The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Self-Healable, Tough, and Ultrastretchable Nanocomposite Hydrogels Based on Reversible Polyacrylamide/Montmorillonite Adsorption
Abstract
Nanocomposite hydrogels with unprecedented stretchability, toughness, and self-healing have been developed by in situ polymerization of acrylamide with the presence of exfoliated montmorillonite (MMT) layers as noncovalent cross-linkers. The exfoliated MMT clay nanoplatelets with high aspect ratios, as confirmed by transmission electron microscopy (TEM) and X-ray diffraction (XRD) results, are well dispersed in the polyacrylamide matrix. Strong polymer/MMT interaction was confirmed by Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The effective cross-link densities of these hydrogels are estimated in the range of 2.2-5.7 mol m(-3). Uniaxial tensile tests showed a very high fracture elongation up to 11 800% and a fracture toughness up to 10.1 MJ m(-3). Cyclic loading-unloading tests showed remarkable hysteresis, which indicates energy dissipation upon deformation. Residual strain after cyclic loadings could be recovered under mild conditions, with the recovery extent depending on clay content. A mechanism based on reversible desorption/adsorption of polymer chains on clay platelets surface is discussed. Finally, these nanocomposite hydrogels are demonstrated to fully heal by dry-reswell treatments.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Highly stretchable and tough hydrogels
Sun, J.-Y., Zhao, X., Illeperuma, W. R. K., Chaudhuri, O., Oh, K. H., Mooney, D. J., Vlassak, J. J., & Suo, Z. (2012) · Nature · doi:10.1038/nature11409 · Cited by 5,481
Introduction to Physical Polymer Science
Sperling, L. H. (2005) · doi:10.1002/0471757128 · Cited by 2,917
Methods of Soil Analysis: Part 1 Physical and Mineralogical Methods
(1986) · SSSA Book Series · doi:10.2136/sssabookser5.1.2ed · Cited by 2,440
Why are double network hydrogels so tough?
Gong, J. P. (2010) · Soft Matter · doi:10.1039/b924290b · Cited by 2,328
Haraguchi, K., & Takehisa, T. (2002) · Advanced Materials · doi:10.1002/1521-4095(20020816)14:16<1120::aid-adma1120>3.0.co;2-9 · Cited by 2,108
Ultrastrong and Stiff Layered Polymer Nanocomposites
Podsiadlo, P., Kaushik, A. K., Arruda, E. M., Waas, A. M., Shim, B. S., Xu, J., Nandivada, H., Pumplin, B. G., Lahann, J., Ramamoorthy, A., et al. (2007) · Science · doi:10.1126/science.1143176 · Cited by 1,630
Redox-responsive self-healing materials formed from host–guest polymers
Nakahata, M., Takashima, Y., Yamaguchi, H., & Harada, A. (2011) · Nature Communications · doi:10.1038/ncomms1521 · Cited by 1,389
Multi-scale multi-mechanism design of tough hydrogels: building dissipation into stretchy networks
Zhao, X. (2014) · Soft Matter · doi:10.1039/c3sm52272e · Cited by 1,252
Nanoparticle solutions as adhesives for gels and biological tissues
Rose, S., Prevoteau, A., Elzière, P., Hourdet, D., Marcellan, A., & Leibler, L. (2014) · Nature · doi:10.1038/nature12806 · Cited by 806
Self‐Healing Supramolecular Gels Formed by Crown Ether Based Host–Guest Interactions
Zhang, M., Xu, D., Yan, X., Chen, J., Dong, S., Zheng, B., & Huang, F. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203063 · Cited by 728
Phadke, A., Zhang, C., Arman, B., Hsu, C.-C., Mashelkar, R. A., Lele, A. K., Tauber, M. J., Arya, G., & Varghese, S. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201122109 · Cited by 726
Large Strain Hysteresis and Mullins Effect of Tough Double-Network Hydrogels
