroundSelf-citation
- Authors
- Tang, J., Dietzel, M., Fernandez, A., Tripati, A. K., & Rosenheim, B. E.
- Affiliations
- Tulane University (US)
- Graz University of Technology (AT)
- University of California, Los Angeles (US)
- Corresponding author
- Tang, Jianwu
- Venue
- Geochimica et Cosmochimica Acta
- Publisher
- Elsevier BV
- Published
- 2014-06
- Volume
- 134
- Pages
- 120-136
- ISSN
- 0016-7037 (ISSN-L)
- OpenAlex
- W2121761338
- Cited by
- 137
- References
- 64
- Citations by year
- 2026: 4 · 2025: 4 · 2024: 4 · 2023: 6 · 2022: 15 · 2021: 11 · 2020: 9 · 2019: 16 · 2018: 18 · 2017: 12 · 2016: 13 · 2015: 18 · 2014: 6 · 2013: 1
- FWCI
- 10.85
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- www.elsevier.com/open-access/userlicense/1.0/ (am, 296 d)
- doi.org/10.15223/policy-017 (stm-asf)
- doi.org/10.15223/policy-037 (stm-asf)
- doi.org/10.15223/policy-012 (stm-asf)
- doi.org/10.15223/policy-029 (stm-asf)
- doi.org/10.15223/policy-004 (stm-asf)
- Locations
- Geochimica et Cosmochimica Acta (acceptedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (acceptedVersion)
- Digital Commons - University of South Florida (University of South Florida) (submittedVersion)
- eScholarship (California Digital Library) (submittedVersion)
- Funders
- Deutsche Forschungsgemeinschaft (Ei272/20-1/-2)
- Austrian Science Fund (I34-B06)
- National Science Foundation
- University of California, Los Angeles
- American Chemical Society (51182-DNI2)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Geology and Paleoclimatology Research
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Keywords
- Δ47, calcite precipitation, precipitation kinetics, precipitation rate, ionic strength, pH effect, paleothermometry, carbonate mineralogy, acid digestion, oxygen isotopes
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