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A new approach toward improved low temperature performance of Li-ion battery
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“Zhang et al. [95] found that although a LiBF 4 -based electrolyte has an overall lower ionic conductivity than the electrolyte using LiPF 6 , it delivered higher capacity at -30 °C than the LiPF 6 -based electrolyte, as shown in Fig. 12a.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
In the citing paper
“It can be clearly seen that the interphase impedance, especially the charge transfer resistance of the LiBF 4 -based electrolyte, is lower than that of the LiPF 6 -based electrolyte, showing the origin of the capacity difference.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
Citations
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“In addition, LiBF4 exhibits high ionic conductivity but this decreases at low temperatures (Zhang et al., 2002).”
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“163 In order to conduct an experimental investigation into the thermal properties of battery performance, Zhang et al. 164 prototyped a hybrid (PCM + bottom LC) BTMS.”
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“Therefore, it is speculated that LiBF 4 -based electrolytes have a small charge transfer resistance, which may improve the low-temperature performance of LIBs [15,35].”
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“[91] prepared 1 M LiBF6 and 1 M LiBF4 electrolytes in a glovebox filled with argon gas and dissolved them in 1:1:3 PC/EC/EMC solvent to study the low-temperature performance of batteries with a graphite anode and lithium nickel-based mixed oxide cathode.”
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“In addition, we performed Li deposition at −10 °C, at which Li dendrite growth is typically intensified (52).”
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“LiBF4, having moderate ionic conductivities, is more resistant to hydrolysis and thermal decomposition and exhibits excellent performances at low temperatures [21,23,24].”
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Kuo, T.-J. (2019) · Applied Sciences · doi:10.3390/app9214572 · Cited by 7
Vorfolomeeva, A. A., Zaguzina, A. A., Maximovskiy, E. A., Gusel’nikov, A. V., Plyusnin, P. E., Okotrub, A. V., & Bulusheva, L. G. (2025) · Nanomaterials · doi:10.3390/nano15110824 · Cited by 6
“As a result, the kinetics of charge transfer at the electrode–electrolyte interface are improved [12,14,15].”
Zhang, Y., Liang, L.-X., Sun, J., & Hou, G.-J. (2025) · Energy Storage Materials · doi:10.1016/j.ensm.2025.104812 · Cited by 5
Metadata
- Authors
- Zhang, S. S., Xu, K., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Zhang, S.S
- Venue
- Electrochemistry Communications
- Publisher
- Elsevier BV
- Published
- 2002-11
- Volume
- 4
- Issue
- 11
- Pages
- 928-932
- ISSN
- 1388-2481 (ISSN-L)
- OpenAlex
- W2048302690
- Cited by
- 302
- References
- 0
- Citations by year
- 2026: 9 · 2025: 28 · 2024: 19 · 2023: 30 · 2022: 37 · 2021: 19 · 2020: 25 · 2019: 25 · 2018: 10 · 2017: 19 · 2016: 12 · 2015: 12 · 2014: 7 · 2013: 7 · 2012: 6
- FWCI
- 3.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochemistry Communications (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, low-temperature performance, electrolyte formulation, lithium tetrafluoroborate, LiPF6, ionic conductivity, propylene carbonate, ethylene carbonate, capacity retention, polarization, charge transfer resistance, cell impedance
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