The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
A Predictive Model for Matrix and Analyte Effects in Electrospray Ionization of Singly-Charged Ionic Analytes
Abstract
In electrospray ionization (ESI), droplets with a surface excess charge are created. The rate of production of surface excess charge is a constant and is equal to the rate of ion production. The ions appearing in the mass spectrum are postulated to be those that formed the surface excess charge at the time of droplet formation (or their collision products). An equilibrium model based on competition among the ions in the solution for the limited number of excess charge sites has been developed. This model accurately predicts the response curves of singly-charged ionic analytes as a function of the concentration of electrolyte and other analytes and provides an explanation for the selective effectiveness of ESI. At low concentrations of total analyte (micromolar and less), the response curves are linear, indifferent to the presence of other low concentration analytes, and suppressed by electrolyte concentrations in excess of the minimum required. At higher analyte concentrations, the response becomes independent of analyte concentration but highly affected by the presence of other analytes.
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Cites
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Electrospray interface for liquid chromatographs and mass spectrometers
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On the evaporation of small ions from charged droplets
Iribarne, J. V., & Thomson, B. A. (1976) · The Journal of Chemical Physics · doi:10.1063/1.432536 · Cited by 1,281
Charge and fission of droplets in electrostatic sprays
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Field induced ion evaporation from liquid surfaces at atmospheric pressure
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[21] Electrospray ionization mass spectrometry
Fred Banks, J., & Whitehouse, C. M. (1996) · Methods in Enzymology · doi:10.1016/s0076-6879(96)70023-x · Cited by 522
Weighing Naked Proteins: Practical, High-Accuracy Mass Measurement of Peptides and Proteins
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Some Developments in Nuclear Magnetic Resonance of Solids
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Electrospray mass spectrometry applied to inorganic and organometallic chemistry
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Cited by
Practical implications of some recent studies in electrospray ionization fundamentals
Cech, N. B., & Enke, C. G. (2001) · Mass Spectrometry Reviews · doi:10.1002/mas.10008 · Cited by 1,435
Self-citationElectrospray: From ions in solution to ions in the gas phase, what we know now
Kebarle, P., & Verkerk, U. H. (2009) · Mass Spectrometry Reviews · doi:10.1002/mas.20247 · Cited by 905
A brief overview of the present status of the mechanisms involved in electrospray mass spectrometry
Kebarle, P. (2000) · Journal of Mass Spectrometry · doi:10.1002/1096-9888(200007)35:7<804::aid-jms22>3.0.co;2-q · Cited by 675
Metadata
- Authors
- Enke, C. G.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-12-01
- Volume
- 69
- Issue
- 23
- Pages
- 4885-4893
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W2049044923
- Cited by
- 419
- References
- 16
- FWCI
- 4.70
- Type
- journal article
- Language
- en
- Open access
- closed
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- Enke, C. G. (1997). A Predictive Model for Matrix and Analyte Effects in Electrospray Ionization of Singly-Charged Ionic Analytes. Analytical Chemistry. https://doi.org/10.1021/ac970095w
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
