The DOI matches its Crossref record; 164 of the 164 references it cites were found in a registry or an index.
Thermochemical CO2 Hydrogenation to Single Carbon Products: Scientific and Technological Challenges
Open accessAbstract
Abstract Catalytic conversion of CO2 to chemicals and fuels is a “two birds, one stone” approach toward solving the climate change problem and energy demand–supply deficit in the modern world. Recent advances in mechanistic insights and design of suitable catalysts for direct thermocatalytic hydrogenation of CO2 to C1 products are thoroughly discussed in this Review. The role of catalyst composition and process conditions in determining the selective pathways to various products like carbon monoxide, methanol, methane, and dimethyl ether has been overviewed in light of thermodynamic and kinetic considerations. After extensive elaboration of the main motivation of the reaction pathways, catalytic roles, and reaction thermodynamics, we summarize the most important macroscopic aspects of CO2 hydrogenation technology development, which include reactor innovations, industrial status of the technology, life cycle assessment and technoeconomic analysis. Finally, a critical perspective on the future challenges and opportunities in both the core fronts and overall technology development is provided.
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Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Aresta, M., Dibenedetto, A., & Angelini, A. (2014) · Chemical Reviews · doi:10.1021/cr4002758 · Cited by 3,143
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts
Behrens, M., Studt, F., Kasatkin, I., Kühl, S., Hävecker, M., Abild-Pedersen, F., Zander, S., Girgsdies, F., Kurr, P., Kniep, B.-L., et al. (2012) · Science · doi:10.1126/science.1219831 · Cited by 2,670
Artz, J., Müller, T. E., Thenert, K., Kleinekorte, J., Meys, R., Sternberg, A., Bardow, A., & Leitner, W. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00435 · Cited by 2,436
Handbook of Heterogeneous Catalysis
(1997) · Wiley eBooks · doi:10.1002/9783527619474 · Cited by 2,387
Platinum-Like Behavior of Tungsten Carbide in Surface Catalysis
Levy, R. B., & Boudart, M. (1973) · Science · doi:10.1126/science.181.4099.547 · Cited by 2,000
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts
Kattel, S., Ramírez, P. J., Chen, J. G., Rodriguez, J. A., & Liu, P. (2017) · Science · doi:10.1126/science.aal3573 · Cited by 1,824
Kondratenko, E. V., Mul, G., Baltrusaitis, J., Larrazábal, G. O., & Pérez-Ramírez, J. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41272e · Cited by 1,802
Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A. V., Wezendonk, T. A., Makkee, M., Gascon, J., & Kapteijn, F. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00816 · Cited by 1,600
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Computational Approach to Molecular Catalysis by 3d Transition Metals: Challenges and Opportunities
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Jiang, Y., Liao, J.-F., Chen, H.-Y., Zhang, H.-H., Li, J.-Y., Wang, X.-D., & Kuang, D.-B. (2020) · Chem · doi:10.1016/j.chempr.2020.01.005 · Cited by 404
The reverse water gas shift reaction: a process systems engineering perspective
González-Castaño, M., Dorneanu, B., & Arellano-García, H. (2021) · Reaction Chemistry & Engineering · doi:10.1039/d0re00478b · Cited by 369
Advances in the Design of Heterogeneous Catalysts and Thermocatalytic Processes for CO2 Utilization
De, S., Dokania, A., Ramirez, A., & Gascon, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c04273 · Cited by 355
A Review of The Methanol Economy: The Fuel Cell Route
Simon Araya, S., Liso, V., Cui, X., Li, N., Zhu, J., Sahlin, S. L., Jensen, S. H., Nielsen, M. P., & Kær, S. K. (2020) · Energies · doi:10.3390/en13030596 · Cited by 298
Metadata
- Authors
- Roy, S., Cherevotan, A., & Peter, S. C.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-07-06
- Volume
- 3
- Issue
- 8
- Pages
- 1938-1966
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2878663886
- Cited by
- 512
- References
- 164
- FWCI
- 7.59
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Roy, S., Cherevotan, A., & Peter, S. C. (2018). Thermochemical CO2 Hydrogenation to Single Carbon Products: Scientific and Technological Challenges. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00740
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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