The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Improved CO2 Electroreduction Performance on Plasma-Activated Cu Catalysts via Electrolyte Design: Halide Effect
Abstract
As a sustainable pathway for energy storage and to close the carbon cycle, CO 2 electroreduction has recently gained significant interest. We report here the role of the electrolyte, in particular of halide ions, on CO 2 electroreduction over plasma-oxidized polycrystalline Cu foils. It was observed that halide ions such as I – can induce significant nanostructuring of the oxidized Cu surface, even at open circuit potential, including the formation of Cu crystals with well-defined shapes. Furthermore, the presence of Cl –, Br –, and I – was found to lower the overpotential and to increase the CO 2 electroreduction rate on plasma-activated preoxidized Cu catalyst in the order Cl – < Br – < I –, without sacrificing their intrinsically high C 2 –C 3 product selectivity (∼65% total Faradaic efficiency at −1.0 V vs RHE). This enhancement in catalytic performance is mainly attributed to the specific adsorption of halides with a higher coverage on our oxidized Cu surface during the reaction, which have been previously reported to facilitate the formation and stabilization of the carboxyl (*COOH) intermediate by partial charge donation from the halide ions to CO 2 .
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How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Self-citationRen, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930
Electric Field Effects in Electrochemical CO 2 Reduction
Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702
Goodpaster, J. D., Bell, A. T., & Head-Gordon, M. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00358 · Cited by 702
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
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Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Ma, W., Xie, S., Liu, T., Fan, Q., Ye, J., Sun, F., Jiang, Z., Zhang, Q., Cheng, J., & Wang, Y. (2020) · Nature Catalysis · doi:10.1038/s41929-020-0450-0 · Cited by 1,468
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Arán-Ais, R. M., Scholten, F., Kunze, S., Rizo, R., & Roldan Cuenya, B. (2020) · Nature Energy · doi:10.1038/s41560-020-0594-9 · Cited by 771
Self-citationYang, P.-P., Zhang, X.-L., Gao, F.-Y., Zheng, Y.-R., Niu, Z.-Z., Yu, X., Liu, R., Wu, Z.-Z., Qin, S., Chi, L.-P., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c01699 · Cited by 709
Defect and Interface Engineering for Aqueous Electrocatalytic CO2 Reduction
Wang, Y., Han, P., Lv, X., Zhang, L., & Zheng, G. (2018) · Joule · doi:10.1016/j.joule.2018.09.021 · Cited by 677
Theoretical Insights into Heterogeneous (Photo)electrochemical CO2Reduction
Xu, S., & Carter, E. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00481 · Cited by 652
Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts
Woldu, A. R., Huang, Z., Zhao, P., Hu, L., & Astruc, D. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.214340 · Cited by 578
Yi, J., Xie, R., Xie, Z., Chai, G., Liu, T., Chen, R., Huang, Y., & Cao, R. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202010601 · Cited by 566
Catalyst Preparation with Plasmas: How Does It Work?
Wang, Z., Zhang, Y., Neyts, E. C., Cao, X., Zhang, X., Jang, B. W.-L., & Liu, C.-J. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03723 · Cited by 494
Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 478
Solvents and Supporting Electrolytes in the Electrocatalytic Reduction of CO2
König, M., Vaes, J., Klemm, E., & Pant, D. (2019) · iScience · doi:10.1016/j.isci.2019.07.014 · Cited by 429
Waegele, M. M., Gunathunge, C. M., Li, J., & Li, X. (2019) · The Journal of Chemical Physics · doi:10.1063/1.5124878 · Cited by 423
Lai, W., Qiao, Y., Zhang, J., Lin, Z., & Huang, H. (2022) · Energy & Environmental Science · doi:10.1039/d2ee00472k · Cited by 373
Structure- and Electrolyte-Sensitivity in CO2 Electroreduction
Arán-Ais, R. M., Gao, D., & Roldan Cuenya, B. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00360 · Cited by 341
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Meng, D., Zhang, M., Si, D., Mao, M., Hou, Y., Huang, Y., & Cao, R. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202111136 · Cited by 312
Herzog, A., Bergmann, A., Jeon, H. S., Timoshenko, J., Kühl, S., Rettenmaier, C., Lopez Luna, M., Haase, F. T., & Roldan Cuenya, B. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202017070 · Cited by 303
Self-citationJeon, H. S., Timoshenko, J., Scholten, F., Sinev, I., Herzog, A., Haase, F. T., & Roldan Cuenya, B. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10709 · Cited by 266
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Metadata
- Authors
- Gao, D., Scholten, F., & Roldan Cuenya, B.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-07-07
- Volume
- 7
- Issue
- 8
- Pages
- 5112-5120
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2698517883
- Cited by
- 338
- References
- 16
- FWCI
- 6.05
- Type
- journal article
- Language
- en
- Open access
- closed
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