Sonochemistry of carbohydrate compounds
Abstract
A literature survey of carbohydrate sonochemistry is presented. The basic physical principles are discussed qualitatively before the main applications are reviewed. Along with other non-classical activation methods developed in accordance with 'Green Chemistry' requirements, ultrasonic irradiation offers important potential for the conversion of biomass raw materials such as polymeric carbohydrates to useful lower weight molecules. A number of reactions involving mono- or disaccharides, considered as a renewable source of fine chemicals, can also be performed with ultrasonic activation. This is the case for glycosylation, acetalization, oxidation, C-D, C-heteroatom, and C-C bond formations, which are improved in terms of reaction rates and yields and, in some instances, in their chemo-, regio- and stereoselectivities. The equipment available is briefly described, and practical considerations are given.
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The main non-enzymatic hydrolytic techniques used at an industrial level are ultrasound, microwaves, free radicals, or diluted acids.
“the main non-enzymatic hydrolytic techniques used at an industrial level are ultrasound (in the case of carrageenans, agarose and xylan), microwaves (for hydrolysis of exopolysaccharides obtained from Porphyridium cruentum), use of free radicals (for fucoidan and algae galactan), or the application of diluted acids (for example, phosphoric acid) [124,125,126,127,128,129,130].”
From The Potential of Seaweeds as a Source of Functional Ingredients of Prebiotic and Antioxidant Value (2019) · cites this paper as [124]
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- Authors
- Kardos, N., & Luche, J.-L.
- Affiliations
- Université Savoie Mont Blanc (FR)
- Corresponding author
- Kardos, Nathalie
- ORCID
- Kardos, Nathalie
- Venue
- Carbohydrate Research
- Publisher
- Elsevier BV
- Published
- 2001-05
- Volume
- 332
- Issue
- 2
- Pages
- 115-131
- ISSN
- 0008-6215 (ISSN-L)
- OpenAlex
- W2089269752
- Cited by
- 263
- References
- 113
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- FWCI
- 0.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Carbohydrate Research (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Ultrasound and Cavitation Phenomena
- Physical Sciences › Chemistry › Organic Chemistry › Carbohydrate Chemistry and Synthesis
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Keywords
- sonochemistry, ultrasound, carbohydrates, biomass conversion, monosaccharides, disaccharides, glycosylation, acetalization, oxidation, carbon-heteroatom bond formation, C–C bond formation, green chemistry, reaction selectivity
- MeSH terms
- Biopolymers, Carbohydrates, Carbon, Cellulose, Chemistry, Organic, Deuterium, Dextrans, Disaccharides, Glycosylation, Hydrolysis, Lactose, Oxidation-Reduction, Polysaccharides, Sonication, Starch, Stress, Mechanical, Sucrose, Temperature, Reactive Oxygen Species
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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