MoS 2 Moiré Superlattice for Hydrogen Evolution Reaction
Abstract
A MoS 2 moiré superlattice with a twisted angle of θ ≈ 7.3° via a facile method instead of a conventional mechanical stacking method is successfully fabricated. With reduced interlayer potential barriers demonstrated by first-principles calculations and ultralow frequency Raman spectra, electrons can transfer easily from a conductive substrate to active sites in this MoS 2 superlattice, thus leading to good hydrogen evolution reaction (HER) activities. By using an electrochemical microcell technique, improved catalytic performance in the MoS 2 moiré superlattice is validated, with a current density of −10 mA/cm 2 at an overpotential of −153 mV and a Tafel slope of 73 mV/dec. A strategy to boost the electrocatalytic performance by reducing the interlayer potential barriers is successfully achieved by employing a MoS 2 moiré superlattice. The work paves a new pathway to break the bottleneck for further improvement of HER performance and also opens interesting possibilities for implementing moiré superlattices in catalysis, energy storage, and 2D functional devices.
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MoS2 shows great potential as a cost-effective HER electrocatalyst due to its low cost, abundant resources, and unique physical and chemical properties.
“Among them, MoS2, with its low cost, abundant resources, and unique physical and chemical properties, shows great potential as a cost-effective HER electrocatalyst [13, 14].”
From Molybdenum disulfide supported on chitin carbon aerogels as an efficient and stable hydrogen evolution electrocatalyst (2025) · cites this paper as [13]
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- Authors
- Jiang, Z., Zhou, W., Hong, A., Guo, M., Luo, X., & Yuan, C.
- Affiliations
- Jiangxi Normal University (CN)
- Corresponding author
- Yuan, Cailei
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-10-30
- Volume
- 4
- Issue
- 12
- Pages
- 2830-2835
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2982461889
- Cited by
- 135
- References
- 45
- Citations by year
- 2026: 10 · 2025: 14 · 2024: 18 · 2023: 23 · 2022: 30 · 2021: 30 · 2020: 10
- FWCI
- 3.73
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Energy Letters (publishedVersion)
- Funders
- National Natural Science Foundation of China (51561012, 51661012, 51761017, 51871115)
- Government of Jiangxi Province (20171BCB23033)
- Natural Science Foundation of Jiangxi Province (20181BAB206001)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Keywords
- MoS2, moiré superlattices, hydrogen evolution reaction, electrocatalysis, twisted bilayers, two-dimensional materials, electrochemical microcell, Tafel slope, overpotential
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