The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Supported Transition Metal Phosphides: Activity Survey for HER, ORR, OER, and Corrosion Resistance in Acid and Alkaline Electrolytes
Abstract
Carbon-supported M x P y (M = Ni, Co, W, Cr, and Mo) were prepared via pyrolysis using a very simple and scalable method utilizing nontoxic metal and phosphorus precursors. The electrochemical hydrogen evolution (HER), oxygen reduction (ORR), and oxygen evolution (OER) reactions and corrosion resistance under both acidic and alkaline conditions were examined for all these catalysts and compared to those for the benchmark catalysts Pt/C (HER/ORR) and IrO 2 (OER). The highest activities were found in alkaline solutions for Co 2 P for HER and ORR and Ni 2 P for OER. Good activity was also found in acid for some of these reactions, although the catalysts suffered from susceptibility to corrosion. Co 2 P was further studied in an alkaline environment, as it shows high catalytic activity toward the oxygen reduction reaction (ORR) without significant hysteresis. The onset potential (at 0.5 mA cm –2 ) obtained was 0.8 V vs RHE, and a Tafel slope value of 38 mV dec –1 was found with a maximum kinetic mass activity of 2870 A g Co –1 at 0.7 V vs RHE. Utilizing high-resolution transmission electron microscopy, it is possible to observe high-surface-area needle-like single-crystal cobalt oxide structures on the surface of the Co 2 P particles at the beginning of the ORR. Hence the high rates of initial corrosion of the Co 2 P appear to be associated with the dissolution and precipitation of cobalt oxide on the particle surface. The as-synthesized Co 2 P/C also shows good performance in an 8-h stability test for the OER, carried out at 1.6 V vs RHE in alkaline conditions, with negligible drop in current density over time. Interestingly, in an acidic environment the catalyst is very active toward two-electron oxygen reduction, leading to H 2 O 2 with high selectivity (85%). It is intriguing that the pH dependence of this catalyst toward the ORR is similar to that seen for gold.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
CRC Handbook of Chemistry and Physics
P, D. (1992) · Journal of Molecular Structure · doi:10.1016/0022-2860(92)85083-s · Cited by 9,329
Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
Liang, Y., Li, Y., Wang, H., Zhou, J., Wang, J., Regier, T., & Dai, H. (2011) · Nature Materials · doi:10.1038/nmat3087 · Cited by 5,494
Formation of hollow nanocrystals through the nanoscale kirkendall \neffect
Yin, Y., Rioux, R. M., Erdonmez, C. K., Hughes, S. M., Somorjai, G. A., & Alivisatos, A. P. (2004) · eScholarship (California Digital Library) · Cited by 3,537
Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Electrolysis of water on oxide surfaces
Rossmeisl, J., Qu, Z.-W., Zhu, H., Kroes, G.-J., & Nørskov, J. K. (2007) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.11.008 · Cited by 3,096
Zitolo, A., Goellner, V., Armel, V., Sougrati, M.-T., Mineva, T., Stievano, L., Fonda, E., & Jaouen, F. (2015) · Nature Materials · doi:10.1038/nmat4367 · Cited by 2,123
Ni2P as a Janus catalyst for water splitting: the oxygen evolution activity of Ni2P nanoparticles
Stern, L.-A., Feng, L., Song, F., & Hu, X. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01155h · Cited by 1,616
Enabling direct H2O2 production through rational electrocatalyst design
Siahrostami, S., Verdaguer-Casadevall, A., Karamad, M., Deiana, D., Malacrida, P., Wickman, B., Escudero-Escribano, M., Paoli, E. A., Frydendal, R., Hansen, T. W., et al. (2013) · Nature Materials · doi:10.1038/nmat3795 · Cited by 1,597
Burke, M. S., Enman, L. J., Batchellor, A. S., Zou, S., & Boettcher, S. W. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b03148 · Cited by 1,177
Mukerjee, S., Srinivasan, S., Soriaga, M. P., & McBreen, J. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2048590 · Cited by 1,155
Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives
Carenco, S., Portehault, D., Boissière, C., Mézailles, N., & Sanchez, C. (2013) · Chemical Reviews · doi:10.1021/cr400020d · Cited by 1,063
Single Atom Hot-Spots at Au–Pd Nanoalloys for Electrocatalytic H2O2 Production
Jirkovský, J. S., Panas, I., Ahlberg, E., Halasa, M., Romani, S., & Schiffrin, D. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206477z · Cited by 790
Zhou, R., Zheng, Y., Jaroniec, M., & Qiao, S.-Z. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01581 · Cited by 668
Chang, J., Xiao, Y., Xiao, M., Ge, J., Liu, C., & Xing, W. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02076 · Cited by 478
Alternative catalytic materials: carbides, nitrides, phosphides and amorphous boron alloys
Alexander, A.-M., & Hargreaves, J. S. J. (2010) · Chemical Society Reviews · doi:10.1039/b916787k · Cited by 467
Surface Chemistry in Cobalt Phosphide-Stabilized Lithium–Sulfur Batteries
Zhong, Y., Yin, L., He, P., Liu, W., Wu, Z., & Wang, H. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b11434 · Cited by 458
Coordination tuning of cobalt phosphates towards efficient water oxidation catalyst
Kim, H., Park, J., Park, I., Jin, K., Jerng, S. E., Kim, S. H., Nam, K. T., & Kang, K. (2015) · Nature Communications · doi:10.1038/ncomms9253 · Cited by 450
Yang, H., Zhang, Y., Hu, F., & Wang, Q. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b03446 · Cited by 449
Henkes, A. E., Vasquez, Y., & Schaak, R. E. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068502l · Cited by 422
Metal Phosphides: Preparation, Characterization and Catalytic Reactivity
Prins, R., & Bussell, M. E. (2012) · Catalysis Letters · doi:10.1007/s10562-012-0929-7 · Cited by 417
Kucernak, A. R. J., & Naranammalpuram Sundaram, V. N. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta03468f · Cited by 379
Self-citationOffer, G. J. (2009) · Platinum Metals Review · doi:10.1595/147106709x474361 · Cited by 361
Recent Trends in Fuel Cell Science and Technology
(2007) · Springer eBooks · doi:10.1007/978-0-387-68815-2 · Cited by 345
Xiao, J., Kuang, Q., Yang, S., Xiao, F., Wang, S., & Guo, L. (2013) · Scientific Reports · doi:10.1038/srep02300 · Cited by 332
Hall, D. S., Bock, C., & MacDougall, B. R. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.026303jes · Cited by 330
Park, J., Koo, B., Yoon, K. Y., Hwang, Y., Kang, M., Park, J.-G., & Hyeon, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0427496 · Cited by 307
X-ray Photoelectron and Absorption Spectroscopy of Metal-Rich Phosphides M2P and M3P (M = Cr−Ni)
Blanchard, P. E. R., Grosvenor, A. P., Cavell, R. G., & Mar, A. (2008) · Chemistry of Materials · doi:10.1021/cm802123a · Cited by 261
Wang, J., Yang, W., & Liu, J. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta00596a · Cited by 261
Li, J., Li, J., Zhou, X., Xia, Z., Gao, W., Ma, Y., & Qu, Y. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b00731 · Cited by 240
Nanostructured Carbon Materials for Catalysis
Serp, P., & Machado, B. (2015) · Royal Society of Chemistry eBooks · doi:10.1039/9781782622567 · Cited by 235
Wang, P., Song, F., Amal, R., Ng, Y. H., & Hu, X. (2016) · ChemSusChem · doi:10.1002/cssc.201501599 · Cited by 203
Ramaswamy, N., Hakim, N., & Mukerjee, S. (2008) · Electrochimica Acta · doi:10.1016/j.electacta.2007.11.010 · Cited by 189
Wendt, H., & Kreysa, G. (1999) · Springer eBooks · doi:10.1007/978-3-662-03851-2 · Cited by 169
Zhong, X., Jiang, Y., Chen, X., Wang, L., Zhuang, G., Li, X., & Wang, J. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta03820d · Cited by 154
Mechanism of Oxygen Electroreduction on Gold Surfaces in Basic Media
Kim, J., & Gewirth, A. A. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0549529 · Cited by 150
Doan‐Nguyen, V. V. T., Zhang, S., Trigg, E. B., Agarwal, R., Li, J., Su, D., Winey, K. I., & Murray, C. B. (2015) · ACS Nano · doi:10.1021/acsnano.5b02191 · Cited by 144