Webber, R. E., Creton, C., Brown, H. R., & Gong, J. P. (2007) · Macromolecules · doi:10.1021/ma062924y · Cited by 702
“Nonswellable” Hydrogel Without Mechanical Hysteresis
Kamata, H., Akagi, Y., Kayasuga-Kariya, Y., Chung, U.-I., & Sakai, T. (2014) · Science · doi:10.1126/science.1247811 · Cited by 669
Kakuta, T., Takashima, Y., Nakahata, M., Otsubo, M., Yamaguchi, H., & Harada, A. (2013) · Advanced Materials · doi:10.1002/adma.201205321 · Cited by 621
Kulshrestha, P., Giese, & Aga, D. S. (2004) · Environmental Science & Technology · doi:10.1021/es034856q · Cited by 527
Poly(vinyl alcohol) Hydrogel Can Autonomously Self-Heal
Zhang, H., Xia, H., & Zhao, Y. (2012) · ACS Macro Letters · doi:10.1021/mz300451r · Cited by 509
Tough and highly stretchable graphene oxide/polyacrylamide nanocomposite hydrogels
Liu, R., Liang, S., Tang, X.-Z., Yan, D., Li, X., & Yu, Z.-Z. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm32541a · Cited by 500
Haraguchi, K., Farnworth, R., Ohbayashi, A., & Takehisa, T. (2003) · Macromolecules · doi:10.1021/ma034366i · Cited by 488
Mechanical Properties and Structure of Polymer−Clay Nanocomposite Gels with High Clay Content
Haraguchi, K., & Li, H. (2006) · Macromolecules · doi:10.1021/ma052468y · Cited by 411
Zhang, Y., Li, Y., & Liu, W. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201401989 · Cited by 355
Wang, L., Zhang, J., & Wang, A. (2008) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2008.02.019 · Cited by 347
Multivalent H-bonds for self-healing hydrogels
Cui, J., & Campo, A. D. (2012) · Chemical Communications · doi:10.1039/c2cc34701f · Cited by 344
Yao, H., Tan, Z., Fang, H., & Yu, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004748 · Cited by 326
Heinz, H., Koerner, H., Anderson, K. L., Vaia, R. A., & Farmer, B. L. (2005) · Chemistry of Materials · doi:10.1021/cm0509328 · Cited by 325
Self‐healing in Nanocomposite Hydrogels
Haraguchi, K., Uyama, K., & Tanimoto, H. (2011) · Macromolecular Rapid Communications · doi:10.1002/marc.201100248 · Cited by 321
Polyacrylamide−Clay Nanocomposite Hydrogels: Rheological and Light Scattering Characterization
Okay, O., & Oppermann, W. (2007) · Macromolecules · doi:10.1021/ma062929v · Cited by 316
Hu, Z., & Chen, G. (2014) · Advanced Materials · doi:10.1002/adma.201400179 · Cited by 314
Necking Phenomenon of Double-Network Gels
Na, Y.-H., Tanaka, Y., Kawauchi, Y., Furukawa, H., Sumiyoshi, T., Gong, J. P., & Osada, Y. (2006) · Macromolecules · doi:10.1021/ma060568d · Cited by 281
Characterization of internal fracture process of double network hydrogels under uniaxial elongation
Nakajima, T., Kurokawa, T., Ahmed, S., Wu, W.-L., & Gong, J. P. (2013) · Soft Matter · doi:10.1039/c2sm27232f · Cited by 259
Haraguchi, K. (2011) · Polymer Journal · doi:10.1038/pj.2010.141 · Cited by 245
Interaction and Properties of Highly Exfoliated Soy Protein/Montmorillonite Nanocomposites
Chen, P., & Zhang, L. (2006) · Biomacromolecules · doi:10.1021/bm050924k · Cited by 244
Structure optimization of self-healing hydrogels formed via hydrophobic interactions
Tuncaboylu, D. C., Argun, A., Sahin, M., Sari, M., & Okay, O. (2012) · Polymer · doi:10.1016/j.polymer.2012.10.015 · Cited by 201
Liu, D., Yuan, P., Liu, H., Cai, J., Tan, D., He, H., Zhu, J., & Chen, T. (2013) · Applied Clay Science · doi:10.1016/j.clay.2013.07.006 · Cited by 197
Facile Fabrication of Tough Hydrogels Physically Cross-Linked by Strong Cooperative Hydrogen Bonding
Song, G., Zhang, L., He, C., Fang, D.-C., Whitten, P. G., & Wang, H. (2013) · Macromolecules · doi:10.1021/ma401053c · Cited by 194
