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Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles

Open access
Burke, Michaela S., Enman, Lisa J., Batchellor, Adam S., Zou, Shihui, Boettcher, Shannon W.·2015·Chemistry of Materials
DOI 10.1021/acs.chemmater.5b03148
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Abstract

Poor oxygen evolution reaction (OER) catalysis limits the efficiency of H 2 production from water electrolysis and photoelectrolysis routes to large-scale energy storage. Despite nearly a century of research, the factors governing the activity of OER catalysts are not well understood. In this Perspective, we discuss recent advances in understanding the OER in alkaline media for earth-abundant, first-row, transition-metal oxides and (oxy)hydroxides. We argue that the most-relevant structures for study are thermodynamically stable (oxy)hydroxides and not crystalline oxides. We discuss thin-film electrochemical microbalance techniques to accurately quantify intrinsic activity and in situ conductivity measurements to identify materials limited by electronic transport. We highlight the dramatic effect that Fe cations—added either intentionally or unintentionally from ubiquitous electrolyte impurities—have on the activity of common OER catalysts. We find new activity trends across the first-row transition metals, opposite of the established ones, and propose a new view of OER on mixed-metal (oxy)hydroxides that illustrates possible design principles and applications.

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Metadata

Authors
Burke, M. S., Enman, L. J., Batchellor, A. S., Zou, S., & Boettcher, S. W.
Venue
Chemistry of Materials
Publisher
American Chemical Society (ACS)
Published
2015-10-14
Volume
27
Issue
22
Pages
7549-7558
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
DOI
10.1021/acs.chemmater.5b03148
OpenAlex
W2229597030
Cited by
1,177
References
4
FWCI
31.67
Type
journal article
Language
en
Open access
green
Funders
  • Division of Chemistry (CHE-1301461)
  • Camille and Henry Dreyfus Foundation
  • Research Corporation for Science Advancement
  • Alfred P. Sloan Foundation

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CoChat. (2026). Citation check: Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles. https://app.cochat.ai/papers/10.1021/acs.chemmater.5b03148
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Burke, M. S., Enman, L. J., Batchellor, A. S., Zou, S., & Boettcher, S. W. (2015). Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b03148

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