The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Electrolysis of Gaseous CO2 to CO in a Flow Cell with a Bipolar Membrane
Abstract
The conversion of CO 2 to CO is demonstrated in an electrolyzer flow cell containing a bipolar membrane at current densities of 200 mA/cm 2 with a Faradaic efficiency of 50%. Electrolysis was carried out by delivering gaseous CO 2 at the cathode with a silver catalyst integrated in a carbon-based gas diffusion layer. Nonprecious nickel foam in a strongly alkaline electrolyte (1 M NaOH) was used to mediate the anode reaction. While a configuration where the anode and cathode were separated by only a bipolar membrane was found to be unfavorable for robust CO 2 reduction, a modified configuration with a solid-supported aqueous layer inserted between the silver-based catalyst layer and the bipolar membrane enhanced the cathode selectivity for CO 2 reduction to CO. We report higher current densities (200 mA/cm 2 ) than previously reported for gas-phase CO 2 to CO electrolysis and demonstrate the dependence of long-term stability on adequate hydration of the CO 2 inlet stream.
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A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Verma, S., Lu, X., Ma, S., Masel, R. I., & Kenis, P. J. A. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp05665a · Cited by 497
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Electrolysis of CO2 to Syngas in Bipolar Membrane-Based Electrochemical Cells
Li, Y. C., Zhou, D., Yan, Z., Gonçalves, R. H., Salvatore, D. A., Berlinguette, C. P., & Mallouk, T. E. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00475 · Cited by 313
Self-citationBench-scale electrochemical system for generation of CO and syn-gas
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Cited by
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Bipolar membranes: A review on principles, latest developments, and applications
Pärnamäe, R., Mareev, S., Nikonenko, V., Melnikov, S., Sheldeshov, N., Zabolotskii, V., Hamelers, H. V. M., & Tedesco, M. (2021) · Journal of Membrane Science · doi:10.1016/j.memsci.2020.118538 · Cited by 610
Garg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2020) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 478
Towards membrane-electrode assembly systems for CO2 reduction: a modeling study
Weng, L.-C., Bell, A. T., & Weber, A. Z. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00909d · Cited by 452
Metadata
- Authors
- Salvatore, D. A., Weekes, D. M., He, J., Dettelbach, K. E., Li, Y. C., Mallouk, T. E., & Berlinguette, C. P.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-12-19
- Volume
- 3
- Issue
- 1
- Pages
- 149-154
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2779986708
- Cited by
- 349
- References
- 10
- FWCI
- 6.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Salvatore, D. A., Weekes, D. M., He, J., Dettelbach, K. E., Li, Y. C., Mallouk, T. E., & Berlinguette, C. P. (2018). Electrolysis of Gaseous CO2 to CO in a Flow Cell with a Bipolar Membrane. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.7b01017
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