Grimaud, A., Carlton, C. E., Risch, M., Hong, W. T., May, K. J., & Shao‐Horn, Y. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp408585z · Cited by 135
Li, J., Liu, G., Liu, B., Min, Z., Qian, D. J., Jiang, J., & Li, J. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.11.102 · Cited by 133
A novel synthetic approach to synthesizing bulk and supported metal phosphides
Guan, Q., & Li, W. (2010) · Journal of Catalysis · doi:10.1016/j.jcat.2010.02.031 · Cited by 124
Shu, Y., & Oyama, S. T. (2005) · Carbon · doi:10.1016/j.carbon.2005.01.036 · Cited by 113
The Role of the Lower Metal Oxide/Higher Metal Oxide Couple in Oxygen Evolution Reactions
Rasiyah, P., & Tseung, A. C. C. (1984) · Journal of The Electrochemical Society · doi:10.1149/1.2115703 · Cited by 111
Mei, D., He, Z. D., Zheng, Y. L., Jiang, D. C., & Chen, Y. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00257a · Cited by 101
Kucernak, A. R., Fahy, K. F., & Sundaram, V. N. N. (2015) · Catalysis Today · doi:10.1016/j.cattod.2015.09.031 · Cited by 82
Self-citationThe intriguing poison tolerance of non-precious metal oxygen reduction reaction (ORR) catalysts
Malko, D., Lopes, T., Symianakis, E., & Kucernak, A. R. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta05794a · Cited by 80
Self-citationKim, N.-I., Jin, Y., Cho, S.-H., So, I., Kwon, K., Joo, S. H., & Park, J. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0031611jes · Cited by 69
Jiang, H., Li, C., Shen, H., Liu, Y., Li, W., & Li, J. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.02.074 · Cited by 65
Cobalt phosphide-based nanoparticles as bifunctional electrocatalysts for alkaline water splitting
Vigil, J. A., Lambert, T. N., & Christensen, B. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta00637j · Cited by 62
Ramakrishnan, V., Kim, H., Park, J., & Yang, B. (2016) · RSC Advances · doi:10.1039/c5ra23200g · Cited by 41
Chen, K., Huang, X., Wan, C., & Liu, H. (2015) · RSC Advances · doi:10.1039/c5ra21385a · Cited by 40
One-pot synthesis and characterization of metal phosphide-doped carbon xerogels
Wang, H., Shu, Y., Wang, A., Wang, J., Zheng, M., Wang, X., & Zhang, T. (2008) · Carbon · doi:10.1016/j.carbon.2008.08.021 · Cited by 29
Kim, T., Song, H. J., Dar, M. A., Shim, H., & Kim, D. (2018) · Journal of the American Ceramic Society · doi:10.1111/jace.15581 · Cited by 27
A novel synthetic route to transition metal phosphide nanoparticles
Yao, Z., Li, M., Wang, X., Qiao, X., Zhu, J., Zhao, Y. F., Wang, G., Yin, J., & Wang, H. (2015) · Dalton Transactions · doi:10.1039/c4dt03886j · Cited by 24
Cited by
Pu, Z., Liu, T., Amiinu, I. S., Cheng, R., Wang, P., Zhang, C., Ji, P., Hu, W., Liu, J., & Mu, S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202004009 · Cited by 604
Zhang, G., Li, Y., Xiao, X., Shan, Y., Bai, Y., Xue, H.-G., Pang, H., Tian, Z., & Xu, Q. (2021) · Nano Letters · doi:10.1021/acs.nanolett.1c00179 · Cited by 367
Zhai, L., Benedict Lo, T. W., Xu, Z.-L., Potter, J., Mo, J., Guo, X., Tang, C. C., Edman Tsang, S. C., & Lau, S. P. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c01385 · Cited by 188
Wu, T., Hong, J., Lu, Z., Wu, H., Wu, C., Tang, Z., Liu, X., Zeng, B., Xu, Y., Chen, G., et al. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119795 · Cited by 50
Bimetallic Ni–Co selenide heterostructure aerogel for highly efficient overall water splitting
Liu, H., Yang, F., Chen, F., Che, S., Chen, N., Xu, C., Wu, N., Wei, W., & Li, Y. (2023) · Materials Chemistry Frontiers · doi:10.1039/d2qm01082h · Cited by 40
Metadata
- Authors
- Parra-Puerto, A., Ng, K. L., Fahy, K., Goode, A. E., Ryan, M. P., & Kucernak, A.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-10-31
- Volume
- 9
- Issue
- 12
- Pages
- 11515-11529
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2982496391
- Cited by
- 391
- References
- 52
- FWCI
- 8.61
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
