The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Recyclable and Malleable Epoxy Thermoset Bearing Aromatic Imine Bonds
Abstract
A method for preparing reprocessable epoxy thermoset is presented. The process is composed of synthesis of a bisphenol monomer bridged by an imine bond, glycidylation of the bisphenol, and cross-linking with a hardener to form thermoset. The resulting epoxy thermoset possesses comparable properties to conventional high-performance thermosets made from bisphenol A. However, when treated by a stimulus like acid, temperature, and/or water, the described thermoset exhibits reprocessability. Degradation and recycling involve hydrolysis and re-formation of imine bonds; reshaping and repairing of the thermoset are realized through imine exchange reactions. All the described processes require no metal catalyst, press heating, or additional monomer, which significantly widens thermoset reprocessing.
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Cites
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Biobased Thermosetting Epoxy: Present and Future
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Cited by
Bio-based polymers with performance-advantaged properties
Cywar, R. M., Rorrer, N. A., Hoyt, C. B., Beckham, G. T., & Chen, E. Y.-X. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00363-3 · Cited by 811
Vitrimers: Permanently crosslinked polymers with dynamic network topology
Van Zee, N. J., & Nicolaÿ, R. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101233 · Cited by 734
Biobased vitrimers: Towards sustainable and adaptable performing polymer materials
Lucherelli, M. A., Duval, A., & Avérous, L. (2022) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2022.101515 · Cited by 291
Metadata
- Authors
- Zhao, S., & Abu-Omar, M. M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-11-27
- Volume
- 51
- Issue
- 23
- Pages
- 9816-9824
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2902863502
- Cited by
- 435
- References
- 52
- FWCI
- 10.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, S., & Abu-Omar, M. M. (2018). Recyclable and Malleable Epoxy Thermoset Bearing Aromatic Imine Bonds. Macromolecules. https://doi.org/10.1021/acs.macromol.8b01976
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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