Cited by 33Heavy metals in environmentAdsorption and biosorption for pollutant removalEnvironmental remediation with nanomaterials

Effect of crop-straw derived biochars on Pb (II) adsorption in two variable charge soils

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JIANG, Tian-yu, XU, Ren-kou, GU, Tian-xia, JIANG, Jun·2014·Journal of Integrative Agriculture

Abstract

Two variable charge soils were incubated with biochars derived from straws of peanut, soybean, canola, and rice to investigate the effect of the biochars on their chemical properties and Pb(II) adsorption using batch experiments. The results showed soil cation exchange capacity (CEC) and pH significantly increased after 30 d of incubation with the biochars added. The incorporation of the biochars markedly increased the adsorption of Pb(II), and both the electrostatic and non-electrostatic adsorption mechanisms contributed to Pb(II) adsorption by the variable charge soils. Adsorption isotherms illustrated legume-straw derived biochars more greatly increased Pb(II) adsorption on soils through the non-electrostatic mechanism via the formation of surface complexes between Pb(II) and acid functional groups of the biochars than did non-legume straw biochars. The adsorption capacity of Pb(II) increased, while the desorption amount slightly decreased with the increasing suspension pH for the studied soils, especially in a high suspension pH, indicating that precipitation also plays an important role in immobilizing Pb(II) to the soils.

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Research works printed but not linked: 3

  1. ASTM D 1762-84. 1990. Standard Method for Chemical Analysis of Wood Charcoal. ASTM International, Philadelphia. pp. 1-2.
  2. JIANG Tian-yu et al. © 2014, CAAS. All rights reserved. Published by Elsevier Ltd. of Environmental Quality, 41, 1138-1149.
  3. Yu T R. 1997. Chemistry of Variable Charge Soil. Oxford University Press, New York. pp. 8-15.

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Authors
JIANG, T.-Y., XU, R.-K., GU, T.-X., & JIANG, J.
Affiliations
  • Nanjing Agricultural University (CN)
  • Chinese Academy of Sciences (CN)
  • Nanjing Foreign Language School (CN)
Corresponding author
JIANG, Jun
Venue
Journal of Integrative Agriculture
Publisher
Elsevier BV
Published
2014-03
Volume
13
Issue
3
Pages
507-516
ISSN
2095-3119 (ISSN-L)
OpenAlex
W1988912838
Cited by
33
References
30
Citations by year
2024: 4 · 2023: 4 · 2022: 2 · 2021: 6 · 2020: 2 · 2019: 3 · 2018: 3 · 2017: 2 · 2016: 1 · 2015: 5 · 2014: 1
FWCI
2.12
Type
journal article
Language
en
Open access
Locations
  • Journal of Integrative Agriculture (publishedVersion, cc-by-nc-nd)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Funders
  • Natural Science Foundation of Shanghai
  • National Natural Science Foundation of China (41230855)
Topics
  • Physical Sciences › Environmental Science › Pollution › Heavy metals in environment
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
Keywords
biochar, crop straw, lead adsorption, variable charge soils, cation exchange capacity, soil pH, electrostatic adsorption, surface complexation, adsorption isotherms, lead desorption, lead precipitation, peanut straw, soybean straw, canola straw, rice straw, heavy metal immobilization

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