The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts
Abstract
Electrochemical oxidation of biomass-derived platform molecules can enable the production of value-added oxygenated commodity chemicals under mild conditions in a distributed fashion using renewable electricity; however, very few efficient, robust, and inexpensive electrocatalysts are available for such electrochemical oxidation. Here we demonstrate that earth-abundant NiFe layered double hydroxide (LDH) nanosheets grown on carbon fiber paper can efficiently catalyze the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) at the anode of an electrochemical cell. A near-quantitative yield of FDCA and 99.4% Faradaic efficiency of HMF conversion under ambient conditions can be achieved in the electrochemical process. HMF has a higher rate of oxidation than water and can act as an alternative anodic reaction for alkaline H 2 evolution in water-splitting cells. As the first report on using bimetallic metal hydroxide/oxide catalysts for electrochemical oxidation of HMF, this work opens up opportunities in electrochemical devices to simultaneously produce building-block chemicals from biomass-derived molecules and clean H 2 fuels under ambient conditions with earth-abundant materials.
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Cites
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Metadata
- Authors
- Liu, W.-J., Dang, L., Xu, Z., Yu, H.-Q., Jin, S., & Huber, G. W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-05-10
- Volume
- 8
- Issue
- 6
- Pages
- 5533-5541
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2801231312
- Cited by
- 507
- References
- 45
- FWCI
- 16.04
- Type
- journal article
- Language
- en
- Open access
- closed
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