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The low temperature performance of Li-ion batteries
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“The LT effects on charging and discharging are asymmetric: the charge transfer resistance at LTs in the discharged state is substantially higher, making it much more challenging when charging a discharged LIB at LTs [14,15].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [14]
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“When the battery temperature drops below –10C, the battery’s energy and power are considerably decreased since the battery’s efficiency declines dramatically, resulting in a significant loss in EV driving range [23]–[25].”
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BackgroundRecent Progress on the Low‐Temperature Lithium Metal Batteries and Electrolytes
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“Zhang et al. [15], demonstrated that with a decrease in temperature, the internal resistance of the battery increases.”
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“As the consequence, slower kinetics of the electrode reactions are observed.(30) This observation indicates that the high internal impedance of Li-ion battery at low temperature is contributed dominantly by the charge-transfer resistance.”
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THERMAL MANAGEMENT OF LI-ION CELLS FOR IMPROVED SAFETY AND PERFORMANCE: A REVIEW
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“The authors of [13,29] found that the strength and density of Panasonic 18,650 Li-Bs at 25 ◦C were 800 Wh/L, 100 Wh/L, and 5 Wh/L, which decreased by 98.”
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“Moreover, as has been shown in different experimental studies [2,3], the increase of the charge-transfer resistance in LIBs contributes to the performance degradation at low temperatures.”
BackgroundHigh frequency alternating current heating method for Li-Ion cells based on boost converter topology
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“Operating at extreme temperatures (<10°C or >50°C, a temperature easily achieved when batteries are left out in the sun) reduced not only battery voltages and capacity but also the life of the battery (Bloom et al. 2001; Zhang et al. 2003).”
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“…resistance ( R s ), charge transfer resistance ( R ct ), double layer capacitance ( C dl ), resistance and capacitance of the solid electrolyte inter-phase ( R SEI and C SEI ) and a Warburg impedance ( Z W ) corresponding to diffusion of Na + ions through the electrolyte (Figure 3b) [20,34].”
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“The lithium-ion battery’s performance is influenced by the lithium-ion battery’s charge transfer resistance [8].”
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“[4] argue that poor performance of lithiumion batteries at low temperatures is linked to poor charge transfer at the electrode/electrolyte interface.”
BackgroundSimplification strategy research on hard‐cased Li‐ion battery for thermal modeling
Xifeng, C., Zeng, J. C., Zhang, H., Yang, J., Qiao, J., Li, J., & Li, W. (2020) · International Journal of Energy Research · doi:10.1002/er.5140 · Cited by 10
“The available power and energy of Li-ion batteries decrease heavily at low temperatures.(2) High temperatures cause capacity fading because of the thick but nonuniformity solid electrolyte interface (SEI) layer and electrolyte decomposition.”
BackgroundDual‐purpose thermal management of Li‐ion cells using solid‐state thermoelectric elements
Mostafavi, A., & Jain, A. (2020) · International Journal of Energy Research · doi:10.1002/er.6094 · Cited by 10
Qi, X., Liu, B., Yun, F., Wang, C., Wang, R., Pang, J., Tang, H., Quan, W., Zhang, Q., Yang, M., et al. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta08597b · Cited by 10
Metadata
- Authors
- Zhang, S. S., Xu, K., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Zhang, S.S.
- Venue
- Journal of Power Sources
- Publisher
- Elsevier BV
- Published
- 2003-03
- Volume
- 115
- Issue
- 1
- Pages
- 137-140
- ISSN
- 0378-7753 (ISSN-L)
- OpenAlex
- W2055575936
- Cited by
- 712
- References
- 12
- Citations by year
- 2026: 42 · 2025: 66 · 2024: 79 · 2023: 66 · 2022: 80 · 2021: 67 · 2020: 54 · 2019: 49 · 2018: 32 · 2017: 37 · 2016: 29 · 2015: 24 · 2014: 33 · 2013: 15 · 2012: 12
- FWCI
- 10.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Power Sources (publishedVersion)
- Topics
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, low-temperature performance, charge transfer resistance, electrode polarization, symmetric cells, impedance spectra, graphite anode, cathode
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