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Robust, Fire-Safe, Monomer-Recovery, Highly Malleable Thermosets from Renewable Bioresources
Abstract
Conventional thermosets are built by nonrenewable fossil resources and are arduous to be reprocessed, recycled, and reshaped due to their permanent covalent cross-linking, and their flammability makes them unsafe during use. Here, for the first time, we synthesized a novel Schiff base precursor from abundant and renewable lignin derivative vanillin and produced malleable thermosets (Schiff base covalent adaptable networks (CANs)) combining high performance, super-rapid reprocessability, excellent monomer recovery, and arbitrary permanent shape changeability as well as outstanding fire resistance. The Schiff base CANs exhibited high glass transition temperatures of ∼178 °C, tensile strength of ∼69 MPa, tensile modulus of ∼1925 MPa, excellent flame retardancy with UL-94 V0 rating and V1 rating, and high LOI of ∼30%. Meanwhile, three Schiff base CANs showed high malleability with the activation energy of the bond exchange of 49–81 kJ mol –1 and could be reprocessed in 2–10 min at 180 °C. These Schiff base CANs provide a prime example to foster the development of advanced thermosetting materials from renewable bioresources.
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Self-citation
Metadata
- Authors
- Wang, S., Ma, S., Li, Q., Yuan, W., Wang, B., & Zhu, J.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-10-03
- Volume
- 51
- Issue
- 20
- Pages
- 8001-8012
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2895432777
- Cited by
- 386
- References
- 50
- FWCI
- 13.01
- Type
- journal article
- Language
- en
- Open access
- closed
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