The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Ion-Exchange and Cation Solvation Reactions in Ti3C2 MXene
Open accessAbstract
Ti 3 C 2 and other two-dimensional transition metal carbides known as MXenes are currently being explored for many applications involving intercalated ions, from electrochemical energy storage, to contaminant sorption from water, to selected ion sieving. We report here a systematic investigation of ion exchange in Ti 3 C 2 MXene and its hydration/dehydration behavior. We have investigated the effects of the presence of LiCl during the chemical etching of the MAX phase Ti 3 AlC 2 into MXene Ti 3 C 2 T x (T stands for surface termination) and found that the resulting MXene has Li + cations in the interlayer space. We successfully exchanged the Li + cations with K +, Na +, Rb +, Mg 2+, and Ca 2+ (supported by X-ray photoelectron and energy-dispersive spectroscopy) and found that the exchanged material expands on the unit-cell level in response to changes in humidity, with the nature of expansion dependent on the intercalated cation, similar to behavior of clay minerals; stepwise expansions of the basal spacing were observed, with changes consistent with the size of the H 2 O molecule. Thermogravimetric analysis of the dehydration behavior of these materials shows that the amounts of H 2 O contained at ambient humidity correlates simply with the hydration enthalpy of the intercalated cation, and that the diffusion of the exiting H 2 O proceeds with kinetics similar to clays. These results have implications for understanding, controlling, and exploiting structural changes and H 2 O sorption in MXene films and powders utilized in applications involving ions, such as electrochemical capacitors, sensors, reverse osmosis membranes, or contaminant sorbents.
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Cites
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011) · Advanced Materials · doi:10.1002/adma.201102306 · Cited by 11,855
Self-citation25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials
Naguib, M., Mochalin, V. N., Barsoum, M. W., & Gogotsi, Y. (2014) · Advanced Materials · doi:10.1002/adma.201304138 · Cited by 6,414
Self-citationConductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y., & Barsoum, M. W. (2014) · Nature · doi:10.1038/nature13970 · Cited by 5,997
Self-citationTwo-Dimensional Transition Metal Carbides
Naguib, M., Mashtalir, O., Carle, J., Presser, V., Lu, J., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2012) · ACS Nano · doi:10.1021/nn204153h · Cited by 4,769
Self-citationCation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
Lukatskaya, M. R., Mashtalir, O., Ren, C. E., Dall’Agnese, Y., Rozier, P., Taberna, P. L., Naguib, M., Simon, P., Barsoum, M. W., & Gogotsi, Y. (2013) · Science · doi:10.1126/science.1241488 · Cited by 4,320
Self-citationPractical surface analysis: By auger and x-ray photoelectron spectroscopy
Briggs, D., & Seah, M. P. (1983) · Medical Entomology and Zoology · Cited by 4,292
Intercalation and delamination of layered carbides and carbonitrides
Mashtalir, O., Naguib, M., Mochalin, V. N., Dall’Agnese, Y., Heon, M., Barsoum, M. W., & Gogotsi, Y. (2013) · Nature Communications · doi:10.1038/ncomms2664 · Cited by 2,852
Self-citationPractical surface analysis by auger and X-ray photoelectron spectroscopy
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X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)
Halim, J., Cook, K. M., Naguib, M., Eklund, P., Gogotsi, Y., Rosen, J., & Barsoum, M. W. (2016) · Applied Surface Science · doi:10.1016/j.apsusc.2015.11.089 · Cited by 2,047
Self-citationTransparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
Halim, J., Lukatskaya, M. R., Cook, K. M., Lu, J., Smith, C. R., Näslund, L.-Å., May, S. J., Hultman, L., Gogotsi, Y., Eklund, P., et al. (2014) · Chemistry of Materials · doi:10.1021/cm500641a · Cited by 1,698
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Cited by
Fluorine‐Free Synthesis of High‐Purity Ti3C2Tx (T=OH, O) via Alkali Treatment
Li, T., Yao, L., Liu, Q., Gu, J., Luo, R., Li, J., Yan, X., Wang, W., Liu, P., Chen, B., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201800887 · Cited by 1,457
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Self-citationEffective ion sieving with Ti3C2Tx MXene membranes for production of drinking water from seawater
Ding, L., Li, L., Liu, Y., Wu, Y., Lu, Z., Deng, J., Wei, Y., Caro, J., & Wang, H. (2020) · Nature Sustainability · doi:10.1038/s41893-020-0474-0 · Cited by 804
Ma, Y., Liu, N., Li, L., Hu, X., Zou, Z., Wang, J., Luo, S., & Gao, Y. (2017) · Nature Communications · doi:10.1038/s41467-017-01136-9 · Cited by 788
Liu, L., Chen, W., Zhang, H., Wang, Q., Guan, F., & Yu, Z. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201905197 · Cited by 699
Metadata
- Authors
- Ghidiu, M., Halim, J., Kota, S., Bish, D., Gogotsi, Y., & Barsoum, M. W.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-05-10
- Volume
- 28
- Issue
- 10
- Pages
- 3507-3514
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2342701378
- Cited by
- 733
- References
- 29
- FWCI
- 21.10
- Type
- journal article
- Language
- en
- Open access
- green
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