Chrysotile dissolution rates: Implications for carbon sequestration
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Mg-silicate minerals such as forsterite and serpentine group minerals have pH-dependent dissolution rates much faster than other silicate minerals, yet their dissolution at Earth's surface conditions is still sluggish.
“Mg-silicate minerals such as forsterite (Mg2SiO4) and serpentine group minerals [Mg3Si2O5(OH)4] have pH-dependent dissolution rates that are much faster than other silicate minerals, yet their dissolution at Earth's surface conditions is still sluggish [22,81].”
From Integrated Mineral Carbonation of Ultramafic Mine Deposits—A Review (2018) · cites this paper as [81]
Limited dissolution of Mg2+ occurred, and the dissolution did not correspond with published lizardite values to the order of 10−11.
“Limited dissolution of Mg2+ occurred, where the dissolution did not correspond with published lizardite values to the order of 10−11 [45].”
From Carbon Mineralization with North American PGM Mine Tailings—Characterization and Reactivity Analysis (2021) · cites this paper as [45]
pH-dependent dissolution rates for lizardite, chrysotile, forsterite, and brucite have been experimentally determined and generally increase with increasing acidity.
“The pH-dependent dissolution rates for some common ultramafic tailings minerals such lizardite [55], chrysotile [38], forsterite [53] and brucite [54] have been experimentally determined and generally increase with increasing acidity.”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [38]
The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters.
“The reactivity of ultramafic mine waste is enhanced by increased surface area due to mineral processing, yet dissolution rates remain sluggish at the alkaline pH of process waters [11,38,[52][53][54][55].”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [38]
There was good agreement between experimental results and those predicted using a pH-dependent chrysotile dissolution rate law, hence geochemical modeling could be used in a predictive capacity.
“There was good agreement between the experimental results and those predicted using a pH-dependent chrysotile dissolution rate law [38], hence geochemical modeling could be used in a predictive capacity.”
From Strategizing carbon-neutral mines: A case for pilot projects (2014) · cites this paper as [38]
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“Mg-silicate minerals such as forsterite (Mg2SiO4) and serpentine group minerals [Mg3Si2O5(OH)4] have pH-dependent dissolution rates that are much faster than other silicate minerals, yet their dissolution at Earth’s surface conditions is still sluggish [22,81].”
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Self-citation
- Authors
- Thom, J. G. M., Dipple, G. M., Power, I. M., & Harrison, A. L.
- Affiliations
- University of British Columbia (CA)
- Corresponding author
- Dipple, Gregory M.
- Venue
- Applied Geochemistry
- Publisher
- Elsevier BV
- Published
- 2013-08
- Volume
- 35
- Pages
- 244-254
- ISSN
- 0883-2927 (ISSN-L)
- OpenAlex
- W2080282162
- Semantic Scholar
- 9fedc41d4523ab21e6c89eeee8cd8737abfd568f
- Cited by
- 86
- References
- 88
- Citations by year
- 2026: 6 · 2025: 12 · 2024: 6 · 2023: 6 · 2022: 4 · 2021: 13 · 2020: 9 · 2019: 6 · 2018: 5 · 2017: 5 · 2016: 3 · 2015: 3 · 2014: 7 · 2013: 1
- FWCI
- 3.88
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Geochemistry (publishedVersion)
- Bern Open Repository and Information System (University of Bern) (submittedVersion)
- UCL Discovery (University College London) (submittedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Keywords
- chrysotile, serpentine minerals, mineral dissolution kinetics, CO2 sequestration, silicon flux, pH dependence, mine tailings, reaction path modeling, CO2 geological storage
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