The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Effect of Selective Contacts on the Thermal Stability of Perovskite Solar Cells
Open accessAbstract
Thermal stability of CH 3 NH 3 PbI 3 (MAPbI 3 )-based perovskite solar cells was investigated for normal structure including the mesoporous TiO 2 layer and spiro-MeOTAD and the inverted structure with PCBM and NiO. MAPbI 3 was found to be intrinsically stable from 85 °C to 120 °C in the absence of moisture. However, fast degradation was observed for the encapsulated device including spiro-MeOTAD upon thermal stress at 85 °C. Photoluminescence (PL) intensity and the time constant for charge separation increased with thermal exposure time, which is indicative of inhibition of charge separation from MAPbI 3 into spiro-MeOTAD. A full recovery of photovoltaic performance was observed for the 85 °C-aged device after renewal with fresh spiro-MeOTAD, which clearly indicates that thermal instability of the normal structured device is mainly due to spiro-MeOTAD, and MAPbI 3 is proved to be thermally stable. Spiro-MeOTAD with additives was crystallized at 85 °C due to a low glass transition temperature, and hole mobility was significantly deteriorated, which was responsible for the thermal instability. Thermal stability was significantly improved for the inverted structure with the NiO hole transporting layer, where the power conversion efficiency (PCE) was maintained at 74% of its initial PCE of 14.71% after the 80th thermal cycle (one cycle: heating at 85 °C for 2 h and cooling at 25 °C for 2 h). This work implies that the thermal stability of perovskite solar cells depends on selective contacts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Kojima, A., Teshima, K., Shirai, Y., & Miyasaka, T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809598r · Cited by 23,090
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Self-citationSolvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
Yang, W. S., Noh, J. H., Jeon, N. J., Kim, Y. C., Ryu, S., Seo, J., & Seok, S. I. (2015) · Science · doi:10.1126/science.aaa9272 · Cited by 6,251
Self-citationEperon, G. E., Stranks, S. D., Menelaou, C., Johnston, M. B., Herz, L. M., & Snaith, H. J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43822h · Cited by 4,140
Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance
Saliba, M., Matsui, T., Domanski, K., Seo, J.-Y., Ummadisingu, A., Zakeeruddin, S. M., Correa-Baena, J.-P., Tress, W. R., Abate, A., Hagfeldt, A., et al. (2016) · Science · doi:10.1126/science.aah5557 · Cited by 3,706
Self-citation6.5% efficient perovskite quantum-dot-sensitized solar cell
Im, J.-H., Lee, C.-R., Lee, J.-W., Park, S.-W., & Park, N.-G. (2011) · Nanoscale · doi:10.1039/c1nr10867k · Cited by 3,173
Self-citationAhn, N., Son, D.-Y., Jang, I.-H., Kang, S. M., Choi, M., & Park, N.-G. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04930 · Cited by 2,312
Self-citationIntrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite
Conings, B., Drijkoningen, J., Gauquelin, N., Babayigit, A., D'Haen, J., D'Olieslaeger, L., Ethirajan, A., Verbeeck, J., Manca, J., Mosconi, E., et al. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500477 · Cited by 2,234
Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers
You, J., Meng, L., Song, T.-B., Guo, T.-F., Yang, Y. (., Chang, W.-H., Hong, Z., Chen, H., Zhou, H., Chen, Q., et al. (2016) · Nature Nanotechnology · doi:10.1038/nnano.2015.230 · Cited by 2,123
Leijtens, T., Eperon, G. E., Pathak, S., Abate, A., Lee, M. M., & Snaith, H. J. (2013) · Nature Communications · doi:10.1038/ncomms3885 · Cited by 1,867
Photovoltaic Degradation Rates—an Analytical Review
Jordan, D. C., & Kurtz, S. R. (2013) · Progress in Photovoltaics: Research and Applications · doi:10.1002/pip.1182 · Cited by 1,529
Perovskite solar cells employing organic charge-transport layers
Malinkiewicz, O., Yella, A., Lee, Y. H., Espallargas, G. M., Graetzel, M., Nazeeruddin, M. K., & Bolink, H. J. (2014) · Nature Photonics · doi:10.1038/nphoton.2013.341 · Cited by 1,474
Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility
You, J., Hong, Z., Yang, Y. (., Chen, Q., Cai, M., Song, T.-B., Chen, C.-C., Lu, S., Liu, Y., Zhou, H., et al. (2014) · ACS Nano · doi:10.1021/nn406020d · Cited by 1,448
