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A new approach toward improved low temperature performance of Li-ion battery
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“Zhang et al. [95] found that although a LiBF 4 -based electrolyte has an overall lower ionic conductivity than the electrolyte using LiPF 6 , it delivered higher capacity at -30 °C than the LiPF 6 -based electrolyte, as shown in Fig. 12a.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
In the citing paper
“It can be clearly seen that the interphase impedance, especially the charge transfer resistance of the LiBF 4 -based electrolyte, is lower than that of the LiPF 6 -based electrolyte, showing the origin of the capacity difference.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [95]
Citations
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“In addition, it is generally regarded that LiBF4 is superior to LiPF6 with respect to factors such as high-temperature performance, reaction characteristics with water and chemical stability [77,78].”
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“The successful improvement of the low temperature performance is mainly based on two approaches: (1) formulating new solvent mixtures to lower freezing temperature of the liquid electrolytes [6, 10, 11] and (2) replacing the existing LiPF6 salt with LiPF6 to reduce charge-transfer resistance of the batteries [ 9 ].”
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Self-citationRapid restoration of electric vehicle battery performance while driving at cold temperatures
Zhang, G.-S., Ge, S., Yang, X.-G., Leng, Y.-J., Marple, D., & Wang, C.-Y. (2017) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.10.029 · Cited by 64
Lin, W., Zhu, M., Fan, Y., Wang, H., Tao, G., Ding, M., Liu, N., Yang, H., Wu, J., Fang, J., et al. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164163 · Cited by 64
Nanostructured strategies towards boosting organic lithium-ion batteries
Liu, Y., Sun, G., Cai, X., Yang, F., Ma, C., Xue, M., & Tao, X. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.05.021 · Cited by 61
Lu, Y., Guo, J.-L., He, Z.-K., Gao, Z.-D., & Song, Y.-Y. (2022) · Energy Storage Materials · doi:10.1016/j.ensm.2022.03.050 · Cited by 59
Microporous gel electrolyte Li-ion battery
Zhang, S.-B., Xu, K., Foster, D., Ervin, M., & Jow, T. (2004) · doi:10.1016/j.jpowsour.2003.07.008 · Cited by 59
Self-citationChen, K., Yu, Z.-Q., Deng, S., Wu, Q., Zou, J., & Zeng, X.-Q. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.12.051 · Cited by 58
Metal-oxidized graphite composite electrodes for lithium-ion batteries
Nobili, F., Dsoke, S., Mecozzi, T., & Marassi, R. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2005.05.012 · Cited by 67
Exploring low temperature Li+ ion conducting plastic battery electrolyte
Das, A., Thakur, A. K., & Kumar, K. (2013) · Ionics (Kiel) · doi:10.1007/s11581-013-0898-x · Cited by 56
“8×10 −3 S cm at −20 °C) [2], LiBOB–PC–EC–EMC (10 S cm at −30 °C) [3], LiPF6–EC–DEC–EP (10 −3 S cm at −30 °C) [4], LiPF6– EC–DMC–EMC (2×10 S cm at −30 °C), LiPF6–EC– DMC (2×10 S cm at −30 °C) [1], LiPF6–EC–PC–EMC (10 S cm at −30 °C) [5], LiBF4–PC–EC–EMC (10 S cm at −30 °C) [5], LiPF6–EC–EMC (0.”
Hosseini, S. M., Soleymani, M., Kelouwani, S., & Amamou, A. (2023) · IEEE Access · doi:10.1109/access.2023.3301329 · Cited by 56
Dubarry, M., Truchot, C., Liaw, B. Y., Gering, K. L., Sazhin, S. V., Jamison, D. K., & Michelbacher, C. J. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.063301jes · Cited by 65
Metadata
- Authors
- Zhang, S. S., Xu, K., & Jow, T. R.
- Affiliations
- DEVCOM Army Research Laboratory (US)
- Corresponding author
- Zhang, S.S
- Venue
- Electrochemistry Communications
- Publisher
- Elsevier BV
- Published
- 2002-11
- Volume
- 4
- Issue
- 11
- Pages
- 928-932
- ISSN
- 1388-2481 (ISSN-L)
- OpenAlex
- W2048302690
- Cited by
- 302
- References
- 0
- Citations by year
- 2026: 9 · 2025: 28 · 2024: 19 · 2023: 30 · 2022: 37 · 2021: 19 · 2020: 25 · 2019: 25 · 2018: 10 · 2017: 19 · 2016: 12 · 2015: 12 · 2014: 7 · 2013: 7 · 2012: 6
- FWCI
- 3.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochemistry Communications (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion batteries, low-temperature performance, electrolyte formulation, lithium tetrafluoroborate, LiPF6, ionic conductivity, propylene carbonate, ethylene carbonate, capacity retention, polarization, charge transfer resistance, cell impedance
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