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Probing the Mechanism of Aqueous CO2 Reduction on Post-Transition-Metal Electrodes using ATR-IR Spectroelectrochemistry
Abstract
The role of metastable surface oxides in the reduction of CO 2 on lead, bismuth, tin, and indium electrodes was probed using in situ attenuated total reflectance infrared (ATR-IR) spectroelectrochemistry. The effect of the surface oxide on the Faradaic efficiency of CO 2 reduction to formic acid was studied by etching and anodizing the electrodes, and the results were correlated with respect to the observed spectroscopic behavior of the catalysts. A metastable oxide is observed on lead, tin, and indium cathodes under the electrochemical conditions necessary for CO 2 reduction. Spectroscopic evidence suggests that bismuth electrodes are fully reduced to the metal under the same conditions. The dynamics of the electroreduction of CO 2 at lead and bismuth electrodes appears to be different from that on on tin and indium electrodes, which suggests that these catalysts act through different mechanistic pathways. The post-transition-metal block can be divided into three classes of materials: oxide-active materials, oxide-buffered materials, and oxide-independent materials, and the mechanistic differences are discussed.
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Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Greening coal: breakthroughs and challenges in carbon capture and storage
Stauffer, P. H., Keating, G. N., Middleton, R. S., Viswanathan, H. S., Berchtold, K. A., Singh, R. P., Pawar, R. J., & Mancino, A. (2011) · Environmental Science & Technology · doi:10.1021/es200510f · Cited by 122
Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Metal‐Free Carbon Materials for CO2 Electrochemical Reduction
Duan, X., Xu, J., Wei, Z., Ma, J., Guo, S., Wang, S., Liu, H., & Dou, S. (2017) · Advanced Materials · doi:10.1002/adma.201701784 · Cited by 754
Han, N., Ding, P., He, L., Li, Y., & Li, Y. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902338 · Cited by 655
Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate
Zheng, X., De Luna, P., García de Arquer, F. P., Zhang, B., Becknell, N., Ross, M. B., Li, Y., Banis, M. N., Li, Y., Liu, M., et al. (2017) · Joule · doi:10.1016/j.joule.2017.09.014 · Cited by 515
Metadata
- Authors
- Pander, J. E., Baruch, M. F., & Bocarsly, A. B.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-10-19
- Volume
- 6
- Issue
- 11
- Pages
- 7824-7833
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2531769711
- Cited by
- 218
- References
- 3
- FWCI
- 5.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pander, J. E., Baruch, M. F., & Bocarsly, A. B. (2016). Probing the Mechanism of Aqueous CO2 Reduction on Post-Transition-Metal Electrodes using ATR-IR Spectroelectrochemistry. ACS Catalysis. https://doi.org/10.1021/acscatal.6b01879
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