Recovery of cobalt from spent lithium ion batteries by using acidic and basic extractants in solvent extraction process

Torkaman, Rezvan; Asadollahzadeh, Mehdi; Torab-Mostaedi, Meisam; Ghanadi Maragheh, Mohammad

doi:10.1016/j.seppur.2017.06.023

Cited by 133Extraction and Separation ProcessesChemical and Physical Properties in Aqueous SolutionsRadioactive element chemistry and processing

Recovery of cobalt from spent lithium ion batteries by using acidic and basic extractants in solvent extraction process

Torkaman, Rezvan, Asadollahzadeh, Mehdi, Torab-Mostaedi, Meisam, Ghanadi Maragheh, Mohammad·2017·Separation and Purification Technology

DOI 10.1016/j.seppur.2017.06.023

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Strong interaction of extractants and diluents leads to lower performance in the extraction of metal ions.
“The strong interaction of extractants and diluents leads to a lower performance in the extraction of metal ions [7].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [7]
Cyanex 301 has higher loading capacity for Co(II) from dilute chloride solution at pH 6 than Cyanex 272.
“The advantage of Cyanex 301 lies in its higher loading capacity for Co(II) from dilute chloride solution with pH 6 than Cyanex 272.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [7]
Extraction efficiency depends on temperature and polarity of diluents.
“However, the extraction e ciency depends on the temperature and the polarity of the diluents.”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [7]
Strong interaction between polar diluents and extractants leads to a decrease in extraction efficiency of Co(II).
“In general, the strong interaction between polar diluents and extractants leads to a decrease in the extraction e ciency of Co(II) [7,29].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [7]
Many metal ions in loaded phases of Cyanex extractants can be stripped by acidic agents such as HCl, H2SO4, HNO3, and HClO4.
“It was reported that many metal ions in the loaded phases of Cyanex extractants can be stripped by acidic agents such as HCl, H2SO4, HNO3, and HClO4 [7,27,31].”
From Review on the Comparison of the Chemical Reactivity of Cyanex 272, Cyanex 301 and Cyanex 302 for Their Application to Metal Separation from Acid Media (2020) · cites this paper as [7]

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Authors: Torkaman, R., Asadollahzadeh, M., Torab-Mostaedi, M., & Ghanadi Maragheh, M.
Affiliations: Nuclear Science and Technology Research Institute (IR)
Corresponding author: Torkaman, Rezvan
ORCID: Asadollahzadeh, Mehdi
Venue: Separation and Purification Technology
Publisher: Elsevier BV
Published: 2017-10
Volume: 186
Pages: 318-325
ISSN: 1383-5866 (ISSN-L)
DOI: 10.1016/j.seppur.2017.06.023
OpenAlex: W2626367431
Cited by: 133
References: 29
Citations by year: 2026: 14 · 2025: 13 · 2024: 21 · 2023: 13 · 2022: 20 · 2021: 13 · 2020: 17 · 2019: 13 · 2018: 8 · 2017: 1
FWCI: 8.29
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Separation and Purification Technology (publishedVersion)
Topics: Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
Physical Sciences › Chemistry › Inorganic Chemistry › Radioactive element chemistry and processing
Keywords: cobalt recovery, spent lithium-ion batteries, solvent extraction, D2EHPA, Cyanex 272, time of arrival, chloride solutions, metal stripping, stoichiometric coefficients, leach liquor, battery recycling

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Recovery of cobalt from spent lithium ion batteries by using acidic and basic extractants in solvent extraction process

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