Self‐Healing in Tough Graphene Oxide Composite Hydrogels
Liu, J., Song, G., He, C., & Wang, H. (2013) · Macromolecular Rapid Communications · doi:10.1002/marc.201300242 · Cited by 192
Haraguchi, K., Ebato, M., & Takehisa, T. (2006) · Advanced Materials · doi:10.1002/adma.200600143 · Cited by 186
A Novel Highly Resilient Nanocomposite Hydrogel with Low Hysteresis and Ultrahigh Elongation
Zhu, M., Liu, Y., Sun, B., Zhang, W., Liu, X., Yu, H., Zhang, Y., Kuckling, D., & Adler, H. P. (2006) · Macromolecular Rapid Communications · doi:10.1002/marc.200600159 · Cited by 174
Time Dependence of Dissipative and Recovery Processes in Nanohybrid Hydrogels
Rose, S., Dizeux, A., Narita, T., Hourdet, D., & Marcellan, A. (2013) · Macromolecules · doi:10.1021/ma400447j · Cited by 139
Xiong, L., Hu, X., Liu, X., & Tong, Z. (2008) · Polymer · doi:10.1016/j.polymer.2008.09.021 · Cited by 126
Adsorption and binding of amino acids on homoionic montmorillonite and kaolinite
Dashman, T., & Stotzky, G. (1982) · Soil Biology and Biochemistry · doi:10.1016/0038-0717(82)90103-1 · Cited by 99
Thin, Tough, pH-Sensitive Hydrogel Films with Rapid Load Recovery
Naficy, S., Spinks, G. M., & Wallace, G. G. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am405708v · Cited by 97
Self-healing hydrogels formed in catanionic surfactant solutions
Akay, G., Raeisi, A. H., Tuncaboylu, D. C., Orakdöğen, N., Abdurrahmanoğlu, S., Oppermann, W., & Okay, O. (2013) · Soft Matter · doi:10.1039/c2sm27515e · Cited by 90
Yang, J. H., Deng, L., Han, C., Duan, J., Ma, M., Zhang, X., Xu, F., & Sun, R. (2012) · Soft Matter · doi:10.1039/c2sm27233d · Cited by 76
Fiorito, T. M., Icoz, I., & Stotzky, G. (2007) · Applied Clay Science · doi:10.1016/j.clay.2007.07.006 · Cited by 59
Guilherme, M. R., Fajardo, A. R., Moia, T. A., et al. (2010) · European Polymer Journal · doi:10.1016/j.eurpolymj.2010.04.008 · Cited by 46
Haraguchi, K., Li, H., Ren, H.-Y., & Zhu, M. (2010) · Macromolecules · doi:10.1021/ma102118b · Cited by 44
Novel Developed Systems and Techniques Based on Double-Network Principle
Wu, Z. L., Kurokawa, T., & Gong, J. P. (2011) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20110201 · Cited by 34
Khanlari, A., Detamore, M. S., & Gehrke, S. H. (2013) · Macromolecules · doi:10.1021/ma401838h · Cited by 30
Cited by
Soft Materials by Design: Unconventional Polymer Networks Give Extreme Properties
Zhao, X., Chen, X., Yuk, H., Lin, S., Liu, X., & Parada, G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01088 · Cited by 1,161
Stretchable and tough conductive hydrogels for flexible pressure and strain sensors
Wang, Z., Cong, Y., & Fu, J. (2020) · Journal of Materials Chemistry B · doi:10.1039/c9tb02570g · Cited by 607
Self-citation3D Printing of Highly Stretchable, Shape-Memory, and Self-Healing Elastomer toward Novel 4D Printing
Kuang, X., Chen, K., Dunn, C. K., Wu, J., Li, V. C. F., & Qi, H. J. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b18265 · Cited by 523
Zhang, K., Feng, Q., Fang, Z., Gu, L., & Bian, L. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00071 · Cited by 394
Qin, Z., Sun, X., Yu, Q., Zhang, H., Wu, X., Yao, M., Liu, W., Yao, F., & Li, J. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b21659 · Cited by 384
Metadata
- Authors
- Gao, G., Du, G., Sun, Y., & Fu, J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-18
- Volume
- 7
- Issue
- 8
- Pages
- 5029-5037
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2329807175
- Cited by
- 331
- References
- 48
- FWCI
- 13.02
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