Habisreutinger, S. N., Leijtens, T., Eperon, G. E., Stranks, S. D., Nicholas, R. J., & Snaith, H. J. (2014) · Nano Letters · doi:10.1021/nl501982b · Cited by 1,210
Towards stable and commercially available perovskite solar cells
Park, N.-G., Grätzel, M., Miyasaka, T., Zhu, K., & Emery, K. (2016) · Nature Energy · doi:10.1038/nenergy.2016.152 · Cited by 1,182
Self-citationHan, Y., Meyer, S., Dkhissi, Y., Weber, K., Pringle, J. M., Bach, U., Spiccia, L., & Cheng, Y.-B. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta00358j · Cited by 1,002
Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers
Bella, F., Griffini, G., Correa-Baena, J.-P., Saracco, G., Grätzel, M., Hagfeldt, A., Turri, S., & Gerbaldi, C. (2016) · Science · doi:10.1126/science.aah4046 · Cited by 870
A dopant-free hole-transporting material for efficient and stable perovskite solar cells
Liu, J., Wu, Y., Qin, C., Yang, X., Yasuda, T., Islam, A., Zhang, K., Peng, W., Chen, W., & Han, L. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01589d · Cited by 719
Origin of the Thermal Instability in CH3NH3PbI3 Thin Films Deposited on ZnO
Yang, J., Siempelkamp, B. D., Mosconi, E., De Angelis, F., & Kelly, T. L. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01598 · Cited by 629
Zhang, H., Cheng, J., Lin, F., He, H., Mao, J., Wong, K. S., Jen, A. K.-Y., & Choy, W. C. H. (2016) · ACS Nano · doi:10.1021/acsnano.5b07043 · Cited by 560
Misra, R. K., Aharon, S., Li, B., Mogilyansky, D., Visoly-Fisher, I., Etgar, L., & Katz, E. A. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/jz502642b · Cited by 552
Solution‐Processed Nickel Oxide Hole Transport Layers in High Efficiency Polymer Photovoltaic Cells
Manders, J. R., Tsang, S., Hartel, M. J., Lai, T., Chen, S., Amb, C. M., Reynolds, J. R., & So, F. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202269 · Cited by 541
Philippe, B., Park, B.-W., Lindblad, R., Oscarsson, J., Ahmadi, S., Johansson, E. M. J., & Rensmo, H. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00348 · Cited by 462
p-type Mesoscopic Nickel Oxide/Organometallic Perovskite Heterojunction Solar Cells
Wang, K.-C., Jeng, J.-Y., Shen, P.-S., Chang, Y.-C., Diau, E. W.-G., Tsai, C.-H., Chao, T.-Y., Hsu, H.-C., Lin, P.-Y., Chen, P., et al. (2014) · Scientific Reports · doi:10.1038/srep04756 · Cited by 444
Li, X., Tschumi, M., Han, H., Babkair, S. S., Alzubaydi, R. A., Ansari, A. A., Habib, S. S., Nazeeruddin, M. K., Zakeeruddin, S. M., & Grätzel, M. (2015) · Energy Technology · doi:10.1002/ente.201500045 · Cited by 379
Malinauskas, T., Tomkute-Luksiene, D., Sens, R., Daskeviciene, M., Send, R., Wonneberger, H., Jankauskas, V., Bruder, I., & Getautis, V. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am5090385 · Cited by 368
Phase Diagram of P3HT/PCBM Blends and Its Implication for the Stability of Morphology
Zhao, J., Swinnen, A., Van Assche, G., Manca, J., Vanderzande, D., & Mele, B. V. (2009) · The Journal of Physical Chemistry B · doi:10.1021/jp804151a · Cited by 350
Stability Issues on Perovskite Solar Cells
Zhao, X., & Park, N.-G. (2015) · Photonics · doi:10.3390/photonics2041139 · Cited by 262
Self-citation
Cited by
Jeon, N. J., Na, H., Jung, E. H., Yang, T.-Y., Lee, Y. G., Kim, G., Shin, H.-W., Il Seok, S., Lee, J., & Seo, J. (2018) · Nature Energy · doi:10.1038/s41560-018-0200-6 · Cited by 2,089
Self-citationLessons learned from spiro-OMeTAD and PTAA in perovskite solar cells
Rombach, F. M., Haque, S. A., & Macdonald, T. J. (2021) · Energy & Environmental Science · doi:10.1039/d1ee02095a · Cited by 730
Chen, J., Zhao, X., Kim, S., & Park, N. (2019) · Advanced Materials · doi:10.1002/adma.201902902 · Cited by 527
Self-citationImpact of H2O on organic–inorganic hybrid perovskite solar cells
Huang, J., Tan, S., Lund, P. D., & Zhou, H. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01674c · Cited by 489
The Role of the Interfaces in Perovskite Solar Cells
Shao, S., & Loi, M. A. (2020) · Advanced Materials Interfaces · doi:10.1002/admi.201901469 · Cited by 477
Metadata
- Authors
- Zhao, X., Kim, H.-S., Seo, J.-Y., & Park, N.-G.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-20
- Volume
- 9
- Issue
- 8
- Pages
- 7148-7153
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2586249383
- Cited by
- 265
- References
- 29
- FWCI
- 12.98
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
