The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Enhanced Electrocatalytic Reduction of CO2 via Chemical Coupling between Indium Oxide and Reduced Graphene Oxide
Abstract
The chemical coupling interaction has been explored extensively to boost heterogeneous catalysis, but the insight into how chemical coupling interaction works on CO 2 electroreduction remains unclear. Herein we demonstrate how the chemical coupling interaction between porous In 2 O 3 nanobelts and reduced graphene oxide (rGO) could substantially improve the electrocatalytic activity toward CO 2 electroreduction. Such an In 2 O 3 –rGO hybrid catalyst showed 1.4-fold and 3.6-fold enhancements in Faradaic efficiency and specific current density for the formation of formate at −1.2 V versus reversible hydrogen electrode relative to the catalyst prepared by physically loading of In 2 O 3 nanobelts onto rGO, respectively. The density functional theory calculations and electrochemical analysis together revealed that the chemical coupling interaction boosted CO 2 electroreduction activity by improving electrical conductivity and stabilizing key intermediate HCOO –* . The present work not only deepens an understanding of chemical coupling effect but also provides an effective lever to optimize the catalytic performance toward CO 2 electroreduction.
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Cites
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Huang, H., Li, K., Chen, Z., Luo, L., Gu, Y., Zhang, D., Ma, C., Si, R., Yang, J., Peng, Z., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01036 · Cited by 312
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Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy
Timoshenko, J., & Roldan Cuenya, B. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00396 · Cited by 931
Lai, W., Qiao, Y., Zhang, J., Lin, Z., & Huang, H. (2022) · Energy & Environmental Science · doi:10.1039/d2ee00472k · Cited by 373
Self-citationJiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
Metadata
- Authors
- Zhang, Z., Ahmad, F., Zhao, W., Yan, W., Zhang, W., Huang, H., Ma, C., & Zeng, J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-28
- Volume
- 19
- Issue
- 6
- Pages
- 4029-4034
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2947463343
- Cited by
- 177
- References
- 4
- FWCI
- 6.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, Z., Ahmad, F., Zhao, W., Yan, W., Zhang, W., Huang, H., Ma, C., & Zeng, J. (2019). Enhanced Electrocatalytic Reduction of CO2 via Chemical Coupling between Indium Oxide and Reduced Graphene Oxide. Nano Letters. https://doi.org/10.1021/acs.nanolett.9b01393
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