Bench-scale electrochemical system for generation of CO and syn-gas
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Buffer layers between catalyst and membrane may not be effective for long run timescales, increase cell resistance, and negate attractive features of gas phase electrolyzers.
“however, these layers may not be effective for long run timescales, increase the resistance of the cell, and negate some of the most attractive features of gas phase electrolyzers.[157]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [157]
Including a buffer layer between the catalyst and membrane can circumvent cathode acidification in these systems.
“Researchers have managed to circumvent this acidification by including a buffer layer between the catalyst and membrane, however, these layers may not be effective for long run timescales, increase the resistance of the cell, and negate some of the most attractive features of gas phase electrolyzers.[157]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [157]
Delacourt et al. found that catalysts with 20 wt% acetylene black support exhibited higher CO2RR selectivity compared to their unsupported counterparts.
“Similarly, in CO2RR, Delacourt et al. found that catalysts with 20 wt% acetylene black support exhibited higher CO2RR selectivity compared to their unsupported counterparts.[157]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [157]
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- Authors
- Dufek, E. J., Lister, T. E., & McIlwain, M. E.
- Affiliations
- Idaho National Laboratory (US)
- Corresponding author
- Lister, Tedd E.
- Venue
- Journal of Applied Electrochemistry
- Published
- 2011-03-02
- Volume
- 41
- Issue
- 6
- Pages
- 623-631
- ISSN
- 0021-891X (ISSN-L)
- 1572-8838
- OpenAlex
- W2013558393
- Cited by
- 139
- References
- 25
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 10 · 2023: 12 · 2022: 15 · 2021: 18 · 2020: 11 · 2019: 16 · 2018: 8 · 2017: 9 · 2016: 4 · 2015: 5 · 2014: 5 · 2013: 6 · 2012: 4
- FWCI
- 2.25
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.springer.com/tdm (tdm)
- Locations
- Journal of Applied Electrochemistry (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- electrochemical CO2 reduction, syngas, carbon monoxide production, hydrogen production, flow cell, high-temperature operation, overpotential, current density, H2/CO ratio control, cell efficiency
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