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Porous NiFe-Oxide Nanocubes as Bifunctional Electrocatalysts for Efficient Water-Splitting

Kumar, Ashwani, Bhattacharyya, Sayan·2017·ACS Applied Materials & Interfaces

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Abstract

Electrocatalytic water-splitting, a combination of oxygen and hydrogen evolution reactions (OER and HER), is highly attractive in clean energy technologies, especially for high-purity hydrogen production, whereas developing stable, earth-abundant, bifunctional catalysts has continued to pose major challenges. Herein, a mesoporous NiFe-oxide nanocube (NiFe-NC) system is developed from a NiFe Prussian blue analog metal–organic framework as an efficient bifunctional catalyst for overall water-splitting. The NiFe-NCs with ∼200 nm side length have a Ni/Fe molar ratio of 3:2 and is a composite of NiO and α/γ-Fe 2 O 3 . The NCs demonstrate overpotentials of 271 and 197 mV for OER and HER, respectively, in 1 M KOH at 10 mA cm –2, which outperform those of 339 and 347 mV for the spherical NiFe-oxide nanoparticles having a similar composition. The electrolyzer constructed using NiFe-NCs requires an impressive cell voltage of 1.67 V to deliver a current density of 10 mA cm –2 . Along with a mesoporous structure with a broad pore size distribution, the NiFe-NCs demonstrate the qualities of a desired corrosion-resistant water-splitting catalyst with long-term stability. The exposure of active sites at the edges and vertices of the NCs was validated to play a crucial role in their overall catalytic performance.

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Introduction to Metal–Organic Frameworks
Zhou, H.-C., Long, J. R., & Yaghi, O. M. (2012) · Chemical Reviews · doi:10.1021/cr300014x · Cited by 7,720
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Recent progress in alkaline water electrolysis for hydrogen production and applications
Zeng, K., & Zhang, D. (2010) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2009.11.002 · Cited by 3,611
Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., May, K. J., Perry, E. E., & Shao-Horn, Y. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz2016507 · Cited by 3,534
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts
Subbaraman, R., Tripkovic, D., Chang, K.-C., Strmcnik, D., Paulikas, A. P., Hirunsit, P., Chan, M., Greeley, J., Stamenkovic, V., & Markovic, N. M. (2012) · Nature Materials · doi:10.1038/nmat3313 · Cited by 3,053
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation
Gong, M., Li, Y., Wang, H., Liang, Y., Wu, J. Z., Zhou, J., Wang, J., Regier, T., Wei, F., & Dai, H. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4027715 · Cited by 2,837
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen
Louie, M. W., & Bell, A. T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405351s · Cited by 2,803
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
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Ma, T. Y., Dai, S., Jaroniec, M., & Qiao, S. Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5082553 · Cited by 1,846
In situ Cobalt–Cobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution
Jin, H., Wang, J., Su, D., Wei, Z., Pang, Z., & Wang, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5127165 · Cited by 1,765
NiSe Nanowire Film Supported on Nickel Foam: An Efficient and Stable 3D Bifunctional Electrode for Full Water Splitting
Tang, C., Cheng, N., Pu, Z., Xing, W., & Sun, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201503407 · Cited by 1,441
Interface Engineering of MoS2/Ni3S2 Heterostructures for Highly Enhanced Electrochemical Overall‐Water‐Splitting Activity
Zhang, J., Wang, T., Pohl, D., Rellinghaus, B., Dong, R., Liu, S., Zhuang, X., & Feng, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602237 · Cited by 1,412
Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts
Chen, W.-F., Muckerman, J. T., & Fujita, E. (2013) · Chemical Communications · doi:10.1039/c3cc44076a · Cited by 1,179
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst
Song, F., & Hu, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5096733 · Cited by 1,163
Core–shell MoO3–MoS2 Nanowires for Hydrogen Evolution: A Functional Design for Electrocatalytic Materials
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
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Liu, Y., Cheng, H., Lyu, M., Fan, S., Liu, Q., Zhang, W., Zhi, Y., Wang, C., Xiao, C., Wei, S., et al. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5085157 · Cited by 1,094
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Liao, L., Wang, S., Xiao, J., Bian, X., Zhang, Y., Scanlon, M. D., Hu, X., Tang, Y., Liu, B., & Girault, H. H. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42441c · Cited by 1,044
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Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885
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Jiang, N., You, B., Sheng, M., & Sun, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201501616 · Cited by 844
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Formation of Prussian‐Blue‐Analog Nanocages via a Direct Etching Method and their Conversion into Ni–Co‐Mixed Oxide for Enhanced Oxygen Evolution
Han, L., Yu, X., & Lou, X. W. (. (2016) · Advanced Materials · doi:10.1002/adma.201506315 · Cited by 633
Selenide‐Based Electrocatalysts and Scaffolds for Water Oxidation Applications
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Du, J. H., Chen, C., Cheng, F., & Chen, J. (2015) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b00518 · Cited by 138
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Electrochemical studies of the nickel electrode for the oxygen evolution reaction
Kibria, A. K. M. F. (1996) · International Journal of Hydrogen Energy · doi:10.1016/0360-3199(95)00066-6 · Cited by 97
Electrodeposited Ni‐P Alloy Nanoparticle Films for Efficiently Catalyzing Hydrogen‐ and Oxygen‐Evolution Reactions
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Authors: Kumar, A., & Bhattacharyya, S.
Venue: ACS Applied Materials & Interfaces
Publisher: American Chemical Society (ACS)
Published: 2017-11-17
Volume: 9
Issue: 48
Pages: 41906-41915
ISSN: 1944-8244 (ISSN-L)
1944-8252
DOI: 10.1021/acsami.7b14096
OpenAlex: W2767930587
Cited by: 299
References: 52
FWCI: 8.40
Type: journal article
Language: en
Open access: closed

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Porous NiFe-Oxide Nanocubes as Bifunctional Electrocatalysts for Efficient Water-Splitting

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