Evaluation of pilot-scale biochar-amended woodchip bioreactors to remove nitrate, metals, and trace organic contaminants from urban stormwater runoff
Abstract
Stormwater is increasingly being valued as a freshwater resource in arid regions and can provide opportunities for beneficial reuse via aquifer recharge if adequate pollutant removal can be achieved. We envision a multi-unit operation approach to capture, treat, and recharge (CTR) stormwater using low energy, cost-effective technologies appropriate for larger magnitude, less frequent events. Herein, we tested nutrient, metal, and trace organic contaminant removal of a pilot-scale CTR system in the laboratory using biochar-amended woodchip bioreactors following eight months of aging under field conditions with exposure to real stormwater. Replicate columns with woodchips and biochar (33% by weight), woodchips and straw, or woodchips only were operated with continuous, saturated flow for eight months using water from a watershed that drained an urban area consisting of residential housing and parks in Sonoma, California. After aging, columns were challenged for five months by continuous exposure to synthetic stormwater amended with 50 μg L -1 of six trace organic contaminants (i.e., fipronil, diuron, 1H-benzotriazole, atrazine, 2,4-D, and TCEP) and five metals (Cd, Cu, Ni, Pb, Zn) frequently detected in stormwater in order to replicate the treatment unit operation of a CTR system. Throughout the eight-month aging and five-month challenge experiment, nitrate concentrations were below the detection limit after treatment (i.e., -1 ). The removal efficiencies for metals in all trea…
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Batch/column/mesocosm experiments have frequently shown that biochar amendment can enhance the OMP removal capacity of biofilters.
“Batch/column/mesocosm experiments have frequently shown that biochar amendment can enhance the OMP removal capacity of biofilters (Ashoori et al., 2019; Buates et al., 2024; Chen et al., 2017; Pritchard et al., 2023; Roh et al., 2015; Spahr et al., 2022; Ulrich et al., 2017b, 2017a, 2015; Yan et al., 2017; Zhang et al., 2015).”
From Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals (2025) · cites this paper as Ashoori et al., 2019
The particle size of the biochar used herein (0.1-10 mm; d50: 4 mm) was larger than what has been used in most lab-scale studies (dmax<1 mm) that demonstrate relatively effective OMP removal rates.
“The particle size of the biochar used herein (0.1–10 mm; d50: 4 mm) was larger than what has been used in most lab-scale studies (dmax<1 mm) that demonstrate relatively effective OMP removal rates (e.g., Ashoori et al., 2019; Spahr et al., 2022; Ulrich et al., 2017b, 2017a, 2015).”
From Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals (2025) · cites this paper as Ashoori et al., 2019
Extensive amounts of small-sized biochar may reduce hydraulic conductivity, limiting the biochar's longevity.
“Extensive amounts of small-sized biochar may also reduce hydraulic”
From Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals (2025) · cites this paper as Ashoori et al., 2019
Biochar is abundant and inexpensive to produce and exhibits a huge potential for applications in stormwater treatment.
“Biochar is another emerging material, which is both abundant and inexpensive to produce [19], and exhibits a huge potential for applications in stormwater treatment [20][21][22].”
From Application of Biochar in Stormwater Treatment: Experimental and Modeling Investigation (2021) · cites this paper as [20]
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- Authors
- Ashoori, N., Teixido, M., Spahr, S., LeFevre, G. H., Sedlak, D. L., & Luthy, R. G.
- Affiliations
- U.S. National Science Foundation (US)
- University of Iowa (US)
- Corresponding author
- Luthy, Richard G.
- Venue
- Water Research
- Publisher
- Elsevier BV
- Published
- 2019-05
- Volume
- 154
- Pages
- 1-11
- ISSN
- 0043-1354 (ISSN-L)
- OpenAlex
- W2913524403
- Cited by
- 197
- References
- 61
- Citations by year
- 2026: 20 · 2025: 28 · 2024: 23 · 2023: 18 · 2022: 32 · 2021: 33 · 2020: 29 · 2019: 14
- FWCI
- 11.44
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Water Research (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Water Research Foundation (4567)
- National Science Foundation Engineering Research Center Program for Reinventing the Nation’s Urban Water Infrastructure (1028968)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › Urban Stormwater Management Solutions
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Environmental Science › Pollution › Pharmaceutical and Antibiotic Environmental Impacts
- Keywords
- biochar, woodchip bioreactors, stormwater treatment, groundwater recharge, nitrate removal, heavy metal removal, trace organic contaminants, atrazine, fipronil, TCEP, diuron, benzotriazole, 2,4-D, straw amendment, breakthrough modeling, urban stormwater
- MeSH terms
- California, Charcoal, Metals, Bioreactors, Denitrification
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