Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface speciation and chemical affinity control

Pokrovsky, Oleg S.; Schott, Jacques

doi:10.1016/s0016-7037(03)00238-2

Cited by 348CO2 Sequestration and Geologic InteractionsCrystallization and Solubility StudiesCalcium Carbonate Crystallization and Inhibition

Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface speciation and chemical affinity control

Pokrovsky, Oleg S., Schott, Jacques·2004·Geochimica et Cosmochimica Acta

DOI 10.1016/s0016-7037(03)00238-2

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The pH of the solutions was not high enough to initiate brucite formation at the end of the experiments.
“as the pH of the solutions was not high enough to initiate brucite formation (Pokrovsky and Schott, 2004; Li et al., 2014) at the end of the experiments.”
From Tracing olivine carbonation and serpentinization in CO2-rich fluids via magnesium exchange and isotopic fractionation (2018) · cites this paper as Pokrovsky and Schott, 2004
The limited effect of nucleation surface area is related to the fact that the secondary minerals reached close-to-equilibrium conditions with the fluid relatively quickly, thus their formation rates were primarily driven by the affinity term (1-SI_m), rather than the surface area of the nuclei and crystals.
“This observation is related to the fact that the secondary minerals reached close-to-equilibrium conditions with the fluid relatively quickly, thus their formation rates were primarily driven by the affinity term (1-SI m ), rather than the surface area of the nuclei and crystals (Pokrovsky and Schott, 2004).”
From Tracing olivine carbonation and serpentinization in CO2-rich fluids via magnesium exchange and isotopic fractionation (2018) · cites this paper as Pokrovsky and Schott, 2004
The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters.
“The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters [11,38,[52][53][54][55].”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [54]

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Authors: Pokrovsky, O. S., & Schott, J.
Venue: Geochimica et Cosmochimica Acta
Publisher: Elsevier BV
Published: 2004-01
Volume: 68
Issue: 1
Pages: 31-45
ISSN: 0016-7037 (ISSN-L)
DOI: 10.1016/s0016-7037(03)00238-2
OpenAlex: W2090430868
Cited by: 348
References: 80
Citations by year: 2026: 35 · 2025: 25 · 2024: 20 · 2023: 16 · 2022: 16 · 2021: 20 · 2020: 23 · 2019: 18 · 2018: 22 · 2017: 17 · 2016: 13 · 2015: 11 · 2014: 18 · 2013: 24 · 2012: 13
FWCI: 7.96
Type: journal article
Language: en
Open access: closed
Licence: www.elsevier.com/tdm/userlicense/1.0/ (tdm)
Locations: Geochimica et Cosmochimica Acta (publishedVersion)
Helmholtz Centre for Ocean Research Kiel (GEOMAR) (acceptedVersion)
HAL (submittedVersion)
Topics: Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
Keywords: brucite, magnesium hydroxide, dissolution kinetics, precipitation kinetics, surface speciation, surface charge, isoelectric point, transition state theory, saturation index, surface hydroxylation, electric double layer, rate law

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Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface speciation and chemical affinity control

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